Volumetric Properties in the NaAsO2 + H2O System at Temperature from 283.15 to 363.15 K and Atmospheric Pressure
Densities of sodium arsenite (NaAsO2) aqueous solution with the molality varied from 0.19570 to 1.94236 mol·kg−1 at temperature intervals of 5 K from 283.15 to 363.15 K and 101 ± 5 kPa were measured by a precise Anton Paar Digital vibrating-tube densimeter. Apparent molar volumes (VΦ) and thermal ex...
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| Aineistotyyppi: | Artikkeli |
| Kieli: | English |
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Wiley
2020-01-01
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| Sarja: | Journal of Chemistry |
| Linkit: | http://dx.doi.org/10.1155/2020/9478365 |
| _version_ | 1826823572475084800 |
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| author | Hongfang Hou Wanjing Cui Jiaojiao Chen Lingzong Meng Yafei Guo Tianlong Deng |
| author_facet | Hongfang Hou Wanjing Cui Jiaojiao Chen Lingzong Meng Yafei Guo Tianlong Deng |
| author_sort | Hongfang Hou |
| collection | DOAJ |
| description | Densities of sodium arsenite (NaAsO2) aqueous solution with the molality varied from 0.19570 to 1.94236 mol·kg−1 at temperature intervals of 5 K from 283.15 to 363.15 K and 101 ± 5 kPa were measured by a precise Anton Paar Digital vibrating-tube densimeter. Apparent molar volumes (VΦ) and thermal expansion coefficient (α) were obtained on the basis of experimental data. The 3D diagram of apparent molar volume against temperature and molality and the diagram of thermal expansion coefficient against molality were generated. According to the Pitzer ion-interaction equation of the apparent molar volume model, the Pitzer single-salt parameters (βM,X0υ, βM,X1υ, βM,X2υ, and CM,Xυ, MX = NaAsO2) and their temperature-dependent correlation F(i, p, T) = a1 + a2ln (T/298.15) + a3(T − 298.15) + a4/(620 − T) + a5/(T − 227) (where T is temperature in Kelvin and ai are the correlation coefficients) for NaAsO2 were obtained for the first time. The predictive apparent molar volumes agree well with the experimental values, and those results indicated that the single-salt parameters and the temperature-dependent formula are reliable. |
| first_indexed | 2025-02-16T07:25:21Z |
| format | Article |
| id | doaj.art-b51d99a6031740b5b06b9de849d2ec17 |
| institution | Directory Open Access Journal |
| issn | 2090-9063 2090-9071 |
| language | English |
| last_indexed | 2025-02-16T07:25:21Z |
| publishDate | 2020-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Chemistry |
| spelling | doaj.art-b51d99a6031740b5b06b9de849d2ec172025-02-03T06:06:43ZengWileyJournal of Chemistry2090-90632090-90712020-01-01202010.1155/2020/94783659478365Volumetric Properties in the NaAsO2 + H2O System at Temperature from 283.15 to 363.15 K and Atmospheric PressureHongfang Hou0Wanjing Cui1Jiaojiao Chen2Lingzong Meng3Yafei Guo4Tianlong Deng5Tianjin Key Laboratory of Marine Resources and Chemistry, College of Chemical Engineering and Materials Science, Tianjin University of Science and Technology, Tianjin 300457, ChinaTianjin Key Laboratory of Marine Resources and Chemistry, College of Chemical Engineering and Materials Science, Tianjin University of Science and Technology, Tianjin 300457, ChinaTianjin Key Laboratory of Marine Resources and Chemistry, College of Chemical Engineering and Materials Science, Tianjin University of Science and Technology, Tianjin 300457, ChinaTianjin Key Laboratory of Marine Resources and Chemistry, College of Chemical Engineering and Materials Science, Tianjin University of Science and Technology, Tianjin 300457, ChinaTianjin Key Laboratory of Marine Resources and Chemistry, College of Chemical Engineering and Materials Science, Tianjin University of Science and Technology, Tianjin 300457, ChinaTianjin Key Laboratory of Marine Resources and Chemistry, College of Chemical Engineering and Materials Science, Tianjin University of Science and Technology, Tianjin 300457, ChinaDensities of sodium arsenite (NaAsO2) aqueous solution with the molality varied from 0.19570 to 1.94236 mol·kg−1 at temperature intervals of 5 K from 283.15 to 363.15 K and 101 ± 5 kPa were measured by a precise Anton Paar Digital vibrating-tube densimeter. Apparent molar volumes (VΦ) and thermal expansion coefficient (α) were obtained on the basis of experimental data. The 3D diagram of apparent molar volume against temperature and molality and the diagram of thermal expansion coefficient against molality were generated. According to the Pitzer ion-interaction equation of the apparent molar volume model, the Pitzer single-salt parameters (βM,X0υ, βM,X1υ, βM,X2υ, and CM,Xυ, MX = NaAsO2) and their temperature-dependent correlation F(i, p, T) = a1 + a2ln (T/298.15) + a3(T − 298.15) + a4/(620 − T) + a5/(T − 227) (where T is temperature in Kelvin and ai are the correlation coefficients) for NaAsO2 were obtained for the first time. The predictive apparent molar volumes agree well with the experimental values, and those results indicated that the single-salt parameters and the temperature-dependent formula are reliable.http://dx.doi.org/10.1155/2020/9478365 |
| spellingShingle | Hongfang Hou Wanjing Cui Jiaojiao Chen Lingzong Meng Yafei Guo Tianlong Deng Volumetric Properties in the NaAsO2 + H2O System at Temperature from 283.15 to 363.15 K and Atmospheric Pressure Journal of Chemistry |
| title | Volumetric Properties in the NaAsO2 + H2O System at Temperature from 283.15 to 363.15 K and Atmospheric Pressure |
| title_full | Volumetric Properties in the NaAsO2 + H2O System at Temperature from 283.15 to 363.15 K and Atmospheric Pressure |
| title_fullStr | Volumetric Properties in the NaAsO2 + H2O System at Temperature from 283.15 to 363.15 K and Atmospheric Pressure |
| title_full_unstemmed | Volumetric Properties in the NaAsO2 + H2O System at Temperature from 283.15 to 363.15 K and Atmospheric Pressure |
| title_short | Volumetric Properties in the NaAsO2 + H2O System at Temperature from 283.15 to 363.15 K and Atmospheric Pressure |
| title_sort | volumetric properties in the naaso2 h2o system at temperature from 283 15 to 363 15 k and atmospheric pressure |
| url | http://dx.doi.org/10.1155/2020/9478365 |
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