Design and synthesis of charged porphyrin dimers for polyoxometalate recognition
A series of porphyrin dimers have been prepared and characterized in order to form inclusion complexes with Lindqvist-type polyoxometallates. The synthesis of the porphyrin dimer has been optimized and can serve general purposes. The formation of inclusion complexes has been monitored using spectros...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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Académie des sciences
2021-08-01
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| Series: | Comptes Rendus. Chimie |
| Subjects: | |
| Online Access: | https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.105/ |
| _version_ | 1797651404018417664 |
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| author | Lamare, Raphaël Ruppert, Romain Elhabiri, Mourad Ulrich, Gilles Ruhlmann, Laurent Weiss, Jean |
| author_facet | Lamare, Raphaël Ruppert, Romain Elhabiri, Mourad Ulrich, Gilles Ruhlmann, Laurent Weiss, Jean |
| author_sort | Lamare, Raphaël |
| collection | DOAJ |
| description | A series of porphyrin dimers have been prepared and characterized in order to form inclusion complexes with Lindqvist-type polyoxometallates. The synthesis of the porphyrin dimer has been optimized and can serve general purposes. The formation of inclusion complexes has been monitored using spectroscopic methods and moderate affinities with $\log \, K_{\mathrm{assoc}}$ varying from 2.6 to 4.2 have been determined and the parameters governing the formation of the complexes have been examined. |
| first_indexed | 2024-03-11T16:14:31Z |
| format | Article |
| id | doaj.art-b536ba350fb3435281f8edc302075818 |
| institution | Directory Open Access Journal |
| issn | 1878-1543 |
| language | English |
| last_indexed | 2024-03-11T16:14:31Z |
| publishDate | 2021-08-01 |
| publisher | Académie des sciences |
| record_format | Article |
| series | Comptes Rendus. Chimie |
| spelling | doaj.art-b536ba350fb3435281f8edc3020758182023-10-24T14:23:03ZengAcadémie des sciencesComptes Rendus. Chimie1878-15432021-08-0124S311512610.5802/crchim.10510.5802/crchim.105Design and synthesis of charged porphyrin dimers for polyoxometalate recognitionLamare, Raphaël0https://orcid.org/0000-0003-4661-4000Ruppert, Romain1https://orcid.org/0000-0002-1513-1949Elhabiri, Mourad2https://orcid.org/0000-0001-6371-7533Ulrich, Gilles3https://orcid.org/0000-0002-6980-6091Ruhlmann, Laurent4https://orcid.org/0000-0003-1154-2422Weiss, Jean5https://orcid.org/0000-0001-7753-8958Institut de Chimie de Strasbourg, UMR 7177 CNRS-Université de Strasbourg, 4 rue Blaise Pascal, 67000 Strasbourg, FranceInstitut de Chimie de Strasbourg, UMR 7177 CNRS-Université de Strasbourg, 4 rue Blaise Pascal, 67000 Strasbourg, FranceEquipe Chimie Bioorganique et Médicinale, Laboratoire d’Innovation Moléculaire et Applications (LIMA), UMR7042, CNRS-Unistra-UHA, European School of Chemistry, Polymers and Materials (ECPM), 25, rue Becquerel, 67087 Strasbourg, FranceICPEES - Institut de Chimie et Procédés pour l’Énergie, l’Environnement et la Santé, ECPM, 25 rue Becquerel, 67087 Strasbourg, FranceInstitut de Chimie de Strasbourg, UMR 7177 CNRS-Université de Strasbourg, 4 rue Blaise Pascal, 67000 Strasbourg, FranceInstitut de Chimie de Strasbourg, UMR 7177 CNRS-Université de Strasbourg, 4 rue Blaise Pascal, 67000 Strasbourg, FranceA series of porphyrin dimers have been prepared and characterized in order to form inclusion complexes with Lindqvist-type polyoxometallates. The synthesis of the porphyrin dimer has been optimized and can serve general purposes. The formation of inclusion complexes has been monitored using spectroscopic methods and moderate affinities with $\log \, K_{\mathrm{assoc}}$ varying from 2.6 to 4.2 have been determined and the parameters governing the formation of the complexes have been examined.https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.105/PorphyrinsPolyoxometalatesMolecular recognitionFluorescence quenchingHost–guest chemistry |
| spellingShingle | Lamare, Raphaël Ruppert, Romain Elhabiri, Mourad Ulrich, Gilles Ruhlmann, Laurent Weiss, Jean Design and synthesis of charged porphyrin dimers for polyoxometalate recognition Comptes Rendus. Chimie Porphyrins Polyoxometalates Molecular recognition Fluorescence quenching Host–guest chemistry |
| title | Design and synthesis of charged porphyrin dimers for polyoxometalate recognition |
| title_full | Design and synthesis of charged porphyrin dimers for polyoxometalate recognition |
| title_fullStr | Design and synthesis of charged porphyrin dimers for polyoxometalate recognition |
| title_full_unstemmed | Design and synthesis of charged porphyrin dimers for polyoxometalate recognition |
| title_short | Design and synthesis of charged porphyrin dimers for polyoxometalate recognition |
| title_sort | design and synthesis of charged porphyrin dimers for polyoxometalate recognition |
| topic | Porphyrins Polyoxometalates Molecular recognition Fluorescence quenching Host–guest chemistry |
| url | https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.105/ |
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