2-[(Pyridin-2-yl)amino]pyridinium 2,4,6-trinitrophenolate
In the cation of the title salt, C10H10N3+·C6H2N3O7−, the pyridine and pyridinium rings are linked by an intramolecular N—H...N hydrogen bond and are approximately coplanar, with a dihedral angle between their planes of 4.24 (6)°. In the crystal, the cations and anions are linked through N—H...O hyd...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814012835 |
| _version_ | 1798018487659003904 |
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| author | Kateryna A. Ohui Irina A. Golenya Nadezhda A. Bokach |
| author_facet | Kateryna A. Ohui Irina A. Golenya Nadezhda A. Bokach |
| author_sort | Kateryna A. Ohui |
| collection | DOAJ |
| description | In the cation of the title salt, C10H10N3+·C6H2N3O7−, the pyridine and pyridinium rings are linked by an intramolecular N—H...N hydrogen bond and are approximately coplanar, with a dihedral angle between their planes of 4.24 (6)°. In the crystal, the cations and anions are linked through N—H...O hydrogen bonds, forming supramolecular chains propagating along the c-axis direction. π–π stacking is observed between neighbouring chains, the centroid–centroid distances being 3.7638 (11) (between pyridinium rings) and 3.5331 (11) Å (between benzene rings). |
| first_indexed | 2024-04-11T16:24:46Z |
| format | Article |
| id | doaj.art-b54182e6ab604de590de330e4166540c |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T16:24:46Z |
| publishDate | 2014-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-b54182e6ab604de590de330e4166540c2022-12-22T04:14:13ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-07-01707o778o77810.1107/S1600536814012835xu57942-[(Pyridin-2-yl)amino]pyridinium 2,4,6-trinitrophenolateKateryna A. Ohui0Irina A. Golenya1Nadezhda A. Bokach2Department of Chemistry, Taras Shevchenko National University of Kyiv, Volodymyrska 64/13, 01601 Kyiv, UkraineDepartment of Chemistry, Taras Shevchenko National University of Kyiv, Volodymyrska 64/13, 01601 Kyiv, UkraineDepartment of Chemistry, Saint Petersburg State University, Universitetsky Pr. 26, 198504 Stary Petergof, Russian FederationIn the cation of the title salt, C10H10N3+·C6H2N3O7−, the pyridine and pyridinium rings are linked by an intramolecular N—H...N hydrogen bond and are approximately coplanar, with a dihedral angle between their planes of 4.24 (6)°. In the crystal, the cations and anions are linked through N—H...O hydrogen bonds, forming supramolecular chains propagating along the c-axis direction. π–π stacking is observed between neighbouring chains, the centroid–centroid distances being 3.7638 (11) (between pyridinium rings) and 3.5331 (11) Å (between benzene rings).http://scripts.iucr.org/cgi-bin/paper?S1600536814012835 |
| spellingShingle | Kateryna A. Ohui Irina A. Golenya Nadezhda A. Bokach 2-[(Pyridin-2-yl)amino]pyridinium 2,4,6-trinitrophenolate Acta Crystallographica Section E |
| title | 2-[(Pyridin-2-yl)amino]pyridinium 2,4,6-trinitrophenolate |
| title_full | 2-[(Pyridin-2-yl)amino]pyridinium 2,4,6-trinitrophenolate |
| title_fullStr | 2-[(Pyridin-2-yl)amino]pyridinium 2,4,6-trinitrophenolate |
| title_full_unstemmed | 2-[(Pyridin-2-yl)amino]pyridinium 2,4,6-trinitrophenolate |
| title_short | 2-[(Pyridin-2-yl)amino]pyridinium 2,4,6-trinitrophenolate |
| title_sort | 2 pyridin 2 yl amino pyridinium 2 4 6 trinitrophenolate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536814012835 |
| work_keys_str_mv | AT katerynaaohui 2pyridin2ylaminopyridinium246trinitrophenolate AT irinaagolenya 2pyridin2ylaminopyridinium246trinitrophenolate AT nadezhdaabokach 2pyridin2ylaminopyridinium246trinitrophenolate |