The Applications of Solid-State NMR to Conducting Polymers. The Special Case on Polyaniline
Polyaniline is one of the most well studied conducting polymers due to its advanced electrical, chemical, redox and morphological properties. The high conductivity of regular polyaniline, when partially oxidized and doped under acidic conditions, has been associated with the formation of unique elec...
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| Format: | Article |
| Language: | English |
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MDPI AG
2020-01-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/25/3/444 |
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| author | Zoran Zujovic Paul A. Kilmartin Jadranka Travas-Sejdic |
| author_facet | Zoran Zujovic Paul A. Kilmartin Jadranka Travas-Sejdic |
| author_sort | Zoran Zujovic |
| collection | DOAJ |
| description | Polyaniline is one of the most well studied conducting polymers due to its advanced electrical, chemical, redox and morphological properties. The high conductivity of regular polyaniline, when partially oxidized and doped under acidic conditions, has been associated with the formation of unique electronic states known as polarons and bipolarons. Alternative aniline oxidation products and interesting nanotube and nanorod forms have been observed as the synthesis conditions are varied. Solid-state NMR has offered great opportunities for structural investigations and the determination of molecular dynamics in such a complex and diverse material. This review summarizes various applications of solid-state NMR techniques to polyaniline and its derivatives and the information that can be obtained by solid-state NMR. |
| first_indexed | 2024-12-13T08:42:53Z |
| format | Article |
| id | doaj.art-b55546ffe3dc4e19a6e4ada2b98ca2e7 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-12-13T08:42:53Z |
| publishDate | 2020-01-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-b55546ffe3dc4e19a6e4ada2b98ca2e72022-12-21T23:53:30ZengMDPI AGMolecules1420-30492020-01-0125344410.3390/molecules25030444molecules25030444The Applications of Solid-State NMR to Conducting Polymers. The Special Case on PolyanilineZoran Zujovic0Paul A. Kilmartin1Jadranka Travas-Sejdic2Polymer Electronics Research Centre and the NMR Centre, School of Chemical Sciences, the University of Auckland, Private Bag 92019, Auckland 1010, New ZealandPolymer Electronics Research Centre, School of Chemical Sciences the University of Auckland, Private Bag 92019, Auckland 1010, New ZealandPolymer Electronics Research Centre, School of Chemical Sciences the University of Auckland, Private Bag 92019, Auckland 1010, New ZealandPolyaniline is one of the most well studied conducting polymers due to its advanced electrical, chemical, redox and morphological properties. The high conductivity of regular polyaniline, when partially oxidized and doped under acidic conditions, has been associated with the formation of unique electronic states known as polarons and bipolarons. Alternative aniline oxidation products and interesting nanotube and nanorod forms have been observed as the synthesis conditions are varied. Solid-state NMR has offered great opportunities for structural investigations and the determination of molecular dynamics in such a complex and diverse material. This review summarizes various applications of solid-state NMR techniques to polyaniline and its derivatives and the information that can be obtained by solid-state NMR.https://www.mdpi.com/1420-3049/25/3/444solid-state nmrpolyanilineconducting polymerspolaronsbipolaronsmechanismemeraldine saltconductivity |
| spellingShingle | Zoran Zujovic Paul A. Kilmartin Jadranka Travas-Sejdic The Applications of Solid-State NMR to Conducting Polymers. The Special Case on Polyaniline Molecules solid-state nmr polyaniline conducting polymers polarons bipolarons mechanism emeraldine salt conductivity |
| title | The Applications of Solid-State NMR to Conducting Polymers. The Special Case on Polyaniline |
| title_full | The Applications of Solid-State NMR to Conducting Polymers. The Special Case on Polyaniline |
| title_fullStr | The Applications of Solid-State NMR to Conducting Polymers. The Special Case on Polyaniline |
| title_full_unstemmed | The Applications of Solid-State NMR to Conducting Polymers. The Special Case on Polyaniline |
| title_short | The Applications of Solid-State NMR to Conducting Polymers. The Special Case on Polyaniline |
| title_sort | applications of solid state nmr to conducting polymers the special case on polyaniline |
| topic | solid-state nmr polyaniline conducting polymers polarons bipolarons mechanism emeraldine salt conductivity |
| url | https://www.mdpi.com/1420-3049/25/3/444 |
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