Multi-Scale Analysis of Integrated C<sub>1</sub> (CH<sub>4</sub> and CO<sub>2</sub>) Utilization Catalytic Processes: Impacts of Catalysts Characteristics up to Industrial-Scale Process Flowsheeting, Part II: Techno-Economic Analysis of Integrated C<sub>1</sub> Utilization Process Scenarios
In the second part of this paper (Part II), the potentials and characteristics of an industrial-scale Oxidative Coupling of Methane (OCM) process integrated with CO<sub>2</sub>-hydrogenation, ethane dehydrogenation, and methane reforming processes are highlighted. This novel process conc...
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2020-04-01
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| Series: | Catalysts |
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| Online Access: | https://www.mdpi.com/2073-4344/10/5/488 |
| _version_ | 1797569218161410048 |
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| author | Hamid Reza Godini Mohammadreza Azadi Mohammadali Khadivi Reinhard Schomäcker Fausto Gallucci Günter Wozny Jens-Uwe Repke |
| author_facet | Hamid Reza Godini Mohammadreza Azadi Mohammadali Khadivi Reinhard Schomäcker Fausto Gallucci Günter Wozny Jens-Uwe Repke |
| author_sort | Hamid Reza Godini |
| collection | DOAJ |
| description | In the second part of this paper (Part II), the potentials and characteristics of an industrial-scale Oxidative Coupling of Methane (OCM) process integrated with CO<sub>2</sub>-hydrogenation, ethane dehydrogenation, and methane reforming processes are highlighted. This novel process concept comprises a direct conversion of methane to ethane and ethylene and further conversion of the resulted carbon dioxide and remaining unreacted methane, respectively, to methanol and syngas. In this context, the selected experimental results of the catalytic CO<sub>2</sub>-hydrogenation to methanol reported in the first part of this paper (Part I), were utilized to represent its industrial-scale performance. The experimental results of the mini plant-scale operation of an OCM reactor and CO<sub>2</sub> removal units along with the experimental and industrial data available for representing the operation and performance of all process-units in the integrated process structures were utilized to perform a comparative techno-economic environmental analysis using Aspen-Plus simulation and an Aspen Economic Process Analyzer. The experimental procedure and the results of testing the sequence of OCM and CO<sub>2</sub>-hydrogenation reactors are particularly discussed in this context. It was observed that in the sequential operation of these reactors, ethylene will be also hydrogenated to ethane over the investigated catalysts. Therefore, the parallel-operation of these reactors was found to be a promising alternative in such an integrated process. The main assumptions and the conceptual conclusions made in this analysis are reviewed and discussed in this paper in the light of the practical limitations encountered in the experimentations. In the context of a multi-scale analysis, the contributions of the design and operating parameters in the scale of catalyst and reactor as well as in the process-scale represented by analyzing the type and operating conditions of the downstream-units and the process-flowsheets on the economic and environmental performance of the integrated process structures were studied. Moreover, the economic impacts of extra ethylene and methanol produced respectively via the integrated ethane dehydrogenation and CO<sub>2</sub>-hydrogenation sections were analyzed in detail. The required capital investment was found to be even smaller than the yearly operating cost of the plant. The environmental impacts and sustainability of the integrated OCM process were found to be enhanced by securing a minimum direct CO<sub>2</sub>-emission and energy-efficient conversion of CO<sub>2</sub> and the unreacted CH<sub>4</sub>, respectively, to methanol and syngas. Besides producing such value-added by-products, efficient operation of downstream process-units was secured by minimizing the energy usage and ethylene losses. Under the considered conditions in this analysis, the specifications of the finally selected integrated OCM process structure, providing the fastest return of investments (less than 8 years), are highlighted. |
| first_indexed | 2024-03-10T20:07:46Z |
| format | Article |
| id | doaj.art-b561b99a183f4edd9a2b47e1fba9cd8a |
| institution | Directory Open Access Journal |
| issn | 2073-4344 |
| language | English |
| last_indexed | 2024-03-10T20:07:46Z |
| publishDate | 2020-04-01 |
| publisher | MDPI AG |
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| series | Catalysts |
| spelling | doaj.art-b561b99a183f4edd9a2b47e1fba9cd8a2023-11-19T23:10:16ZengMDPI AGCatalysts2073-43442020-04-0110548810.3390/catal10050488Multi-Scale Analysis of Integrated C<sub>1</sub> (CH<sub>4</sub> and CO<sub>2</sub>) Utilization Catalytic Processes: Impacts of Catalysts Characteristics up to Industrial-Scale Process Flowsheeting, Part II: Techno-Economic Analysis of Integrated C<sub>1</sub> Utilization Process ScenariosHamid Reza Godini0Mohammadreza Azadi1Mohammadali Khadivi2Reinhard Schomäcker3Fausto Gallucci4Günter Wozny5Jens-Uwe Repke6Process Dynamics and Operation, Technische Universität Berlin, Straße des 17. Juni 135, Sekr. KWT-9, D-10623 Berlin, GermanyProcess Dynamics and Operation, Technische Universität Berlin, Straße des 17. Juni 135, Sekr. KWT-9, D-10623 Berlin, GermanyProcess Dynamics and Operation, Technische Universität Berlin, Straße des 17. Juni 135, Sekr. KWT-9, D-10623 Berlin, GermanyDepartment of Chemistry, Technische Universität Berlin, Straße des 17. Juni 124, D-10623 Berlin, GermanyInorganic Membranes and Membrane Reactors, Department of Chemical Engineering and Chemistry, Eindhoven University of Technology (TU/e), Den Dolech 2, 5612AD Eindhoven, The NetherlandsProcess Dynamics and Operation, Technische Universität Berlin, Straße des 17. Juni 135, Sekr. KWT-9, D-10623 Berlin, GermanyProcess Dynamics and Operation, Technische Universität Berlin, Straße des 17. Juni 135, Sekr. KWT-9, D-10623 Berlin, GermanyIn the second part of this paper (Part II), the potentials and characteristics of an industrial-scale Oxidative Coupling of Methane (OCM) process integrated with CO<sub>2</sub>-hydrogenation, ethane dehydrogenation, and methane reforming processes are highlighted. This novel process concept comprises a direct conversion of methane to ethane and ethylene and further conversion of the resulted carbon dioxide and remaining unreacted methane, respectively, to methanol and syngas. In this context, the selected experimental results of the catalytic CO<sub>2</sub>-hydrogenation to methanol reported in the first part of this paper (Part I), were utilized to represent its industrial-scale performance. The experimental results of the mini plant-scale operation of an OCM reactor and CO<sub>2</sub> removal units along with the experimental and industrial data available for representing the operation and performance of all process-units in the integrated process structures were utilized to perform a comparative techno-economic environmental analysis using Aspen-Plus simulation and an Aspen Economic Process Analyzer. The experimental procedure and the results of testing the sequence of OCM and CO<sub>2</sub>-hydrogenation reactors are particularly discussed in this context. It was observed that in the sequential operation of these reactors, ethylene will be also hydrogenated to ethane over the investigated catalysts. Therefore, the parallel-operation of these reactors was found to be a promising alternative in such an integrated process. The main assumptions and the conceptual conclusions made in this analysis are reviewed and discussed in this paper in the light of the practical limitations encountered in the experimentations. In the context of a multi-scale analysis, the contributions of the design and operating parameters in the scale of catalyst and reactor as well as in the process-scale represented by analyzing the type and operating conditions of the downstream-units and the process-flowsheets on the economic and environmental performance of the integrated process structures were studied. Moreover, the economic impacts of extra ethylene and methanol produced respectively via the integrated ethane dehydrogenation and CO<sub>2</sub>-hydrogenation sections were analyzed in detail. The required capital investment was found to be even smaller than the yearly operating cost of the plant. The environmental impacts and sustainability of the integrated OCM process were found to be enhanced by securing a minimum direct CO<sub>2</sub>-emission and energy-efficient conversion of CO<sub>2</sub> and the unreacted CH<sub>4</sub>, respectively, to methanol and syngas. Besides producing such value-added by-products, efficient operation of downstream process-units was secured by minimizing the energy usage and ethylene losses. Under the considered conditions in this analysis, the specifications of the finally selected integrated OCM process structure, providing the fastest return of investments (less than 8 years), are highlighted.https://www.mdpi.com/2073-4344/10/5/488oxidative coupling of methane (OCM) processCO<sub>2</sub>-hydrogenation to methanolmulti-scale analysistechno-economic analysisethane dehydrogenationdownstream units |
| spellingShingle | Hamid Reza Godini Mohammadreza Azadi Mohammadali Khadivi Reinhard Schomäcker Fausto Gallucci Günter Wozny Jens-Uwe Repke Multi-Scale Analysis of Integrated C<sub>1</sub> (CH<sub>4</sub> and CO<sub>2</sub>) Utilization Catalytic Processes: Impacts of Catalysts Characteristics up to Industrial-Scale Process Flowsheeting, Part II: Techno-Economic Analysis of Integrated C<sub>1</sub> Utilization Process Scenarios Catalysts oxidative coupling of methane (OCM) process CO<sub>2</sub>-hydrogenation to methanol multi-scale analysis techno-economic analysis ethane dehydrogenation downstream units |
| title | Multi-Scale Analysis of Integrated C<sub>1</sub> (CH<sub>4</sub> and CO<sub>2</sub>) Utilization Catalytic Processes: Impacts of Catalysts Characteristics up to Industrial-Scale Process Flowsheeting, Part II: Techno-Economic Analysis of Integrated C<sub>1</sub> Utilization Process Scenarios |
| title_full | Multi-Scale Analysis of Integrated C<sub>1</sub> (CH<sub>4</sub> and CO<sub>2</sub>) Utilization Catalytic Processes: Impacts of Catalysts Characteristics up to Industrial-Scale Process Flowsheeting, Part II: Techno-Economic Analysis of Integrated C<sub>1</sub> Utilization Process Scenarios |
| title_fullStr | Multi-Scale Analysis of Integrated C<sub>1</sub> (CH<sub>4</sub> and CO<sub>2</sub>) Utilization Catalytic Processes: Impacts of Catalysts Characteristics up to Industrial-Scale Process Flowsheeting, Part II: Techno-Economic Analysis of Integrated C<sub>1</sub> Utilization Process Scenarios |
| title_full_unstemmed | Multi-Scale Analysis of Integrated C<sub>1</sub> (CH<sub>4</sub> and CO<sub>2</sub>) Utilization Catalytic Processes: Impacts of Catalysts Characteristics up to Industrial-Scale Process Flowsheeting, Part II: Techno-Economic Analysis of Integrated C<sub>1</sub> Utilization Process Scenarios |
| title_short | Multi-Scale Analysis of Integrated C<sub>1</sub> (CH<sub>4</sub> and CO<sub>2</sub>) Utilization Catalytic Processes: Impacts of Catalysts Characteristics up to Industrial-Scale Process Flowsheeting, Part II: Techno-Economic Analysis of Integrated C<sub>1</sub> Utilization Process Scenarios |
| title_sort | multi scale analysis of integrated c sub 1 sub ch sub 4 sub and co sub 2 sub utilization catalytic processes impacts of catalysts characteristics up to industrial scale process flowsheeting part ii techno economic analysis of integrated c sub 1 sub utilization process scenarios |
| topic | oxidative coupling of methane (OCM) process CO<sub>2</sub>-hydrogenation to methanol multi-scale analysis techno-economic analysis ethane dehydrogenation downstream units |
| url | https://www.mdpi.com/2073-4344/10/5/488 |
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