Comparison of Performance between Single- and Multiparameter Luminescence Thermometry Methods Based on the Mn<sup>5+</sup> Near-Infrared Emission
Herein, we investigate the performance of single- and multiparametric luminescence thermometry founded on the temperature-dependent spectral features of Ca<sub>6</sub>BaP<sub>4</sub>O<sub>17</sub>:Mn<sup>5+</sup> near-infrared emission. The material wa...
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MDPI AG
2023-04-01
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| Online Access: | https://www.mdpi.com/1424-8220/23/8/3839 |
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| author | Tahani A. Alrebdi Abdullah N. Alodhayb Zoran Ristić Miroslav D. Dramićanin |
| author_facet | Tahani A. Alrebdi Abdullah N. Alodhayb Zoran Ristić Miroslav D. Dramićanin |
| author_sort | Tahani A. Alrebdi |
| collection | DOAJ |
| description | Herein, we investigate the performance of single- and multiparametric luminescence thermometry founded on the temperature-dependent spectral features of Ca<sub>6</sub>BaP<sub>4</sub>O<sub>17</sub>:Mn<sup>5+</sup> near-infrared emission. The material was prepared by a conventional steady-state synthesis, and its photoluminescence emission was measured from 7500 to 10,000 cm<sup>−1</sup> over the 293–373 K temperature range in 5 K increments. The spectra are composed of the emissions from <sup>1</sup>E → <sup>3</sup>A<sub>2</sub> and <sup>3</sup>T<sub>2</sub> → <sup>3</sup>A<sub>2</sub> electronic transitions and Stokes and anti-Stokes vibronic sidebands at 320 cm<sup>−1</sup> and 800 cm<sup>−1</sup> from the maximum of <sup>1</sup>E → <sup>3</sup>A<sub>2</sub> emission. Upon temperature increase, the <sup>3</sup>T<sub>2</sub> and Stokes bands gained in intensity while the maximum of <sup>1</sup>E emission band is redshifted. We introduced the procedure for the linearization and feature scaling of input variables for linear multiparametric regression. Then, we experimentally determined accuracies and precisions of the luminescence thermometry based on luminescence intensity ratios between emissions from the <sup>1</sup>E and <sup>3</sup>T<sub>2</sub> states, between Stokes and anti-Stokes emission sidebands, and at the <sup>1</sup>E energy maximum. The multiparametric luminescence thermometry involving the same spectral features showed similar performance, comparable to the best single-parameter thermometry. |
| first_indexed | 2024-03-11T04:34:20Z |
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| language | English |
| last_indexed | 2024-03-11T04:34:20Z |
| publishDate | 2023-04-01 |
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| series | Sensors |
| spelling | doaj.art-b56d9272b06b45ffb19540374ab4051d2023-11-17T21:15:19ZengMDPI AGSensors1424-82202023-04-01238383910.3390/s23083839Comparison of Performance between Single- and Multiparameter Luminescence Thermometry Methods Based on the Mn<sup>5+</sup> Near-Infrared EmissionTahani A. Alrebdi0Abdullah N. Alodhayb1Zoran Ristić2Miroslav D. Dramićanin3Department of Physics, College of Science, Princess Nourah Bint Abdulrahman University, P.O. Box 84428, Riyadh 11671, Saudi ArabiaDepartment of Physics and Astronomy, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi ArabiaCentre of Excellence for Photoconversion, Vinča Insitute of Nuclear Sciences—National Institute of the Republic of Serbia, University of Belgrade, P.O. Box 522, 11001 Belgrade, SerbiaCentre of Excellence for Photoconversion, Vinča Insitute of Nuclear Sciences—National Institute of the Republic of Serbia, University of Belgrade, P.O. Box 522, 11001 Belgrade, SerbiaHerein, we investigate the performance of single- and multiparametric luminescence thermometry founded on the temperature-dependent spectral features of Ca<sub>6</sub>BaP<sub>4</sub>O<sub>17</sub>:Mn<sup>5+</sup> near-infrared emission. The material was prepared by a conventional steady-state synthesis, and its photoluminescence emission was measured from 7500 to 10,000 cm<sup>−1</sup> over the 293–373 K temperature range in 5 K increments. The spectra are composed of the emissions from <sup>1</sup>E → <sup>3</sup>A<sub>2</sub> and <sup>3</sup>T<sub>2</sub> → <sup>3</sup>A<sub>2</sub> electronic transitions and Stokes and anti-Stokes vibronic sidebands at 320 cm<sup>−1</sup> and 800 cm<sup>−1</sup> from the maximum of <sup>1</sup>E → <sup>3</sup>A<sub>2</sub> emission. Upon temperature increase, the <sup>3</sup>T<sub>2</sub> and Stokes bands gained in intensity while the maximum of <sup>1</sup>E emission band is redshifted. We introduced the procedure for the linearization and feature scaling of input variables for linear multiparametric regression. Then, we experimentally determined accuracies and precisions of the luminescence thermometry based on luminescence intensity ratios between emissions from the <sup>1</sup>E and <sup>3</sup>T<sub>2</sub> states, between Stokes and anti-Stokes emission sidebands, and at the <sup>1</sup>E energy maximum. The multiparametric luminescence thermometry involving the same spectral features showed similar performance, comparable to the best single-parameter thermometry.https://www.mdpi.com/1424-8220/23/8/3839luminescence thermometryluminescent materialsMn<sup>5+</sup>near-infrared luminescence |
| spellingShingle | Tahani A. Alrebdi Abdullah N. Alodhayb Zoran Ristić Miroslav D. Dramićanin Comparison of Performance between Single- and Multiparameter Luminescence Thermometry Methods Based on the Mn<sup>5+</sup> Near-Infrared Emission Sensors luminescence thermometry luminescent materials Mn<sup>5+</sup> near-infrared luminescence |
| title | Comparison of Performance between Single- and Multiparameter Luminescence Thermometry Methods Based on the Mn<sup>5+</sup> Near-Infrared Emission |
| title_full | Comparison of Performance between Single- and Multiparameter Luminescence Thermometry Methods Based on the Mn<sup>5+</sup> Near-Infrared Emission |
| title_fullStr | Comparison of Performance between Single- and Multiparameter Luminescence Thermometry Methods Based on the Mn<sup>5+</sup> Near-Infrared Emission |
| title_full_unstemmed | Comparison of Performance between Single- and Multiparameter Luminescence Thermometry Methods Based on the Mn<sup>5+</sup> Near-Infrared Emission |
| title_short | Comparison of Performance between Single- and Multiparameter Luminescence Thermometry Methods Based on the Mn<sup>5+</sup> Near-Infrared Emission |
| title_sort | comparison of performance between single and multiparameter luminescence thermometry methods based on the mn sup 5 sup near infrared emission |
| topic | luminescence thermometry luminescent materials Mn<sup>5+</sup> near-infrared luminescence |
| url | https://www.mdpi.com/1424-8220/23/8/3839 |
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