An Electrochemical Study of the S-Derivatives of 2-Amino Cyclopentene-1-Dithiocharboxylic Acid in Aqueous Ethanolic Media
A systematic study on the electrochemical behavior of the S-derivatives of 2-amino cyclopentene-1-dithiocarboxylic acid (ACDA) has been carried out in aqueous ethanolic solutions by means of polarography, coulometry and voltammetry. All the compounds studied exhibited a well defined anodic wave corr...
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| Format: | Article |
| Language: | English |
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Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR
1997-06-01
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| Series: | Iranian Journal of Chemistry & Chemical Engineering |
| Subjects: | |
| Online Access: | http://www.ijcce.ac.ir/article_10327_31c2acc3b46392a5193108005dc8d22d.pdf |
| _version_ | 1818834794370301952 |
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| author | Afsaneh Safavi Mohammad Bagher Golivand |
| author_facet | Afsaneh Safavi Mohammad Bagher Golivand |
| author_sort | Afsaneh Safavi |
| collection | DOAJ |
| description | A systematic study on the electrochemical behavior of the S-derivatives of 2-amino cyclopentene-1-dithiocarboxylic acid (ACDA) has been carried out in aqueous ethanolic solutions by means of polarography, coulometry and voltammetry. All the compounds studied exhibited a well defined anodic wave corresponding to a diffusion controlled process. Controlled potential coulometry gave n=1 per mole for the anodic waves of the S-methyl and N-methyl S-methyl derivatives of ACDA, while for the dimer of ACDA a two electron oxidation wave was obtained. |
| first_indexed | 2024-12-19T02:40:29Z |
| format | Article |
| id | doaj.art-b5741c3592a2473c871cb4d9b888a35b |
| institution | Directory Open Access Journal |
| issn | 1021-9986 1021-9986 |
| language | English |
| last_indexed | 2024-12-19T02:40:29Z |
| publishDate | 1997-06-01 |
| publisher | Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR |
| record_format | Article |
| series | Iranian Journal of Chemistry & Chemical Engineering |
| spelling | doaj.art-b5741c3592a2473c871cb4d9b888a35b2022-12-21T20:39:08ZengIranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECRIranian Journal of Chemistry & Chemical Engineering1021-99861021-99861997-06-01161151810327An Electrochemical Study of the S-Derivatives of 2-Amino Cyclopentene-1-Dithiocharboxylic Acid in Aqueous Ethanolic MediaAfsaneh Safavi0Mohammad Bagher Golivand1Department of Chemistry, Faculty of Science, Shiraz University, Zip code 71454, Shiraz, I.R. IRANDepartment of Chemistry, Faculty of Science, Shiraz University, Zip code 71454, Shiraz, I.R. IRANA systematic study on the electrochemical behavior of the S-derivatives of 2-amino cyclopentene-1-dithiocarboxylic acid (ACDA) has been carried out in aqueous ethanolic solutions by means of polarography, coulometry and voltammetry. All the compounds studied exhibited a well defined anodic wave corresponding to a diffusion controlled process. Controlled potential coulometry gave n=1 per mole for the anodic waves of the S-methyl and N-methyl S-methyl derivatives of ACDA, while for the dimer of ACDA a two electron oxidation wave was obtained.http://www.ijcce.ac.ir/article_10327_31c2acc3b46392a5193108005dc8d22d.pdfelectrochemical studydithiocarboxylic acid derivativesaqueous ethanolic media |
| spellingShingle | Afsaneh Safavi Mohammad Bagher Golivand An Electrochemical Study of the S-Derivatives of 2-Amino Cyclopentene-1-Dithiocharboxylic Acid in Aqueous Ethanolic Media Iranian Journal of Chemistry & Chemical Engineering electrochemical study dithiocarboxylic acid derivatives aqueous ethanolic media |
| title | An Electrochemical Study of the S-Derivatives of 2-Amino Cyclopentene-1-Dithiocharboxylic Acid in Aqueous Ethanolic Media |
| title_full | An Electrochemical Study of the S-Derivatives of 2-Amino Cyclopentene-1-Dithiocharboxylic Acid in Aqueous Ethanolic Media |
| title_fullStr | An Electrochemical Study of the S-Derivatives of 2-Amino Cyclopentene-1-Dithiocharboxylic Acid in Aqueous Ethanolic Media |
| title_full_unstemmed | An Electrochemical Study of the S-Derivatives of 2-Amino Cyclopentene-1-Dithiocharboxylic Acid in Aqueous Ethanolic Media |
| title_short | An Electrochemical Study of the S-Derivatives of 2-Amino Cyclopentene-1-Dithiocharboxylic Acid in Aqueous Ethanolic Media |
| title_sort | electrochemical study of the s derivatives of 2 amino cyclopentene 1 dithiocharboxylic acid in aqueous ethanolic media |
| topic | electrochemical study dithiocarboxylic acid derivatives aqueous ethanolic media |
| url | http://www.ijcce.ac.ir/article_10327_31c2acc3b46392a5193108005dc8d22d.pdf |
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