A one-dimensional copper(II) phenylenediphosphonate: catena-poly[[(1,10-phenanthroline-κ2N,N′)copper(II)]-μ3-[m-phenylenediphosphonato-κ3O:O′:O′′]]
The title compound, [Cu(1,3-HO3PC6H4PO3H)(C12H8N2)]n, is a coordination polymer of the metal–diphosphonate family. The chain structure is constructed from `4+1' square-pyramidally coordinated copper(II) atoms bonded to chelating phenanthroline (phen) ligands and linked through 1,3...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810037359 |
| _version_ | 1818894112249610240 |
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| author | Jon Zubieta Paul DeBurgomaster |
| author_facet | Jon Zubieta Paul DeBurgomaster |
| author_sort | Jon Zubieta |
| collection | DOAJ |
| description | The title compound, [Cu(1,3-HO3PC6H4PO3H)(C12H8N2)]n, is a coordination polymer of the metal–diphosphonate family. The chain structure is constructed from `4+1' square-pyramidally coordinated copper(II) atoms bonded to chelating phenanthroline (phen) ligands and linked through 1,3-phenyldihydrogendiphosphonate ligands. The basal plane of the Cu(II) site is defined by the phen nitrogen donors and phosphonate oxygen atoms from two diphosphonate ligands, while the apical position is occupied by an oxygen donor from a third diphosphonate ligand. The chains propagate along the a-axis direction. Inversion-related phen groups engage in π-π stacking with a mean distance of 3.376 (2) Å between the ring planes. O—H...O hydrogen-bonding interactions between the protonated {P—OH} groups of one chain and the {P=O} groups of adjacent chains stabilize the crystal packing. |
| first_indexed | 2024-12-19T18:23:19Z |
| format | Article |
| id | doaj.art-b577e4be56e8447997b322655e15f3b3 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T18:23:19Z |
| publishDate | 2010-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-b577e4be56e8447997b322655e15f3b32022-12-21T20:10:54ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-10-016610m1304m130510.1107/S1600536810037359A one-dimensional copper(II) phenylenediphosphonate: catena-poly[[(1,10-phenanthroline-κ2N,N′)copper(II)]-μ3-[m-phenylenediphosphonato-κ3O:O′:O′′]]Jon ZubietaPaul DeBurgomasterThe title compound, [Cu(1,3-HO3PC6H4PO3H)(C12H8N2)]n, is a coordination polymer of the metal–diphosphonate family. The chain structure is constructed from `4+1' square-pyramidally coordinated copper(II) atoms bonded to chelating phenanthroline (phen) ligands and linked through 1,3-phenyldihydrogendiphosphonate ligands. The basal plane of the Cu(II) site is defined by the phen nitrogen donors and phosphonate oxygen atoms from two diphosphonate ligands, while the apical position is occupied by an oxygen donor from a third diphosphonate ligand. The chains propagate along the a-axis direction. Inversion-related phen groups engage in π-π stacking with a mean distance of 3.376 (2) Å between the ring planes. O—H...O hydrogen-bonding interactions between the protonated {P—OH} groups of one chain and the {P=O} groups of adjacent chains stabilize the crystal packing.http://scripts.iucr.org/cgi-bin/paper?S1600536810037359 |
| spellingShingle | Jon Zubieta Paul DeBurgomaster A one-dimensional copper(II) phenylenediphosphonate: catena-poly[[(1,10-phenanthroline-κ2N,N′)copper(II)]-μ3-[m-phenylenediphosphonato-κ3O:O′:O′′]] Acta Crystallographica Section E |
| title | A one-dimensional copper(II) phenylenediphosphonate: catena-poly[[(1,10-phenanthroline-κ2N,N′)copper(II)]-μ3-[m-phenylenediphosphonato-κ3O:O′:O′′]] |
| title_full | A one-dimensional copper(II) phenylenediphosphonate: catena-poly[[(1,10-phenanthroline-κ2N,N′)copper(II)]-μ3-[m-phenylenediphosphonato-κ3O:O′:O′′]] |
| title_fullStr | A one-dimensional copper(II) phenylenediphosphonate: catena-poly[[(1,10-phenanthroline-κ2N,N′)copper(II)]-μ3-[m-phenylenediphosphonato-κ3O:O′:O′′]] |
| title_full_unstemmed | A one-dimensional copper(II) phenylenediphosphonate: catena-poly[[(1,10-phenanthroline-κ2N,N′)copper(II)]-μ3-[m-phenylenediphosphonato-κ3O:O′:O′′]] |
| title_short | A one-dimensional copper(II) phenylenediphosphonate: catena-poly[[(1,10-phenanthroline-κ2N,N′)copper(II)]-μ3-[m-phenylenediphosphonato-κ3O:O′:O′′]] |
| title_sort | one dimensional copper ii phenylenediphosphonate catena poly 1 10 phenanthroline amp 954 2n n amp 8242 copper ii amp 956 3 m phenylenediphosphonato amp 954 3o o amp 8242 o amp 8242 amp 8242 |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810037359 |
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