Análise de compostos sulfurados em efluentes gasosos de refinaria de petróleo Analysis of sulfur compounds in petroleum refinery gaseous effluents

<abstract language="eng">This work discusses an analytical procedure for analysis of sulfur compounds in treated petroleum refinery gaseous effluents using a sulfur chemiluminescence detector with dual plasma burner (SCD-DP). Calibration was accomplished by using standards and gaseou...

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Main Authors: Júlio Carlos Afonso, Kátia da Silva Pereira
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2010-01-01
Series:Química Nova
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422010000400035
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author Júlio Carlos Afonso
Kátia da Silva Pereira
author_facet Júlio Carlos Afonso
Kátia da Silva Pereira
author_sort Júlio Carlos Afonso
collection DOAJ
description <abstract language="eng">This work discusses an analytical procedure for analysis of sulfur compounds in treated petroleum refinery gaseous effluents using a sulfur chemiluminescence detector with dual plasma burner (SCD-DP). Calibration was accomplished by using standards and gaseous streams of known concentration of sulfur compounds. The response factors agree with the calibration table of ASTM standard D 5504 (2008). The detection range for sulfur compounds is in &#956;g m-3. The analytical procedure allowed the construction of a chromatographic chart of sulfur compounds present in several refinery gaseous effluents. SO2 was the most difficult compound to be determined because of its high reactivity.
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spelling doaj.art-b587e688a07047349450a271e4f963752022-12-21T19:52:05ZengSociedade Brasileira de QuímicaQuímica Nova0100-40421678-70642010-01-0133495796310.1590/S0100-40422010000400035Análise de compostos sulfurados em efluentes gasosos de refinaria de petróleo Analysis of sulfur compounds in petroleum refinery gaseous effluentsJúlio Carlos AfonsoKátia da Silva Pereira<abstract language="eng">This work discusses an analytical procedure for analysis of sulfur compounds in treated petroleum refinery gaseous effluents using a sulfur chemiluminescence detector with dual plasma burner (SCD-DP). Calibration was accomplished by using standards and gaseous streams of known concentration of sulfur compounds. The response factors agree with the calibration table of ASTM standard D 5504 (2008). The detection range for sulfur compounds is in &#956;g m-3. The analytical procedure allowed the construction of a chromatographic chart of sulfur compounds present in several refinery gaseous effluents. SO2 was the most difficult compound to be determined because of its high reactivity.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422010000400035sulfur compoundschemiluminescencegaseous effluents
spellingShingle Júlio Carlos Afonso
Kátia da Silva Pereira
Análise de compostos sulfurados em efluentes gasosos de refinaria de petróleo Analysis of sulfur compounds in petroleum refinery gaseous effluents
Química Nova
sulfur compounds
chemiluminescence
gaseous effluents
title Análise de compostos sulfurados em efluentes gasosos de refinaria de petróleo Analysis of sulfur compounds in petroleum refinery gaseous effluents
title_full Análise de compostos sulfurados em efluentes gasosos de refinaria de petróleo Analysis of sulfur compounds in petroleum refinery gaseous effluents
title_fullStr Análise de compostos sulfurados em efluentes gasosos de refinaria de petróleo Analysis of sulfur compounds in petroleum refinery gaseous effluents
title_full_unstemmed Análise de compostos sulfurados em efluentes gasosos de refinaria de petróleo Analysis of sulfur compounds in petroleum refinery gaseous effluents
title_short Análise de compostos sulfurados em efluentes gasosos de refinaria de petróleo Analysis of sulfur compounds in petroleum refinery gaseous effluents
title_sort analise de compostos sulfurados em efluentes gasosos de refinaria de petroleo analysis of sulfur compounds in petroleum refinery gaseous effluents
topic sulfur compounds
chemiluminescence
gaseous effluents
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422010000400035
work_keys_str_mv AT juliocarlosafonso analisedecompostossulfuradosemefluentesgasososderefinariadepetroleoanalysisofsulfurcompoundsinpetroleumrefinerygaseouseffluents
AT katiadasilvapereira analisedecompostossulfuradosemefluentesgasososderefinariadepetroleoanalysisofsulfurcompoundsinpetroleumrefinerygaseouseffluents