Design of an open-shell nitrogen-centered diradicaloid with tunable stimuli-responsive electronic properties
The electronic structures and open-shell diradical character of organic diradicaloids endow them with potentially useful optical, electronic and magnetic properties. Here, an open-shell nitrogen-centered diradicaloid is reported and shown to readily react with Lewis and Brønsted acids to form acid-b...
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2022-10-01
|
| Series: | Communications Chemistry |
| Online Access: | https://doi.org/10.1038/s42004-022-00747-8 |
| _version_ | 1828723305968828416 |
|---|---|
| author | Bin Huang Hao Kang Chang-Wei Zhang Xiao-Li Zhao Xueliang Shi Hai-Bo Yang |
| author_facet | Bin Huang Hao Kang Chang-Wei Zhang Xiao-Li Zhao Xueliang Shi Hai-Bo Yang |
| author_sort | Bin Huang |
| collection | DOAJ |
| description | The electronic structures and open-shell diradical character of organic diradicaloids endow them with potentially useful optical, electronic and magnetic properties. Here, an open-shell nitrogen-centered diradicaloid is reported and shown to readily react with Lewis and Brønsted acids to form acid-base adducts, allowing for tuning of ground-state electronic structure, diradical character and spin density distribution. |
| first_indexed | 2024-04-12T12:47:33Z |
| format | Article |
| id | doaj.art-b58f7a1f01e747f08218b2fa05c722c9 |
| institution | Directory Open Access Journal |
| issn | 2399-3669 |
| language | English |
| last_indexed | 2024-04-12T12:47:33Z |
| publishDate | 2022-10-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Communications Chemistry |
| spelling | doaj.art-b58f7a1f01e747f08218b2fa05c722c92022-12-22T03:32:34ZengNature PortfolioCommunications Chemistry2399-36692022-10-015111110.1038/s42004-022-00747-8Design of an open-shell nitrogen-centered diradicaloid with tunable stimuli-responsive electronic propertiesBin Huang0Hao Kang1Chang-Wei Zhang2Xiao-Li Zhao3Xueliang Shi4Hai-Bo Yang5Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal UniversityShanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal UniversityShanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal UniversityShanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal UniversityShanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal UniversityShanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal UniversityThe electronic structures and open-shell diradical character of organic diradicaloids endow them with potentially useful optical, electronic and magnetic properties. Here, an open-shell nitrogen-centered diradicaloid is reported and shown to readily react with Lewis and Brønsted acids to form acid-base adducts, allowing for tuning of ground-state electronic structure, diradical character and spin density distribution.https://doi.org/10.1038/s42004-022-00747-8 |
| spellingShingle | Bin Huang Hao Kang Chang-Wei Zhang Xiao-Li Zhao Xueliang Shi Hai-Bo Yang Design of an open-shell nitrogen-centered diradicaloid with tunable stimuli-responsive electronic properties Communications Chemistry |
| title | Design of an open-shell nitrogen-centered diradicaloid with tunable stimuli-responsive electronic properties |
| title_full | Design of an open-shell nitrogen-centered diradicaloid with tunable stimuli-responsive electronic properties |
| title_fullStr | Design of an open-shell nitrogen-centered diradicaloid with tunable stimuli-responsive electronic properties |
| title_full_unstemmed | Design of an open-shell nitrogen-centered diradicaloid with tunable stimuli-responsive electronic properties |
| title_short | Design of an open-shell nitrogen-centered diradicaloid with tunable stimuli-responsive electronic properties |
| title_sort | design of an open shell nitrogen centered diradicaloid with tunable stimuli responsive electronic properties |
| url | https://doi.org/10.1038/s42004-022-00747-8 |
| work_keys_str_mv | AT binhuang designofanopenshellnitrogencentereddiradicaloidwithtunablestimuliresponsiveelectronicproperties AT haokang designofanopenshellnitrogencentereddiradicaloidwithtunablestimuliresponsiveelectronicproperties AT changweizhang designofanopenshellnitrogencentereddiradicaloidwithtunablestimuliresponsiveelectronicproperties AT xiaolizhao designofanopenshellnitrogencentereddiradicaloidwithtunablestimuliresponsiveelectronicproperties AT xueliangshi designofanopenshellnitrogencentereddiradicaloidwithtunablestimuliresponsiveelectronicproperties AT haiboyang designofanopenshellnitrogencentereddiradicaloidwithtunablestimuliresponsiveelectronicproperties |