Tetracarbonyldi-μ-chlorido-dichloridobis(η5-cyclopentadienyl)diirondigallium(2 Fe—Ga)
The title compound, [Fe2Ga2(C5H5)2Cl4(CO)4], has an iron–gallium bond distance of 2.3028 (3) Å. The gallium atoms are connected by two bridging chlorine atoms, each gallium also has one terminal chlorine. The molecule has an inversion center located between the gallium atoms. The cyclopentadienyl li...
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Format: | Article |
Language: | English |
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International Union of Crystallography
2022-08-01
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Series: | IUCrData |
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Online Access: | http://scripts.iucr.org/cgi-bin/paper?S241431462200832X |
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author | George N. Harakas Mary Elizabeth Demmin |
author_facet | George N. Harakas Mary Elizabeth Demmin |
author_sort | George N. Harakas |
collection | DOAJ |
description | The title compound, [Fe2Ga2(C5H5)2Cl4(CO)4], has an iron–gallium bond distance of 2.3028 (3) Å. The gallium atoms are connected by two bridging chlorine atoms, each gallium also has one terminal chlorine. The molecule has an inversion center located between the gallium atoms. The cyclopentadienyl ligand is disordered over two sites with an occupancy of 0.57 (2) for the major occupied site. |
first_indexed | 2024-04-11T12:19:40Z |
format | Article |
id | doaj.art-b5c169af12df491caba540e5620249a6 |
institution | Directory Open Access Journal |
issn | 2414-3146 |
language | English |
last_indexed | 2024-04-11T12:19:40Z |
publishDate | 2022-08-01 |
publisher | International Union of Crystallography |
record_format | Article |
series | IUCrData |
spelling | doaj.art-b5c169af12df491caba540e5620249a62022-12-22T04:24:07ZengInternational Union of CrystallographyIUCrData2414-31462022-08-0178x22083210.1107/S241431462200832Xbt4125Tetracarbonyldi-μ-chlorido-dichloridobis(η5-cyclopentadienyl)diirondigallium(2 Fe—Ga)George N. Harakas0Mary Elizabeth Demmin1PO Box 6949, Radford University, Radford, Virginia 24142, USAPO Box 6949, Radford University, Radford, Virginia 24142, USAThe title compound, [Fe2Ga2(C5H5)2Cl4(CO)4], has an iron–gallium bond distance of 2.3028 (3) Å. The gallium atoms are connected by two bridging chlorine atoms, each gallium also has one terminal chlorine. The molecule has an inversion center located between the gallium atoms. The cyclopentadienyl ligand is disordered over two sites with an occupancy of 0.57 (2) for the major occupied site.http://scripts.iucr.org/cgi-bin/paper?S241431462200832Xcrystal structureirongallium |
spellingShingle | George N. Harakas Mary Elizabeth Demmin Tetracarbonyldi-μ-chlorido-dichloridobis(η5-cyclopentadienyl)diirondigallium(2 Fe—Ga) IUCrData crystal structure iron gallium |
title | Tetracarbonyldi-μ-chlorido-dichloridobis(η5-cyclopentadienyl)diirondigallium(2 Fe—Ga) |
title_full | Tetracarbonyldi-μ-chlorido-dichloridobis(η5-cyclopentadienyl)diirondigallium(2 Fe—Ga) |
title_fullStr | Tetracarbonyldi-μ-chlorido-dichloridobis(η5-cyclopentadienyl)diirondigallium(2 Fe—Ga) |
title_full_unstemmed | Tetracarbonyldi-μ-chlorido-dichloridobis(η5-cyclopentadienyl)diirondigallium(2 Fe—Ga) |
title_short | Tetracarbonyldi-μ-chlorido-dichloridobis(η5-cyclopentadienyl)diirondigallium(2 Fe—Ga) |
title_sort | tetracarbonyldi μ chlorido dichloridobis η5 cyclopentadienyl diirondigallium 2 fe ga |
topic | crystal structure iron gallium |
url | http://scripts.iucr.org/cgi-bin/paper?S241431462200832X |
work_keys_str_mv | AT georgenharakas tetracarbonyldimchloridodichloridobisē5cyclopentadienyldiirondigallium2fega AT maryelizabethdemmin tetracarbonyldimchloridodichloridobisē5cyclopentadienyldiirondigallium2fega |