Synthesis and Microstructural Investigations of Organometallic Pd(II) Thiol-Gold Nanoparticles Hybrids
<p>Abstract</p> <p>In this work the synthesis and characterization of gold nanoparticles functionalized by a novel thiol-organometallic complex containing Pd(II) centers is presented. Pd(II) thiol,<it>trans, trans</it>-[dithiolate-dibis(tributylphosphine)dipalladium(II)...
| Main Authors: | , , , , , , , , , , |
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| Format: | Article |
| Language: | English |
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SpringerOpen
2008-01-01
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| Series: | Nanoscale Research Letters |
| Subjects: | |
| Online Access: | http://dx.doi.org/10.1007/s11671-008-9181-x |
| _version_ | 1797760307965198336 |
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| author | Cervellino Antonio Vitaliano Rosa Fratoddi Ilaria Russo MariaVittoria Giannini Cinzia Guagliardi Antonella Battocchio Chiara Polzonetti Giovanni Vitale Floriana Piscopiello Emanuela Tapfer Leander |
| author_facet | Cervellino Antonio Vitaliano Rosa Fratoddi Ilaria Russo MariaVittoria Giannini Cinzia Guagliardi Antonella Battocchio Chiara Polzonetti Giovanni Vitale Floriana Piscopiello Emanuela Tapfer Leander |
| author_sort | Cervellino Antonio |
| collection | DOAJ |
| description | <p>Abstract</p> <p>In this work the synthesis and characterization of gold nanoparticles functionalized by a novel thiol-organometallic complex containing Pd(II) centers is presented. Pd(II) thiol,<it>trans, trans</it>-[dithiolate-dibis(tributylphosphine)dipalladium(II)-4,4′-diethynylbiphenyl] was synthesized and linked to Au nanoparticles by the chemical reduction of a metal salt precursor. The new hybrid made of organometallic Pd(II) thiol-gold nanoparticles, shows through a single S bridge a direct link between Pd(II) and Au nanoparticles. The size-control of the Au nanoparticles (diameter range 2–10 nm) was achieved by choosing the suitable AuCl<sub>4</sub> <sup>−</sup>/thiol molar ratio. The size, strain, shape, and crystalline structure of these functionalized nanoparticles were determined by a full-pattern X-ray powder diffraction analysis, high-resolution TEM, and X-ray photoelectron spectroscopy. Photoluminescence spectroscopy measurements of the hybrid system show emission peaks at 418 and 440 nm. The hybrid was exposed to gaseous NO<sub> <it>x</it> </sub>with the aim to evaluate the suitability for applications in sensor devices; XPS measurements permitted to ascertain and investigate the hybrid –gas interaction.</p> |
| first_indexed | 2024-03-12T18:56:43Z |
| format | Article |
| id | doaj.art-b5c93944874846ddb1c5650d678af5d6 |
| institution | Directory Open Access Journal |
| issn | 1931-7573 1556-276X |
| language | English |
| last_indexed | 2024-03-12T18:56:43Z |
| publishDate | 2008-01-01 |
| publisher | SpringerOpen |
| record_format | Article |
| series | Nanoscale Research Letters |
| spelling | doaj.art-b5c93944874846ddb1c5650d678af5d62023-08-02T06:50:48ZengSpringerOpenNanoscale Research Letters1931-75731556-276X2008-01-01311461467Synthesis and Microstructural Investigations of Organometallic Pd(II) Thiol-Gold Nanoparticles HybridsCervellino AntonioVitaliano RosaFratoddi IlariaRusso MariaVittoriaGiannini CinziaGuagliardi AntonellaBattocchio ChiaraPolzonetti GiovanniVitale FlorianaPiscopiello EmanuelaTapfer Leander<p>Abstract</p> <p>In this work the synthesis and characterization of gold nanoparticles functionalized by a novel thiol-organometallic complex containing Pd(II) centers is presented. Pd(II) thiol,<it>trans, trans</it>-[dithiolate-dibis(tributylphosphine)dipalladium(II)-4,4′-diethynylbiphenyl] was synthesized and linked to Au nanoparticles by the chemical reduction of a metal salt precursor. The new hybrid made of organometallic Pd(II) thiol-gold nanoparticles, shows through a single S bridge a direct link between Pd(II) and Au nanoparticles. The size-control of the Au nanoparticles (diameter range 2–10 nm) was achieved by choosing the suitable AuCl<sub>4</sub> <sup>−</sup>/thiol molar ratio. The size, strain, shape, and crystalline structure of these functionalized nanoparticles were determined by a full-pattern X-ray powder diffraction analysis, high-resolution TEM, and X-ray photoelectron spectroscopy. Photoluminescence spectroscopy measurements of the hybrid system show emission peaks at 418 and 440 nm. The hybrid was exposed to gaseous NO<sub> <it>x</it> </sub>with the aim to evaluate the suitability for applications in sensor devices; XPS measurements permitted to ascertain and investigate the hybrid –gas interaction.</p>http://dx.doi.org/10.1007/s11671-008-9181-xGold nanoparticlesThiol complexesOrganometallic complexesNanoparticle synthesis |
| spellingShingle | Cervellino Antonio Vitaliano Rosa Fratoddi Ilaria Russo MariaVittoria Giannini Cinzia Guagliardi Antonella Battocchio Chiara Polzonetti Giovanni Vitale Floriana Piscopiello Emanuela Tapfer Leander Synthesis and Microstructural Investigations of Organometallic Pd(II) Thiol-Gold Nanoparticles Hybrids Nanoscale Research Letters Gold nanoparticles Thiol complexes Organometallic complexes Nanoparticle synthesis |
| title | Synthesis and Microstructural Investigations of Organometallic Pd(II) Thiol-Gold Nanoparticles Hybrids |
| title_full | Synthesis and Microstructural Investigations of Organometallic Pd(II) Thiol-Gold Nanoparticles Hybrids |
| title_fullStr | Synthesis and Microstructural Investigations of Organometallic Pd(II) Thiol-Gold Nanoparticles Hybrids |
| title_full_unstemmed | Synthesis and Microstructural Investigations of Organometallic Pd(II) Thiol-Gold Nanoparticles Hybrids |
| title_short | Synthesis and Microstructural Investigations of Organometallic Pd(II) Thiol-Gold Nanoparticles Hybrids |
| title_sort | synthesis and microstructural investigations of organometallic pd ii thiol gold nanoparticles hybrids |
| topic | Gold nanoparticles Thiol complexes Organometallic complexes Nanoparticle synthesis |
| url | http://dx.doi.org/10.1007/s11671-008-9181-x |
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