Efficient synthesis of cyclic carbonates under atmospheric CO2 by DMAP-based ionic liquids: the difference of inert hydrogen atom and active hydrogen atom in cation

Efficient synthesis of cyclic carbonates under atmospheric CO2 by DMAP-based ionic liquids: the difference of inert hydrogen atom and active hydrogen atom in cation

The coupling reaction of carbon dioxide (CO2) and epoxides is one of the most efficient pathways to achieve the carbon balance. However, to accomplish it under the mild conditions, especially under the atmospheric pressure, is still a perplexing problem. Three novel ionic liquids (ILs), [DMAPBrPC][T...

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Bibliographic Details
Main Authors: Zhengkun Zhang, Jinya Li, Guanyao Yu, Chao Zeng, Menglong Wang, Susu Huang, Li Wang, Jinglai Zhang
Format: Article
Language:English
Published: KeAi Communications Co. Ltd. 2023-09-01
Series:Green Chemical Engineering
Subjects:
Carbon dioxide
DMAP-based ionic liquids
Inert hydrogen atom
DFT calculations
Atmospheric pressure
Online Access:http://www.sciencedirect.com/science/article/pii/S2666952822000504

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http://www.sciencedirect.com/science/article/pii/S2666952822000504

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