INVESTIGATION THE IMPACT OF DIFFERENT ANNEALING TEMPERATURES ON STRUCTURAL AND OPTICAL PROPERTIES OF BI-DOPED GETE (BI: 5 %) THIN FILMS FABRICATED BY PVD TECHNIQUE)

        The impact of different annealing temperatures on the Bi-doped GeTe thin films were investigated. The thin films have been prepared by using physical vapor deposition techniques (PVD). The Bismuth (Bi) is doped GeTe with ratio of 5%. Different characterizations techniques have been used to...

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Main Authors: Shayma M. Ahmed, Azhen H. Jarjes, Ahmed F. Abdulrahman, Raghad Y. Mohammed, Sabah M. Ahmed
Format: Article
Language:English
Published: University of Zakho 2024-03-01
Series:Science Journal of University of Zakho
Subjects:
Online Access:https://sjuoz.uoz.edu.krd/index.php/sjuoz/article/view/1242
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author Shayma M. Ahmed
Azhen H. Jarjes
Ahmed F. Abdulrahman
Raghad Y. Mohammed
Sabah M. Ahmed
author_facet Shayma M. Ahmed
Azhen H. Jarjes
Ahmed F. Abdulrahman
Raghad Y. Mohammed
Sabah M. Ahmed
author_sort Shayma M. Ahmed
collection DOAJ
description         The impact of different annealing temperatures on the Bi-doped GeTe thin films were investigated. The thin films have been prepared by using physical vapor deposition techniques (PVD). The Bismuth (Bi) is doped GeTe with ratio of 5%. Different characterizations techniques have been used to study the different properties of thin films with several annealing temperatures. It has been found that the film thickness decreases as the annealing temperature increases. The XRD patterns show that as-deposited and annealed Bi-doped GeTe films at 150°C,200°C, and 250°C were fully amorphous, while the film annealed at 100 °C was crystalline. FESEM image shows that the structure is amorphous with no grain appearing for the crystallite GeTe compound. Whereas the annealed thin films at 100°C are well-appeared crystallites of GeTe with an average size of (110.64 nm). The thin films are annealed at (150, 200, and 250)°C which reveals that the crystallite or grain is increased. An increase in the annealing temperature has been found to cause a significant shift in the absorption edge toward an extended wavelength and an overall reduction in transmittance. At a wavelength of 1100 nm, the transmittance dropped from 65.25% for as-deposited thin films to 32.57% for annealed thin films at 250 °C. Furthermore, when the annealing temperature rises from 100°C to 250°C, the optical band gap reduces from 0.95 eV to 0.42 eV.
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spelling doaj.art-b5e22531a3cd4072baa4378a511e65202024-04-11T21:56:01ZengUniversity of ZakhoScience Journal of University of Zakho2663-628X2663-62982024-03-0112110.25271/sjuoz.2024.12.1.1242INVESTIGATION THE IMPACT OF DIFFERENT ANNEALING TEMPERATURES ON STRUCTURAL AND OPTICAL PROPERTIES OF BI-DOPED GETE (BI: 5 %) THIN FILMS FABRICATED BY PVD TECHNIQUE)Shayma M. Ahmed0Azhen H. Jarjes1Ahmed F. Abdulrahman2Raghad Y. Mohammed3Sabah M. Ahmed4Department of Physics, College of Science, University of Duhok, Kurdistan Region 42001Department of Physics, College of Science, University of Duhok, Kurdistan Region 42001, IraqDepartment of Energy Engineering, Technical College of Engineering, Duhok Polytechnique University, Kurdistan Region, 42001, Iraq. Department of Medical Laboratory Technology, Technical Institute of Amedi, Duhok Polytechnique University, Kurdistan Region, 42008, IraqDepartment of Physics, College of Science, University of Duhok, Kurdistan Region 42001, IraqDepartment of Physics, College of Science, University of Duhok, Kurdistan Region 42001, Iraq         The impact of different annealing temperatures on the Bi-doped GeTe thin films were investigated. The thin films have been prepared by using physical vapor deposition techniques (PVD). The Bismuth (Bi) is doped GeTe with ratio of 5%. Different characterizations techniques have been used to study the different properties of thin films with several annealing temperatures. It has been found that the film thickness decreases as the annealing temperature increases. The XRD patterns show that as-deposited and annealed Bi-doped GeTe films at 150°C,200°C, and 250°C were fully amorphous, while the film annealed at 100 °C was crystalline. FESEM image shows that the structure is amorphous with no grain appearing for the crystallite GeTe compound. Whereas the annealed thin films at 100°C are well-appeared crystallites of GeTe with an average size of (110.64 nm). The thin films are annealed at (150, 200, and 250)°C which reveals that the crystallite or grain is increased. An increase in the annealing temperature has been found to cause a significant shift in the absorption edge toward an extended wavelength and an overall reduction in transmittance. At a wavelength of 1100 nm, the transmittance dropped from 65.25% for as-deposited thin films to 32.57% for annealed thin films at 250 °C. Furthermore, when the annealing temperature rises from 100°C to 250°C, the optical band gap reduces from 0.95 eV to 0.42 eV. https://sjuoz.uoz.edu.krd/index.php/sjuoz/article/view/1242Germanium TellurideAnnealing TemperatureDopingOptical propertiesBismuth
spellingShingle Shayma M. Ahmed
Azhen H. Jarjes
Ahmed F. Abdulrahman
Raghad Y. Mohammed
Sabah M. Ahmed
INVESTIGATION THE IMPACT OF DIFFERENT ANNEALING TEMPERATURES ON STRUCTURAL AND OPTICAL PROPERTIES OF BI-DOPED GETE (BI: 5 %) THIN FILMS FABRICATED BY PVD TECHNIQUE)
Science Journal of University of Zakho
Germanium Telluride
Annealing Temperature
Doping
Optical properties
Bismuth
title INVESTIGATION THE IMPACT OF DIFFERENT ANNEALING TEMPERATURES ON STRUCTURAL AND OPTICAL PROPERTIES OF BI-DOPED GETE (BI: 5 %) THIN FILMS FABRICATED BY PVD TECHNIQUE)
title_full INVESTIGATION THE IMPACT OF DIFFERENT ANNEALING TEMPERATURES ON STRUCTURAL AND OPTICAL PROPERTIES OF BI-DOPED GETE (BI: 5 %) THIN FILMS FABRICATED BY PVD TECHNIQUE)
title_fullStr INVESTIGATION THE IMPACT OF DIFFERENT ANNEALING TEMPERATURES ON STRUCTURAL AND OPTICAL PROPERTIES OF BI-DOPED GETE (BI: 5 %) THIN FILMS FABRICATED BY PVD TECHNIQUE)
title_full_unstemmed INVESTIGATION THE IMPACT OF DIFFERENT ANNEALING TEMPERATURES ON STRUCTURAL AND OPTICAL PROPERTIES OF BI-DOPED GETE (BI: 5 %) THIN FILMS FABRICATED BY PVD TECHNIQUE)
title_short INVESTIGATION THE IMPACT OF DIFFERENT ANNEALING TEMPERATURES ON STRUCTURAL AND OPTICAL PROPERTIES OF BI-DOPED GETE (BI: 5 %) THIN FILMS FABRICATED BY PVD TECHNIQUE)
title_sort investigation the impact of different annealing temperatures on structural and optical properties of bi doped gete bi 5 thin films fabricated by pvd technique
topic Germanium Telluride
Annealing Temperature
Doping
Optical properties
Bismuth
url https://sjuoz.uoz.edu.krd/index.php/sjuoz/article/view/1242
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