Poly[[triaqua(μ3-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate]
In the title coordination polymer, {[Tm(C7H2NO5)(H2O)3]·H2O}n, the TmIII atom is eight-coordinated by a tridentate 4-oxidopyridine-2,6-dicarboxylate trianion, two monodentate anions and three water molecules, forming a distorted bicapped trigonal–prismatic TmNO7 coordinati...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811007628 |
| _version_ | 1818775517536452608 |
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| author | Zhu-Qing Gao Dong-Yu Lv Jin-Zhong Gu Hong-Jin Li |
| author_facet | Zhu-Qing Gao Dong-Yu Lv Jin-Zhong Gu Hong-Jin Li |
| author_sort | Zhu-Qing Gao |
| collection | DOAJ |
| description | In the title coordination polymer, {[Tm(C7H2NO5)(H2O)3]·H2O}n, the TmIII atom is eight-coordinated by a tridentate 4-oxidopyridine-2,6-dicarboxylate trianion, two monodentate anions and three water molecules, forming a distorted bicapped trigonal–prismatic TmNO7 coordination geometry. The anions bridge adjacent TmIII ions into double chains. Adjacent chains are further connected into sheets. O—H...O hydrogen bonds involving both coordinated and uncoordinated water molecules generate a three-dimensional supramolecular framework. |
| first_indexed | 2024-12-18T10:58:18Z |
| format | Article |
| id | doaj.art-b5f7ba0622e346cca662c9fa5db41983 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-18T10:58:18Z |
| publishDate | 2011-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-b5f7ba0622e346cca662c9fa5db419832022-12-21T21:10:17ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-04-01674m409m40910.1107/S1600536811007628Poly[[triaqua(μ3-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate]Zhu-Qing GaoDong-Yu LvJin-Zhong GuHong-Jin LiIn the title coordination polymer, {[Tm(C7H2NO5)(H2O)3]·H2O}n, the TmIII atom is eight-coordinated by a tridentate 4-oxidopyridine-2,6-dicarboxylate trianion, two monodentate anions and three water molecules, forming a distorted bicapped trigonal–prismatic TmNO7 coordination geometry. The anions bridge adjacent TmIII ions into double chains. Adjacent chains are further connected into sheets. O—H...O hydrogen bonds involving both coordinated and uncoordinated water molecules generate a three-dimensional supramolecular framework.http://scripts.iucr.org/cgi-bin/paper?S1600536811007628 |
| spellingShingle | Zhu-Qing Gao Dong-Yu Lv Jin-Zhong Gu Hong-Jin Li Poly[[triaqua(μ3-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate] Acta Crystallographica Section E |
| title | Poly[[triaqua(μ3-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate] |
| title_full | Poly[[triaqua(μ3-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate] |
| title_fullStr | Poly[[triaqua(μ3-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate] |
| title_full_unstemmed | Poly[[triaqua(μ3-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate] |
| title_short | Poly[[triaqua(μ3-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate] |
| title_sort | poly triaqua amp 956 3 4 oxidopyridine 2 6 dicarboxylato thulium iii monohydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811007628 |
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