Steel passive state stability in activated fly ash mortars

The present study explores the behaviour of structural steel embedded in Portland cement (OPC) mortars and NaOH- and NaOH-waterglass-activated fly ash, in the presence and absence of 2 % Cl- (CaCl2). Variations were determined in the corrosion potential (Ecorr), linear polarization resistance (Rp) a...

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Bibliographic Details
Main Authors: A. Fernández-Jiménez, J. M. Miranda, J. A. González, A. Palomo
Format: Article
Language:English
Published: Consejo Superior de Investigaciones Científicas 2010-12-01
Series:Materiales de Construccion
Subjects:
Online Access:http://materconstrucc.revistas.csic.es/index.php/materconstrucc/article/view/217
Description
Summary:The present study explores the behaviour of structural steel embedded in Portland cement (OPC) mortars and NaOH- and NaOH-waterglass-activated fly ash, in the presence and absence of 2 % Cl- (CaCl2). Variations were determined in the corrosion potential (Ecorr), linear polarization resistance (Rp) and corrosion current density (icorr) under different environmental conditions (90 days at 95 % relative humidity (RH), 30 days at ≈ 30 % RH, 760 days at ≈ 95 % RH). In the absence of Cl-, fly ash mortars were able to passivate steel reinforcement, although the stability of the passive state in changing environmental conditions was found to depend heavily on the activating solution used. Steel corrosion in the presence of 2 % Cl- was observed to be similar to the corrosion reported for the material in OPC mortars.
ISSN:0465-2746
1988-3226