Historical lead seals and the influence of disinfectants on the lead corrosion rate

Abstract Lead used to be a common material for setting seal to historical documents. Lead seals formed parts of historical documents as a guarantee of their legal validity. Disinfectants are commonly used during the restoration of historical documents. They successfully remove mould, bacteria and mi...

Full description

Bibliographic Details
Main Authors: Sarka Msallamova, Milan Kouril, Kristyna Charllote Strachotova, Jan Stoulil, Kateryna Popova, Pavla Dvorakova
Format: Article
Language:English
Published: SpringerOpen 2019-03-01
Series:Heritage Science
Subjects:
Online Access:http://link.springer.com/article/10.1186/s40494-019-0260-3
_version_ 1818446551805067264
author Sarka Msallamova
Milan Kouril
Kristyna Charllote Strachotova
Jan Stoulil
Kateryna Popova
Pavla Dvorakova
author_facet Sarka Msallamova
Milan Kouril
Kristyna Charllote Strachotova
Jan Stoulil
Kateryna Popova
Pavla Dvorakova
author_sort Sarka Msallamova
collection DOAJ
description Abstract Lead used to be a common material for setting seal to historical documents. Lead seals formed parts of historical documents as a guarantee of their legal validity. Disinfectants are commonly used during the restoration of historical documents. They successfully remove mould, bacteria and microscopic fungi from the surface of parchment documents. However, some disinfectants could also be a source of corrosion damage to lead seals. This work was carried out to examine possible corrosion damage to lead seals caused by disinfectants [a solution of carbethopendecinium bromide, a solution of glutaraldehyde, butanol (vapours), a solution of 1-propanol, 2-propanol + ethanol called Bacillol AF], which are commonly used during restoration of historical documents. The lead corrosion rates were determined by using lead resistometric probes. The solutions of carbethopendecinium bromide and glutaraldehyde increase the lead corrosion rate and corrosion products based on carbonates, nitrates and organic lead salts are formed on the lead surface. The most appropriate disinfectants for the restoration of historical documents with lead seals are alcohol-based solutions, such as butanol (vapours) and a solution of 1-propanol, 2-propanol and ethanol called Bacillol AF.
first_indexed 2024-12-14T19:49:32Z
format Article
id doaj.art-b60c878bd7b24dc9aa69b94b3bda95d8
institution Directory Open Access Journal
issn 2050-7445
language English
last_indexed 2024-12-14T19:49:32Z
publishDate 2019-03-01
publisher SpringerOpen
record_format Article
series Heritage Science
spelling doaj.art-b60c878bd7b24dc9aa69b94b3bda95d82022-12-21T22:49:28ZengSpringerOpenHeritage Science2050-74452019-03-01711810.1186/s40494-019-0260-3Historical lead seals and the influence of disinfectants on the lead corrosion rateSarka Msallamova0Milan Kouril1Kristyna Charllote Strachotova2Jan Stoulil3Kateryna Popova4Pavla Dvorakova5University of Chemistry and TechnologyUniversity of Chemistry and TechnologyUniversity of Chemistry and TechnologyUniversity of Chemistry and TechnologyUniversity of Chemistry and TechnologyUniversity of Chemistry and TechnologyAbstract Lead used to be a common material for setting seal to historical documents. Lead seals formed parts of historical documents as a guarantee of their legal validity. Disinfectants are commonly used during the restoration of historical documents. They successfully remove mould, bacteria and microscopic fungi from the surface of parchment documents. However, some disinfectants could also be a source of corrosion damage to lead seals. This work was carried out to examine possible corrosion damage to lead seals caused by disinfectants [a solution of carbethopendecinium bromide, a solution of glutaraldehyde, butanol (vapours), a solution of 1-propanol, 2-propanol + ethanol called Bacillol AF], which are commonly used during restoration of historical documents. The lead corrosion rates were determined by using lead resistometric probes. The solutions of carbethopendecinium bromide and glutaraldehyde increase the lead corrosion rate and corrosion products based on carbonates, nitrates and organic lead salts are formed on the lead surface. The most appropriate disinfectants for the restoration of historical documents with lead seals are alcohol-based solutions, such as butanol (vapours) and a solution of 1-propanol, 2-propanol and ethanol called Bacillol AF.http://link.springer.com/article/10.1186/s40494-019-0260-3LeadCorrosionResistometric probeDisinfectantsSealsHistorical documents
spellingShingle Sarka Msallamova
Milan Kouril
Kristyna Charllote Strachotova
Jan Stoulil
Kateryna Popova
Pavla Dvorakova
Historical lead seals and the influence of disinfectants on the lead corrosion rate
Heritage Science
Lead
Corrosion
Resistometric probe
Disinfectants
Seals
Historical documents
title Historical lead seals and the influence of disinfectants on the lead corrosion rate
title_full Historical lead seals and the influence of disinfectants on the lead corrosion rate
title_fullStr Historical lead seals and the influence of disinfectants on the lead corrosion rate
title_full_unstemmed Historical lead seals and the influence of disinfectants on the lead corrosion rate
title_short Historical lead seals and the influence of disinfectants on the lead corrosion rate
title_sort historical lead seals and the influence of disinfectants on the lead corrosion rate
topic Lead
Corrosion
Resistometric probe
Disinfectants
Seals
Historical documents
url http://link.springer.com/article/10.1186/s40494-019-0260-3
work_keys_str_mv AT sarkamsallamova historicalleadsealsandtheinfluenceofdisinfectantsontheleadcorrosionrate
AT milankouril historicalleadsealsandtheinfluenceofdisinfectantsontheleadcorrosionrate
AT kristynacharllotestrachotova historicalleadsealsandtheinfluenceofdisinfectantsontheleadcorrosionrate
AT janstoulil historicalleadsealsandtheinfluenceofdisinfectantsontheleadcorrosionrate
AT katerynapopova historicalleadsealsandtheinfluenceofdisinfectantsontheleadcorrosionrate
AT pavladvorakova historicalleadsealsandtheinfluenceofdisinfectantsontheleadcorrosionrate