2,5-Dichloro-N-cyclohexylbenzenesulfonamide

The structure of the title sulfonamide, C12H15Cl2NO2S, features a distorted tetrahedral geometry for the S atom [maximum deviation: O—S—O = 120.23 (14)°]. One of the sulfonamide O atoms is coplanar with the benzene ring [C—C&am...

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Bibliographic Details
Main Authors: Edward R. T. Tiekink, Ahmad Mahmood Mumtaz, Shumaila Batool, Shahzad Sharif, Islam Ullah Khan
Format: Article
Language:English
Published: International Union of Crystallography 2010-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681003789X
Description
Summary:The structure of the title sulfonamide, C12H15Cl2NO2S, features a distorted tetrahedral geometry for the S atom [maximum deviation: O—S—O = 120.23 (14)°]. One of the sulfonamide O atoms is coplanar with the benzene ring [C—C—S—O torsion angle = −174.5 (2)°], whereas the other lies well above the plane [C—C—S—O = 57.0 (3)°]. A chair conformation is found for the cyclohexyl ring. In the crystal, supramolecular chains aligned along the c axis are formed via N—H...O hydrogen bonds; these are consolidated in the three-dimensional packing by C—H...O contacts involving the second sulfonamide O atom.
ISSN:1600-5368