The strengthening efficacy of filler/interphase network in polymer halloysite nanotubes system after mechanical percolation

A defective interphase section in polymer halloysite nanotubes (HNT) system is considered and the influences of required interfacial shear strength for effective stress conveying via interphase zone (τc) and interfacial shear strength (τc) on the effective interphase depth, effective filler amount a...

Full description

Bibliographic Details
Main Authors: Yasser Zare, Kyong Yop Rhee
Format: Article
Language:English
Published: Elsevier 2021-11-01
Series:Journal of Materials Research and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2238785421012527
_version_ 1818969295218016256
author Yasser Zare
Kyong Yop Rhee
author_facet Yasser Zare
Kyong Yop Rhee
author_sort Yasser Zare
collection DOAJ
description A defective interphase section in polymer halloysite nanotubes (HNT) system is considered and the influences of required interfacial shear strength for effective stress conveying via interphase zone (τc) and interfacial shear strength (τc) on the effective interphase depth, effective filler amount and percolation onset are stated. Additionally, a novel model is progressed for the strength of nanocomposites after percolation onset assuming these terms. The calculations of the established model at numerous series of all factors are analyzed and several tentative facts for various examples are compared to model's estimations. The nanocomposite's strength reaches 75 MPa at τc = 10 MPa and HNT volume fraction of 0.03, but τc = 50 MPa cannot toughen the system at various HNT contents. τ = 30 MPa and HNT radius (R) = 60 nm cannot strengthen the nanocomposites, while τ = 100 MPa and R = 20 nm maximize the strength of system to 138 MPa. HNT length of 900 nm cannot reinforce the samples at various ranges of percolation onset, whereas the strength of nanocomposites grows to 200 MPa at HNT length of 3.1 μm and percolation onset of 0.002. These results are valuable to optimize the main factors yielding the tough nanocomposites.
first_indexed 2024-12-20T14:18:19Z
format Article
id doaj.art-b61f67284f65455fb7fd8f2945a6be15
institution Directory Open Access Journal
issn 2238-7854
language English
last_indexed 2024-12-20T14:18:19Z
publishDate 2021-11-01
publisher Elsevier
record_format Article
series Journal of Materials Research and Technology
spelling doaj.art-b61f67284f65455fb7fd8f2945a6be152022-12-21T19:37:59ZengElsevierJournal of Materials Research and Technology2238-78542021-11-011553435352The strengthening efficacy of filler/interphase network in polymer halloysite nanotubes system after mechanical percolationYasser Zare0Kyong Yop Rhee1Biomaterials and Tissue Engineering Research Group, Department of Interdisciplinary Technologies, Breast Cancer Research Center, Motamed Cancer Institute, ACECR, Tehran, Iran; Corresponding author.Department of Mechanical Engineering (BK21 Four), College of Engineering, Kyung Hee University, Yongin, Republic of Korea; Corresponding author.A defective interphase section in polymer halloysite nanotubes (HNT) system is considered and the influences of required interfacial shear strength for effective stress conveying via interphase zone (τc) and interfacial shear strength (τc) on the effective interphase depth, effective filler amount and percolation onset are stated. Additionally, a novel model is progressed for the strength of nanocomposites after percolation onset assuming these terms. The calculations of the established model at numerous series of all factors are analyzed and several tentative facts for various examples are compared to model's estimations. The nanocomposite's strength reaches 75 MPa at τc = 10 MPa and HNT volume fraction of 0.03, but τc = 50 MPa cannot toughen the system at various HNT contents. τ = 30 MPa and HNT radius (R) = 60 nm cannot strengthen the nanocomposites, while τ = 100 MPa and R = 20 nm maximize the strength of system to 138 MPa. HNT length of 900 nm cannot reinforce the samples at various ranges of percolation onset, whereas the strength of nanocomposites grows to 200 MPa at HNT length of 3.1 μm and percolation onset of 0.002. These results are valuable to optimize the main factors yielding the tough nanocomposites.http://www.sciencedirect.com/science/article/pii/S2238785421012527Polymer halloysite nanotubes systemInterfacial shear strengthEffective interphase depthPercolation onsetSimulation
spellingShingle Yasser Zare
Kyong Yop Rhee
The strengthening efficacy of filler/interphase network in polymer halloysite nanotubes system after mechanical percolation
Journal of Materials Research and Technology
Polymer halloysite nanotubes system
Interfacial shear strength
Effective interphase depth
Percolation onset
Simulation
title The strengthening efficacy of filler/interphase network in polymer halloysite nanotubes system after mechanical percolation
title_full The strengthening efficacy of filler/interphase network in polymer halloysite nanotubes system after mechanical percolation
title_fullStr The strengthening efficacy of filler/interphase network in polymer halloysite nanotubes system after mechanical percolation
title_full_unstemmed The strengthening efficacy of filler/interphase network in polymer halloysite nanotubes system after mechanical percolation
title_short The strengthening efficacy of filler/interphase network in polymer halloysite nanotubes system after mechanical percolation
title_sort strengthening efficacy of filler interphase network in polymer halloysite nanotubes system after mechanical percolation
topic Polymer halloysite nanotubes system
Interfacial shear strength
Effective interphase depth
Percolation onset
Simulation
url http://www.sciencedirect.com/science/article/pii/S2238785421012527
work_keys_str_mv AT yasserzare thestrengtheningefficacyoffillerinterphasenetworkinpolymerhalloysitenanotubessystemaftermechanicalpercolation
AT kyongyoprhee thestrengtheningefficacyoffillerinterphasenetworkinpolymerhalloysitenanotubessystemaftermechanicalpercolation
AT yasserzare strengtheningefficacyoffillerinterphasenetworkinpolymerhalloysitenanotubessystemaftermechanicalpercolation
AT kyongyoprhee strengtheningefficacyoffillerinterphasenetworkinpolymerhalloysitenanotubessystemaftermechanicalpercolation