Magnetic and structural phase transitions of MnBi under high magnetic fields

High-field x-ray diffraction and magnetization measurements and differential thermal analysis (DTA) were carried out for polycrystalline MnBi with an NiAs-type hexagonal structure to investigate its magnetic and structural phase transitions. The lattice parameter a rapidly decreases below the spin r...

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Main Author: Keiichi Koyama, Yoshifuru Mitsui and Kazuo Watanabe
Format: Article
Language:English
Published: Taylor & Francis Group 2008-01-01
Series:Science and Technology of Advanced Materials
Subjects:
Online Access:http://www.iop.org/EJ/abstract/1468-6996/9/2/024204
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author Keiichi Koyama, Yoshifuru Mitsui and Kazuo Watanabe
author_facet Keiichi Koyama, Yoshifuru Mitsui and Kazuo Watanabe
author_sort Keiichi Koyama, Yoshifuru Mitsui and Kazuo Watanabe
collection DOAJ
description High-field x-ray diffraction and magnetization measurements and differential thermal analysis (DTA) were carried out for polycrystalline MnBi with an NiAs-type hexagonal structure to investigate its magnetic and structural phase transitions. The lattice parameter a rapidly decreases below the spin reorientation temperature TSR(=90 K) in a zero magnetic field. The parameter c decreases gradually with decreasing temperature and exhibits an anomaly in the vicinity of TSR. By applying a magnetic field of 5 T, the parameter a increases by ~0.05% when T<TSR and varies smoothly when 8≤T≤300 K. DTA data show that the magnetic phase transition temperature from the ferromagnetic state to the paramagnetic state increases linearly at a rate of 2 KT−1 with increasing magnetic field up to 14 T.
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spelling doaj.art-b621e716e9f14b13affd2f85321f37ca2022-12-21T18:57:11ZengTaylor & Francis GroupScience and Technology of Advanced Materials1468-69961878-55142008-01-0192024204Magnetic and structural phase transitions of MnBi under high magnetic fieldsKeiichi Koyama, Yoshifuru Mitsui and Kazuo WatanabeHigh-field x-ray diffraction and magnetization measurements and differential thermal analysis (DTA) were carried out for polycrystalline MnBi with an NiAs-type hexagonal structure to investigate its magnetic and structural phase transitions. The lattice parameter a rapidly decreases below the spin reorientation temperature TSR(=90 K) in a zero magnetic field. The parameter c decreases gradually with decreasing temperature and exhibits an anomaly in the vicinity of TSR. By applying a magnetic field of 5 T, the parameter a increases by ~0.05% when T<TSR and varies smoothly when 8≤T≤300 K. DTA data show that the magnetic phase transition temperature from the ferromagnetic state to the paramagnetic state increases linearly at a rate of 2 KT−1 with increasing magnetic field up to 14 T.http://www.iop.org/EJ/abstract/1468-6996/9/2/024204MnBihigh-field x-ray diffractiondifferential thermal analysishigh magnetic fields
spellingShingle Keiichi Koyama, Yoshifuru Mitsui and Kazuo Watanabe
Magnetic and structural phase transitions of MnBi under high magnetic fields
Science and Technology of Advanced Materials
MnBi
high-field x-ray diffraction
differential thermal analysis
high magnetic fields
title Magnetic and structural phase transitions of MnBi under high magnetic fields
title_full Magnetic and structural phase transitions of MnBi under high magnetic fields
title_fullStr Magnetic and structural phase transitions of MnBi under high magnetic fields
title_full_unstemmed Magnetic and structural phase transitions of MnBi under high magnetic fields
title_short Magnetic and structural phase transitions of MnBi under high magnetic fields
title_sort magnetic and structural phase transitions of mnbi under high magnetic fields
topic MnBi
high-field x-ray diffraction
differential thermal analysis
high magnetic fields
url http://www.iop.org/EJ/abstract/1468-6996/9/2/024204
work_keys_str_mv AT keiichikoyamayoshifurumitsuiandkazuowatanabe magneticandstructuralphasetransitionsofmnbiunderhighmagneticfields