9-Phenyl-4,5-diaza-9H-fluoren-9-ol monohydrate
The title compound, C17H12N2O·H2O, was synthesized by the reaction of 4,5-diazafluoren-9-one with a Grignard reagent in ether (the reaction mixture being hydrolysed with saturated NH4Cl solution), and crystallizes with two organic molecules and two water molecules in the asymmetric unit...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812021940 |
| _version_ | 1798017128543027200 |
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| author | Guo-Jie Yin Gang-Bin Yang Shi-Min Wang |
| author_facet | Guo-Jie Yin Gang-Bin Yang Shi-Min Wang |
| author_sort | Guo-Jie Yin |
| collection | DOAJ |
| description | The title compound, C17H12N2O·H2O, was synthesized by the reaction of 4,5-diazafluoren-9-one with a Grignard reagent in ether (the reaction mixture being hydrolysed with saturated NH4Cl solution), and crystallizes with two organic molecules and two water molecules in the asymmetric unit. The 4,5-diazafluorene fragment is approximately planar, with r.m.s. deviations of 0.0448 and 0.0198 Å in the two molecules. The dihedral angles between the 4,5-diazafluorene planes and the phenyl ring are 80.49 (6) and 76.57 (7)°. The crystal packing features O—H...N and O—H...O hydrogen bonds involving the bridging solvent water molecules, which link the molecules into a three-dimensional network. |
| first_indexed | 2024-04-11T16:00:38Z |
| format | Article |
| id | doaj.art-b64b7d1f39884da2986cc9f5763aca32 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T16:00:38Z |
| publishDate | 2012-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-b64b7d1f39884da2986cc9f5763aca322022-12-22T04:15:01ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-06-01686o1817o181710.1107/S16005368120219409-Phenyl-4,5-diaza-9H-fluoren-9-ol monohydrateGuo-Jie YinGang-Bin YangShi-Min WangThe title compound, C17H12N2O·H2O, was synthesized by the reaction of 4,5-diazafluoren-9-one with a Grignard reagent in ether (the reaction mixture being hydrolysed with saturated NH4Cl solution), and crystallizes with two organic molecules and two water molecules in the asymmetric unit. The 4,5-diazafluorene fragment is approximately planar, with r.m.s. deviations of 0.0448 and 0.0198 Å in the two molecules. The dihedral angles between the 4,5-diazafluorene planes and the phenyl ring are 80.49 (6) and 76.57 (7)°. The crystal packing features O—H...N and O—H...O hydrogen bonds involving the bridging solvent water molecules, which link the molecules into a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536812021940 |
| spellingShingle | Guo-Jie Yin Gang-Bin Yang Shi-Min Wang 9-Phenyl-4,5-diaza-9H-fluoren-9-ol monohydrate Acta Crystallographica Section E |
| title | 9-Phenyl-4,5-diaza-9H-fluoren-9-ol monohydrate |
| title_full | 9-Phenyl-4,5-diaza-9H-fluoren-9-ol monohydrate |
| title_fullStr | 9-Phenyl-4,5-diaza-9H-fluoren-9-ol monohydrate |
| title_full_unstemmed | 9-Phenyl-4,5-diaza-9H-fluoren-9-ol monohydrate |
| title_short | 9-Phenyl-4,5-diaza-9H-fluoren-9-ol monohydrate |
| title_sort | 9 phenyl 4 5 diaza 9h fluoren 9 ol monohydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812021940 |
| work_keys_str_mv | AT guojieyin 9phenyl45diaza9hfluoren9olmonohydrate AT gangbinyang 9phenyl45diaza9hfluoren9olmonohydrate AT shiminwang 9phenyl45diaza9hfluoren9olmonohydrate |