A Well-Defined {[(PhCH2O)2P(CH3)2CHNCH(CH3)2]2PdCl2} Complex Catalyzed Hiyama Coupling of Aryl Bromides with Arylsilanes
A palladium (II) complex {[(PhCH2O)2P(CH3)2CHNCH(CH3)2]2PdCl2} catalyzed Hiyama cross-coupling reaction between aryl bromides and arylsilanes has been developed. The substituted biaryls were produced in moderate to high yields, regardless of electron-withdrawing or electron-donating.
Main Authors: | Mengping Guo, Leiqing Fu, Jiamin Li, Lanjiang Zhou, Yanping Kang |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2016-07-01
|
Series: | Molecules |
Subjects: | |
Online Access: | http://www.mdpi.com/1420-3049/21/8/987 |
Similar Items
-
[(PhCH2O)2P(CH3)2CHNCH(CH3)2]2PdCl2/CuI as Cocatalyst for Coupling-Cyclization of 2-Iodophenol with Terminal Alkynes in Water
by: Panli Jiang, et al.
Published: (2018-03-01) -
Copper-Promoted Hiyama Cross-Coupling of Arylsilanes With Thiuram Reagents: A Facile Synthesis of Aryl Dithiocarbamates
by: Yiying Wang, et al.
Published: (2022-04-01) -
Crystal structure of bis(n-propylamine)dichloropalladium(II), (CH3CH2CH2NH2)2PdCl2
by: Casellato U., et al.
Published: (1999-12-01) -
Transition Metal Catalyzed Hiyama Cross-Coupling: Recent Methodology Developments and Synthetic Applications
by: Rida Noor, et al.
Published: (2022-09-01) -
The stereochemistry of the Nozaki-Hiyama-Kishi reaction and the construction of 10-membered lactones. The enantioselective total synthesis of (-)-decarestrictine D
by: Pilli Ronaldo A., et al.
Published: (2001-01-01)