Crystal structure of bis{4-[(4-methylbenzyl)oxy]-N′-(4-methylbenzylidene)benzohydrazidato}nickel(II)

In the title complex, [Ni(C23H21N2O2)2], the central NiII atom is located on an inversion centre and exhibits a slightly distorted square-planar N2O2 coordination environment. A trans-configuration of the N,O chelating ligands results from the imposed site symmetry of the central NiII atom. In the c...

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Main Authors: Md. Hasan Al Banna, Md. Belayet Hossain Howlader, Ryuta Miyatake, Md. Chanmiya Sheikh, Ennio Zangrando
Format: Article
Language:English
Published: International Union of Crystallography 2022-10-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989022009392
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author Md. Hasan Al Banna
Md. Belayet Hossain Howlader
Ryuta Miyatake
Md. Chanmiya Sheikh
Ennio Zangrando
author_facet Md. Hasan Al Banna
Md. Belayet Hossain Howlader
Ryuta Miyatake
Md. Chanmiya Sheikh
Ennio Zangrando
author_sort Md. Hasan Al Banna
collection DOAJ
description In the title complex, [Ni(C23H21N2O2)2], the central NiII atom is located on an inversion centre and exhibits a slightly distorted square-planar N2O2 coordination environment. A trans-configuration of the N,O chelating ligands results from the imposed site symmetry of the central NiII atom. In the crystal, individual molecules stack along the a axis through weak π–π stacking interactions between the phenyl rings.
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spelling doaj.art-b66a0c90958f41fea76d5c591ed4cc982022-12-22T03:37:30ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902022-10-0178101081108310.1107/S2056989022009392wm5661Crystal structure of bis{4-[(4-methylbenzyl)oxy]-N′-(4-methylbenzylidene)benzohydrazidato}nickel(II)Md. Hasan Al Banna0Md. Belayet Hossain Howlader1Ryuta Miyatake2Md. Chanmiya Sheikh3Ennio Zangrando4Department of Chemistry, Rajshahi University, Rajshahi-6205, BangladeshDepartment of Chemistry, Rajshahi University, Rajshahi-6205, BangladeshCenter for Environmental Conservation and Research Safety, University of Toyama, 3190 Gofuku, Toyama, 930-8555, JapanDepartment of Applied Science, Faculty of Science, Okayama University of Science, JapanDepartment of Chemical and Pharmaceutical SCiences, University of Trieste, ItalyIn the title complex, [Ni(C23H21N2O2)2], the central NiII atom is located on an inversion centre and exhibits a slightly distorted square-planar N2O2 coordination environment. A trans-configuration of the N,O chelating ligands results from the imposed site symmetry of the central NiII atom. In the crystal, individual molecules stack along the a axis through weak π–π stacking interactions between the phenyl rings.http://scripts.iucr.org/cgi-bin/paper?S2056989022009392crystal structurenickel(ii) complexsquare-planar coordinationaroylhydrazone ligand
spellingShingle Md. Hasan Al Banna
Md. Belayet Hossain Howlader
Ryuta Miyatake
Md. Chanmiya Sheikh
Ennio Zangrando
Crystal structure of bis{4-[(4-methylbenzyl)oxy]-N′-(4-methylbenzylidene)benzohydrazidato}nickel(II)
Acta Crystallographica Section E: Crystallographic Communications
crystal structure
nickel(ii) complex
square-planar coordination
aroylhydrazone ligand
title Crystal structure of bis{4-[(4-methylbenzyl)oxy]-N′-(4-methylbenzylidene)benzohydrazidato}nickel(II)
title_full Crystal structure of bis{4-[(4-methylbenzyl)oxy]-N′-(4-methylbenzylidene)benzohydrazidato}nickel(II)
title_fullStr Crystal structure of bis{4-[(4-methylbenzyl)oxy]-N′-(4-methylbenzylidene)benzohydrazidato}nickel(II)
title_full_unstemmed Crystal structure of bis{4-[(4-methylbenzyl)oxy]-N′-(4-methylbenzylidene)benzohydrazidato}nickel(II)
title_short Crystal structure of bis{4-[(4-methylbenzyl)oxy]-N′-(4-methylbenzylidene)benzohydrazidato}nickel(II)
title_sort crystal structure of bis 4 4 methylbenzyl oxy n 4 methylbenzylidene benzohydrazidato nickel ii
topic crystal structure
nickel(ii) complex
square-planar coordination
aroylhydrazone ligand
url http://scripts.iucr.org/cgi-bin/paper?S2056989022009392
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AT ryutamiyatake crystalstructureofbis44methylbenzyloxyn4methylbenzylidenebenzohydrazidatonickelii
AT mdchanmiyasheikh crystalstructureofbis44methylbenzyloxyn4methylbenzylidenebenzohydrazidatonickelii
AT enniozangrando crystalstructureofbis44methylbenzyloxyn4methylbenzylidenebenzohydrazidatonickelii