Crystal structure of bis{4-[(4-methylbenzyl)oxy]-N′-(4-methylbenzylidene)benzohydrazidato}nickel(II)
In the title complex, [Ni(C23H21N2O2)2], the central NiII atom is located on an inversion centre and exhibits a slightly distorted square-planar N2O2 coordination environment. A trans-configuration of the N,O chelating ligands results from the imposed site symmetry of the central NiII atom. In the c...
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Format: | Article |
Language: | English |
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International Union of Crystallography
2022-10-01
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Series: | Acta Crystallographica Section E: Crystallographic Communications |
Subjects: | |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989022009392 |
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author | Md. Hasan Al Banna Md. Belayet Hossain Howlader Ryuta Miyatake Md. Chanmiya Sheikh Ennio Zangrando |
author_facet | Md. Hasan Al Banna Md. Belayet Hossain Howlader Ryuta Miyatake Md. Chanmiya Sheikh Ennio Zangrando |
author_sort | Md. Hasan Al Banna |
collection | DOAJ |
description | In the title complex, [Ni(C23H21N2O2)2], the central NiII atom is located on an inversion centre and exhibits a slightly distorted square-planar N2O2 coordination environment. A trans-configuration of the N,O chelating ligands results from the imposed site symmetry of the central NiII atom. In the crystal, individual molecules stack along the a axis through weak π–π stacking interactions between the phenyl rings. |
first_indexed | 2024-04-12T10:03:30Z |
format | Article |
id | doaj.art-b66a0c90958f41fea76d5c591ed4cc98 |
institution | Directory Open Access Journal |
issn | 2056-9890 |
language | English |
last_indexed | 2024-04-12T10:03:30Z |
publishDate | 2022-10-01 |
publisher | International Union of Crystallography |
record_format | Article |
series | Acta Crystallographica Section E: Crystallographic Communications |
spelling | doaj.art-b66a0c90958f41fea76d5c591ed4cc982022-12-22T03:37:30ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902022-10-0178101081108310.1107/S2056989022009392wm5661Crystal structure of bis{4-[(4-methylbenzyl)oxy]-N′-(4-methylbenzylidene)benzohydrazidato}nickel(II)Md. Hasan Al Banna0Md. Belayet Hossain Howlader1Ryuta Miyatake2Md. Chanmiya Sheikh3Ennio Zangrando4Department of Chemistry, Rajshahi University, Rajshahi-6205, BangladeshDepartment of Chemistry, Rajshahi University, Rajshahi-6205, BangladeshCenter for Environmental Conservation and Research Safety, University of Toyama, 3190 Gofuku, Toyama, 930-8555, JapanDepartment of Applied Science, Faculty of Science, Okayama University of Science, JapanDepartment of Chemical and Pharmaceutical SCiences, University of Trieste, ItalyIn the title complex, [Ni(C23H21N2O2)2], the central NiII atom is located on an inversion centre and exhibits a slightly distorted square-planar N2O2 coordination environment. A trans-configuration of the N,O chelating ligands results from the imposed site symmetry of the central NiII atom. In the crystal, individual molecules stack along the a axis through weak π–π stacking interactions between the phenyl rings.http://scripts.iucr.org/cgi-bin/paper?S2056989022009392crystal structurenickel(ii) complexsquare-planar coordinationaroylhydrazone ligand |
spellingShingle | Md. Hasan Al Banna Md. Belayet Hossain Howlader Ryuta Miyatake Md. Chanmiya Sheikh Ennio Zangrando Crystal structure of bis{4-[(4-methylbenzyl)oxy]-N′-(4-methylbenzylidene)benzohydrazidato}nickel(II) Acta Crystallographica Section E: Crystallographic Communications crystal structure nickel(ii) complex square-planar coordination aroylhydrazone ligand |
title | Crystal structure of bis{4-[(4-methylbenzyl)oxy]-N′-(4-methylbenzylidene)benzohydrazidato}nickel(II) |
title_full | Crystal structure of bis{4-[(4-methylbenzyl)oxy]-N′-(4-methylbenzylidene)benzohydrazidato}nickel(II) |
title_fullStr | Crystal structure of bis{4-[(4-methylbenzyl)oxy]-N′-(4-methylbenzylidene)benzohydrazidato}nickel(II) |
title_full_unstemmed | Crystal structure of bis{4-[(4-methylbenzyl)oxy]-N′-(4-methylbenzylidene)benzohydrazidato}nickel(II) |
title_short | Crystal structure of bis{4-[(4-methylbenzyl)oxy]-N′-(4-methylbenzylidene)benzohydrazidato}nickel(II) |
title_sort | crystal structure of bis 4 4 methylbenzyl oxy n 4 methylbenzylidene benzohydrazidato nickel ii |
topic | crystal structure nickel(ii) complex square-planar coordination aroylhydrazone ligand |
url | http://scripts.iucr.org/cgi-bin/paper?S2056989022009392 |
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