Investigating use of chlorine dioxide for pre-treatment of raw water from polluted sources at Morton Jaffray Water Treatment Works, Harare, Zimbabwe

Raw water quality deterioration has affected capabilities of Conventional Water Treatment Processes (CWTP) in many countries. CWTP used at Morton Jaffray Water Treatment Works (MJWTW) in Harare have proven ineffective due to pollution. The study investigated the use of chlorine dioxide (ClO2) as an...

Full description

Bibliographic Details
Main Authors: Zvikomborero Hoko, Tariro N. Toto, Clarence Farai Mapenzauswa, Tamuka Nhiwatiwa, Lisben Chipfunde, Sylvester Hunguru
Format: Article
Language:English
Published: IWA Publishing 2021-10-01
Series:Water Practice and Technology
Subjects:
Online Access:http://wpt.iwaponline.com/content/16/4/1290
_version_ 1818742186440654848
author Zvikomborero Hoko
Tariro N. Toto
Clarence Farai Mapenzauswa
Tamuka Nhiwatiwa
Lisben Chipfunde
Sylvester Hunguru
author_facet Zvikomborero Hoko
Tariro N. Toto
Clarence Farai Mapenzauswa
Tamuka Nhiwatiwa
Lisben Chipfunde
Sylvester Hunguru
author_sort Zvikomborero Hoko
collection DOAJ
description Raw water quality deterioration has affected capabilities of Conventional Water Treatment Processes (CWTP) in many countries. CWTP used at Morton Jaffray Water Treatment Works (MJWTW) in Harare have proven ineffective due to pollution. The study investigated the use of chlorine dioxide (ClO2) as an alternative pre-treatment chemical. Its effectiveness was compared to that of calcium hypochlorite (Ca(CIO)2) used at MJWTW. Grab raw water samples from MJWTW were collected between January and March 2020 and pre-treated with ClO2 and Ca(CIO)2 followed by jar tests with alum to determine pre-treatment effectiveness. Parameters analyzed included electrical conductivity (EC), total dissolved solids (TDS), total solids (TS), turbidity, chemical oxygen demand (COD), pH and total algae counts (TAC). The raw water had mean TDS (264 mg/L), TS (440 mg/L), turbidity (7.1 NTU), COD (85 mg/L), pH (7.9) and TAC (28.4 × 106 cells/mL). The optimum alum dosage without pre-oxidation was 80 mg/L. Pre-oxidation with 0.075 mg/L ClO2 reduced alum dosage to 60 mg/L. This ClO2 dosage was compared to a Ca(CIO)2 dosage of the same concentration and strength at 5 and 15-minutes contact time before alum dosage at 60 mg/L. The treated water quality parameter levels proved better performance for ClO2 compared to calcium hypochlorite. HIGHLIGHTS Raw water quality deterioration in Lake Chivero has complicated treatment and treatment costs.; Chemicals currently used have become ineffective including calcium hypochlorite, which creates risk of formation of carcinogenic compounds.; Chlorine dioxide was considered an an alternative as it has been used widely elsewhere, enhances coagulation compared to calcium hypochlorite, and thus is likely to be economic.;
first_indexed 2024-12-18T02:08:31Z
format Article
id doaj.art-b6727337085c44d0927ccdf73151b015
institution Directory Open Access Journal
issn 1751-231X
language English
last_indexed 2024-12-18T02:08:31Z
publishDate 2021-10-01
publisher IWA Publishing
record_format Article
series Water Practice and Technology
spelling doaj.art-b6727337085c44d0927ccdf73151b0152022-12-21T21:24:33ZengIWA PublishingWater Practice and Technology1751-231X2021-10-011641290130610.2166/wpt.2021.077077Investigating use of chlorine dioxide for pre-treatment of raw water from polluted sources at Morton Jaffray Water Treatment Works, Harare, ZimbabweZvikomborero Hoko0Tariro N. Toto1Clarence Farai Mapenzauswa2Tamuka Nhiwatiwa3Lisben Chipfunde4Sylvester Hunguru5 University of Zimbabwe, Department of Construction and Civil Engineering, Box MP 167, Mt Pleasant, Harare, Zimbabwe Boltgas, 58A Steven Drive, Box 59A, Msasa, Harare, Zimbabwe Boltgas, 58A Steven Drive, Box 59A, Msasa, Harare, Zimbabwe University of Zimbabwe, Biological Sciences Department, Box MP 167, Mt Pleasant, Harare, Zimbabwe City of Harare City Environment Management Unit, Town Clerk's Office, P. O. Box 990, Julius Nyerere Way Town House, Harare, Zimbabwe Boltgas, 58A Steven Drive, Box 59A, Msasa, Harare, Zimbabwe Raw water quality deterioration has affected capabilities of Conventional Water Treatment Processes (CWTP) in many countries. CWTP used at Morton Jaffray Water Treatment Works (MJWTW) in Harare have proven ineffective due to pollution. The study investigated the use of chlorine dioxide (ClO2) as an alternative pre-treatment chemical. Its effectiveness was compared to that of calcium hypochlorite (Ca(CIO)2) used at MJWTW. Grab raw water samples from MJWTW were collected between January and March 2020 and pre-treated with ClO2 and Ca(CIO)2 followed by jar tests with alum to determine pre-treatment effectiveness. Parameters analyzed included electrical conductivity (EC), total dissolved solids (TDS), total solids (TS), turbidity, chemical oxygen demand (COD), pH and total algae counts (TAC). The raw water had mean TDS (264 mg/L), TS (440 mg/L), turbidity (7.1 NTU), COD (85 mg/L), pH (7.9) and TAC (28.4 × 106 cells/mL). The optimum alum dosage without pre-oxidation was 80 mg/L. Pre-oxidation with 0.075 mg/L ClO2 reduced alum dosage to 60 mg/L. This ClO2 dosage was compared to a Ca(CIO)2 dosage of the same concentration and strength at 5 and 15-minutes contact time before alum dosage at 60 mg/L. The treated water quality parameter levels proved better performance for ClO2 compared to calcium hypochlorite. HIGHLIGHTS Raw water quality deterioration in Lake Chivero has complicated treatment and treatment costs.; Chemicals currently used have become ineffective including calcium hypochlorite, which creates risk of formation of carcinogenic compounds.; Chlorine dioxide was considered an an alternative as it has been used widely elsewhere, enhances coagulation compared to calcium hypochlorite, and thus is likely to be economic.;http://wpt.iwaponline.com/content/16/4/1290calcium hypochloritechlorine dioxidemorton jaffray water treatment workspre-treatmentraw waterwater quality
spellingShingle Zvikomborero Hoko
Tariro N. Toto
Clarence Farai Mapenzauswa
Tamuka Nhiwatiwa
Lisben Chipfunde
Sylvester Hunguru
Investigating use of chlorine dioxide for pre-treatment of raw water from polluted sources at Morton Jaffray Water Treatment Works, Harare, Zimbabwe
Water Practice and Technology
calcium hypochlorite
chlorine dioxide
morton jaffray water treatment works
pre-treatment
raw water
water quality
title Investigating use of chlorine dioxide for pre-treatment of raw water from polluted sources at Morton Jaffray Water Treatment Works, Harare, Zimbabwe
title_full Investigating use of chlorine dioxide for pre-treatment of raw water from polluted sources at Morton Jaffray Water Treatment Works, Harare, Zimbabwe
title_fullStr Investigating use of chlorine dioxide for pre-treatment of raw water from polluted sources at Morton Jaffray Water Treatment Works, Harare, Zimbabwe
title_full_unstemmed Investigating use of chlorine dioxide for pre-treatment of raw water from polluted sources at Morton Jaffray Water Treatment Works, Harare, Zimbabwe
title_short Investigating use of chlorine dioxide for pre-treatment of raw water from polluted sources at Morton Jaffray Water Treatment Works, Harare, Zimbabwe
title_sort investigating use of chlorine dioxide for pre treatment of raw water from polluted sources at morton jaffray water treatment works harare zimbabwe
topic calcium hypochlorite
chlorine dioxide
morton jaffray water treatment works
pre-treatment
raw water
water quality
url http://wpt.iwaponline.com/content/16/4/1290
work_keys_str_mv AT zvikomborerohoko investigatinguseofchlorinedioxideforpretreatmentofrawwaterfrompollutedsourcesatmortonjaffraywatertreatmentworkshararezimbabwe
AT tarirontoto investigatinguseofchlorinedioxideforpretreatmentofrawwaterfrompollutedsourcesatmortonjaffraywatertreatmentworkshararezimbabwe
AT clarencefaraimapenzauswa investigatinguseofchlorinedioxideforpretreatmentofrawwaterfrompollutedsourcesatmortonjaffraywatertreatmentworkshararezimbabwe
AT tamukanhiwatiwa investigatinguseofchlorinedioxideforpretreatmentofrawwaterfrompollutedsourcesatmortonjaffraywatertreatmentworkshararezimbabwe
AT lisbenchipfunde investigatinguseofchlorinedioxideforpretreatmentofrawwaterfrompollutedsourcesatmortonjaffraywatertreatmentworkshararezimbabwe
AT sylvesterhunguru investigatinguseofchlorinedioxideforpretreatmentofrawwaterfrompollutedsourcesatmortonjaffraywatertreatmentworkshararezimbabwe