Crystal structure of 1-(2,6-diisopropylphenyl)-1H-imidazole
The crystal structure of the title compound, C15H20N2 or DippIm, is reported. At 106 (2) K, the molecule has monoclinic P21/c symmetry with four molecules in the unit cell. The imidazole ring is rotated 80.7 (1)° relative to the phenyl ring. Intermolecular stabilization primarily results from close...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2023-11-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989023009179 |
| _version_ | 1797635694796996608 |
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| author | Neil Dudeja Briana C. Arreaga Jacob P. Brannon S. Chantal E. Stieber |
| author_facet | Neil Dudeja Briana C. Arreaga Jacob P. Brannon S. Chantal E. Stieber |
| author_sort | Neil Dudeja |
| collection | DOAJ |
| description | The crystal structure of the title compound, C15H20N2 or DippIm, is reported. At 106 (2) K, the molecule has monoclinic P21/c symmetry with four molecules in the unit cell. The imidazole ring is rotated 80.7 (1)° relative to the phenyl ring. Intermolecular stabilization primarily results from close contacts between the N atom at the 3-position on the imidazole ring and the C—H bond at the 4-position on the neighboring DippIm, with aryl–aryl distances outside of the accepted distance of 5 Å for π-stacking. |
| first_indexed | 2024-03-11T12:24:05Z |
| format | Article |
| id | doaj.art-b67b848a7ef7465686b8da3603a0e6d5 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-03-11T12:24:05Z |
| publishDate | 2023-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-b67b848a7ef7465686b8da3603a0e6d52023-11-06T14:46:42ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902023-11-0179111079108210.1107/S2056989023009179oi2001Crystal structure of 1-(2,6-diisopropylphenyl)-1H-imidazoleNeil Dudeja0Briana C. Arreaga1Jacob P. Brannon2S. Chantal E. Stieber3Department of Chemistry & Biochemistry, California State Polytechnic University, Pomona, 3801 W. Temple Ave., Pomona, CA 91768, USADepartment of Chemistry & Biochemistry, California State Polytechnic University, Pomona, 3801 W. Temple Ave., Pomona, CA 91768, USADepartment of Chemistry & Biochemistry, California State Polytechnic University, Pomona, 3801 W. Temple Ave., Pomona, CA 91768, USADepartment of Chemistry & Biochemistry, California State Polytechnic University, Pomona, 3801 W. Temple Ave., Pomona, CA 91768, USAThe crystal structure of the title compound, C15H20N2 or DippIm, is reported. At 106 (2) K, the molecule has monoclinic P21/c symmetry with four molecules in the unit cell. The imidazole ring is rotated 80.7 (1)° relative to the phenyl ring. Intermolecular stabilization primarily results from close contacts between the N atom at the 3-position on the imidazole ring and the C—H bond at the 4-position on the neighboring DippIm, with aryl–aryl distances outside of the accepted distance of 5 Å for π-stacking.http://scripts.iucr.org/cgi-bin/paper?S2056989023009179crystal structuredippimimidazolearyl imidazole |
| spellingShingle | Neil Dudeja Briana C. Arreaga Jacob P. Brannon S. Chantal E. Stieber Crystal structure of 1-(2,6-diisopropylphenyl)-1H-imidazole Acta Crystallographica Section E: Crystallographic Communications crystal structure dippim imidazole aryl imidazole |
| title | Crystal structure of 1-(2,6-diisopropylphenyl)-1H-imidazole |
| title_full | Crystal structure of 1-(2,6-diisopropylphenyl)-1H-imidazole |
| title_fullStr | Crystal structure of 1-(2,6-diisopropylphenyl)-1H-imidazole |
| title_full_unstemmed | Crystal structure of 1-(2,6-diisopropylphenyl)-1H-imidazole |
| title_short | Crystal structure of 1-(2,6-diisopropylphenyl)-1H-imidazole |
| title_sort | crystal structure of 1 2 6 diisopropylphenyl 1h imidazole |
| topic | crystal structure dippim imidazole aryl imidazole |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989023009179 |
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