Influence of the thickness of the copper glaze layer on the color and its formation mechanism
In this paper, the effects of glaze layer thickness on the color properties of copper glaze were investigated, and the related mechanism was also revealed. The results manifest that the glaze thickness would affect the color of copper glaze. The color properties of copper glaze are determined by the...
Main Authors: | , , , , , , , , |
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Format: | Article |
Language: | English |
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IOP Publishing
2022-01-01
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Series: | Materials Research Express |
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Online Access: | https://doi.org/10.1088/2053-1591/ac7f10 |
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author | Chao Wang Kun Liu Xin Chen Wei Shi Xiaohong Li Shaohua Wang Qibing Chang Yongqing Wang Qikun Wang |
author_facet | Chao Wang Kun Liu Xin Chen Wei Shi Xiaohong Li Shaohua Wang Qibing Chang Yongqing Wang Qikun Wang |
author_sort | Chao Wang |
collection | DOAJ |
description | In this paper, the effects of glaze layer thickness on the color properties of copper glaze were investigated, and the related mechanism was also revealed. The results manifest that the glaze thickness would affect the color of copper glaze. The color properties of copper glaze are determined by the phase-separated structure, the distribution of elements and the valence state of copper species. Due to the heterogeneous distribution behavior of the elements, the copper glazes with all thicknesses have three phase-separated structures, which are spherical (top layer), worm-like (interlayer) and nano-porous network-like (bottom layer). Simultaneously, the copper glazes with all thicknesses have three colors, of which the bottom layer of all samples is red. However, the color of the top layer gradually changes from milk white (0.2 mm) to cyan (0.4–0.6 mm) and then to blue (0.8–1.0 mm) with the green body thickness increases. The color of interlayer is the result of the color mixing of the top and bottom layer. A thicker green body thickness (>1 mm) could be propitious for copper glaze to present a superior color performance. This work provides a new and an easily overlooked perspective for the investigation of copper glaze. |
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institution | Directory Open Access Journal |
issn | 2053-1591 |
language | English |
last_indexed | 2024-03-12T15:36:37Z |
publishDate | 2022-01-01 |
publisher | IOP Publishing |
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series | Materials Research Express |
spelling | doaj.art-b68cb9a58125462b88a5fd79bd227dac2023-08-09T16:12:09ZengIOP PublishingMaterials Research Express2053-15912022-01-019808500110.1088/2053-1591/ac7f10Influence of the thickness of the copper glaze layer on the color and its formation mechanismChao Wang0Kun Liu1Xin Chen2Wei Shi3Xiaohong Li4Shaohua Wang5Qibing Chang6Yongqing Wang7Qikun Wang8School of Materials Science and Engineering, Jingdezhen Ceramic University , Jingdezhen 333403, People’s Republic of ChinaSchool of Materials Science and Engineering, Jingdezhen Ceramic University , Jingdezhen 333403, People’s Republic of ChinaJingdezhen Ambitious Banding Materials Co., Ltd., Jingdezhen 333403, People’s Republic of ChinaNational Engineering Research Center for Domestic and Building Ceramics, Jingdezhen Ceramic University , Jingdezhen 333000, People’s Republic of ChinaNational Engineering Research Center for Domestic and Building Ceramics, Jingdezhen Ceramic University , Jingdezhen 333000, People’s Republic of ChinaSchool of Materials Science and Engineering, Jingdezhen Ceramic University , Jingdezhen 333403, People’s Republic of ChinaSchool of Materials Science and Engineering, Jingdezhen Ceramic University , Jingdezhen 333403, People’s Republic of ChinaSchool of Materials Science and Engineering, Jingdezhen Ceramic University , Jingdezhen 333403, People’s Republic of ChinaSchool of Materials Science and Engineering, Jingdezhen Ceramic University , Jingdezhen 333403, People’s Republic of China; Jingdezhen Ambitious Banding Materials Co., Ltd., Jingdezhen 333403, People’s Republic of ChinaIn this paper, the effects of glaze layer thickness on the color properties of copper glaze were investigated, and the related mechanism was also revealed. The results manifest that the glaze thickness would affect the color of copper glaze. The color properties of copper glaze are determined by the phase-separated structure, the distribution of elements and the valence state of copper species. Due to the heterogeneous distribution behavior of the elements, the copper glazes with all thicknesses have three phase-separated structures, which are spherical (top layer), worm-like (interlayer) and nano-porous network-like (bottom layer). Simultaneously, the copper glazes with all thicknesses have three colors, of which the bottom layer of all samples is red. However, the color of the top layer gradually changes from milk white (0.2 mm) to cyan (0.4–0.6 mm) and then to blue (0.8–1.0 mm) with the green body thickness increases. The color of interlayer is the result of the color mixing of the top and bottom layer. A thicker green body thickness (>1 mm) could be propitious for copper glaze to present a superior color performance. This work provides a new and an easily overlooked perspective for the investigation of copper glaze.https://doi.org/10.1088/2053-1591/ac7f10glazethicknessphase separationcopper speciesmicrostructure |
spellingShingle | Chao Wang Kun Liu Xin Chen Wei Shi Xiaohong Li Shaohua Wang Qibing Chang Yongqing Wang Qikun Wang Influence of the thickness of the copper glaze layer on the color and its formation mechanism Materials Research Express glaze thickness phase separation copper species microstructure |
title | Influence of the thickness of the copper glaze layer on the color and its formation mechanism |
title_full | Influence of the thickness of the copper glaze layer on the color and its formation mechanism |
title_fullStr | Influence of the thickness of the copper glaze layer on the color and its formation mechanism |
title_full_unstemmed | Influence of the thickness of the copper glaze layer on the color and its formation mechanism |
title_short | Influence of the thickness of the copper glaze layer on the color and its formation mechanism |
title_sort | influence of the thickness of the copper glaze layer on the color and its formation mechanism |
topic | glaze thickness phase separation copper species microstructure |
url | https://doi.org/10.1088/2053-1591/ac7f10 |
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