Tris(3-chloropentane-2,4-dionato-κ2O,O′)iron(III)
In the title compound, [Fe(C5H6ClO2)3], the FeIII cation is situated on a twofold rotation axis and is coordinated by six O atoms from three 3-chloropentane-2,4-dionate ligands in a slightly distorted octahedral environment. Fe—O bond lengths are in the range 1.9818 (18)&...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812023215 |
| _version_ | 1818500484879613952 |
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| author | Franc Perdih |
| author_facet | Franc Perdih |
| author_sort | Franc Perdih |
| collection | DOAJ |
| description | In the title compound, [Fe(C5H6ClO2)3], the FeIII cation is situated on a twofold rotation axis and is coordinated by six O atoms from three 3-chloropentane-2,4-dionate ligands in a slightly distorted octahedral environment. Fe—O bond lengths are in the range 1.9818 (18)–1.9957 (18) Å. The trans O—Fe—O angles are 169.06 (13) and 171.54 (8)°, whereas the corresponding cis angles are in the range 84.81 (10)–100.68 (12)°. In the crystal, molecules are linked via C—H...Cl interactions. |
| first_indexed | 2024-12-10T20:43:20Z |
| format | Article |
| id | doaj.art-b691d2be7b3e473193f5c01d7236a00f |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T20:43:20Z |
| publishDate | 2012-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-b691d2be7b3e473193f5c01d7236a00f2022-12-22T01:34:18ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-06-01686m807m80710.1107/S1600536812023215Tris(3-chloropentane-2,4-dionato-κ2O,O′)iron(III)Franc PerdihIn the title compound, [Fe(C5H6ClO2)3], the FeIII cation is situated on a twofold rotation axis and is coordinated by six O atoms from three 3-chloropentane-2,4-dionate ligands in a slightly distorted octahedral environment. Fe—O bond lengths are in the range 1.9818 (18)–1.9957 (18) Å. The trans O—Fe—O angles are 169.06 (13) and 171.54 (8)°, whereas the corresponding cis angles are in the range 84.81 (10)–100.68 (12)°. In the crystal, molecules are linked via C—H...Cl interactions.http://scripts.iucr.org/cgi-bin/paper?S1600536812023215 |
| spellingShingle | Franc Perdih Tris(3-chloropentane-2,4-dionato-κ2O,O′)iron(III) Acta Crystallographica Section E |
| title | Tris(3-chloropentane-2,4-dionato-κ2O,O′)iron(III) |
| title_full | Tris(3-chloropentane-2,4-dionato-κ2O,O′)iron(III) |
| title_fullStr | Tris(3-chloropentane-2,4-dionato-κ2O,O′)iron(III) |
| title_full_unstemmed | Tris(3-chloropentane-2,4-dionato-κ2O,O′)iron(III) |
| title_short | Tris(3-chloropentane-2,4-dionato-κ2O,O′)iron(III) |
| title_sort | tris 3 chloropentane 2 4 dionato amp 954 2o o amp 8242 iron iii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812023215 |
| work_keys_str_mv | AT francperdih tris3chloropentane24dionatoamp9542ooamp8242ironiii |