Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal–metal bond
Dilanthanide complexes that possess radical bridges exhibit enhanced magnetic exchange coupling, affording molecular magnets with high blocking temperatures. Here, the authors explore a series of dilanthanide-encapsulated fullerenes where the radical bridge is taken to its limit and the role is play...
| Main Authors: | , , , , , , , , , , , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2019-02-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-019-08513-6 |
| _version_ | 1819036148690845696 |
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| author | Fupin Liu Georgios Velkos Denis S. Krylov Lukas Spree Michal Zalibera Rajyavardhan Ray Nataliya A. Samoylova Chia-Hsiang Chen Marco Rosenkranz Sandra Schiemenz Frank Ziegs Konstantin Nenkov Aram Kostanyan Thomas Greber Anja U. B. Wolter Manuel Richter Bernd Büchner Stanislav M. Avdoshenko Alexey A. Popov |
| author_facet | Fupin Liu Georgios Velkos Denis S. Krylov Lukas Spree Michal Zalibera Rajyavardhan Ray Nataliya A. Samoylova Chia-Hsiang Chen Marco Rosenkranz Sandra Schiemenz Frank Ziegs Konstantin Nenkov Aram Kostanyan Thomas Greber Anja U. B. Wolter Manuel Richter Bernd Büchner Stanislav M. Avdoshenko Alexey A. Popov |
| author_sort | Fupin Liu |
| collection | DOAJ |
| description | Dilanthanide complexes that possess radical bridges exhibit enhanced magnetic exchange coupling, affording molecular magnets with high blocking temperatures. Here, the authors explore a series of dilanthanide-encapsulated fullerenes where the radical bridge is taken to its limit and the role is played by a single unpaired electron. |
| first_indexed | 2024-12-21T08:00:55Z |
| format | Article |
| id | doaj.art-b6952e66d5a64cf88a905e377b3b0ea0 |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-12-21T08:00:55Z |
| publishDate | 2019-02-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-b6952e66d5a64cf88a905e377b3b0ea02022-12-21T19:10:54ZengNature PortfolioNature Communications2041-17232019-02-0110111110.1038/s41467-019-08513-6Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal–metal bondFupin Liu0Georgios Velkos1Denis S. Krylov2Lukas Spree3Michal Zalibera4Rajyavardhan Ray5Nataliya A. Samoylova6Chia-Hsiang Chen7Marco Rosenkranz8Sandra Schiemenz9Frank Ziegs10Konstantin Nenkov11Aram Kostanyan12Thomas Greber13Anja U. B. Wolter14Manuel Richter15Bernd Büchner16Stanislav M. Avdoshenko17Alexey A. Popov18Leibniz Institute for Solid State and Materials Research (IFW Dresden)Leibniz Institute for Solid State and Materials Research (IFW Dresden)Leibniz Institute for Solid State and Materials Research (IFW Dresden)Leibniz Institute for Solid State and Materials Research (IFW Dresden)Institute of Physical Chemistry and Chemical Physics, Slovak University of TechnologyLeibniz Institute for Solid State and Materials Research (IFW Dresden)Leibniz Institute for Solid State and Materials Research (IFW Dresden)Leibniz Institute for Solid State and Materials Research (IFW Dresden)Leibniz Institute for Solid State and Materials Research (IFW Dresden)Leibniz Institute for Solid State and Materials Research (IFW Dresden)Leibniz Institute for Solid State and Materials Research (IFW Dresden)Leibniz Institute for Solid State and Materials Research (IFW Dresden)Physik-Institut der Universität ZürichPhysik-Institut der Universität ZürichLeibniz Institute for Solid State and Materials Research (IFW Dresden)Leibniz Institute for Solid State and Materials Research (IFW Dresden)Leibniz Institute for Solid State and Materials Research (IFW Dresden)Leibniz Institute for Solid State and Materials Research (IFW Dresden)Leibniz Institute for Solid State and Materials Research (IFW Dresden)Dilanthanide complexes that possess radical bridges exhibit enhanced magnetic exchange coupling, affording molecular magnets with high blocking temperatures. Here, the authors explore a series of dilanthanide-encapsulated fullerenes where the radical bridge is taken to its limit and the role is played by a single unpaired electron.https://doi.org/10.1038/s41467-019-08513-6 |
| spellingShingle | Fupin Liu Georgios Velkos Denis S. Krylov Lukas Spree Michal Zalibera Rajyavardhan Ray Nataliya A. Samoylova Chia-Hsiang Chen Marco Rosenkranz Sandra Schiemenz Frank Ziegs Konstantin Nenkov Aram Kostanyan Thomas Greber Anja U. B. Wolter Manuel Richter Bernd Büchner Stanislav M. Avdoshenko Alexey A. Popov Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal–metal bond Nature Communications |
| title | Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal–metal bond |
| title_full | Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal–metal bond |
| title_fullStr | Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal–metal bond |
| title_full_unstemmed | Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal–metal bond |
| title_short | Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal–metal bond |
| title_sort | air stable redox active nanomagnets with lanthanide spins radical bridged by a metal metal bond |
| url | https://doi.org/10.1038/s41467-019-08513-6 |
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