Nanocompósitos eletroativos de poli-o-metoxianilina e polissacarídeos naturais Electroactive nanocomposites made of poly (o-methoxyaniline) and natural polysaccharides

<abstract language="eng">In this work we take advantage of the polyelectrolyte character of some Brazilian native gums to fabricate electrically conductive, nanostructured films. The gums Sterculia urens, (caraia), Sterculia striata (chicha) or Anadenanthera macrocarpa Benth were ass...

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Main Authors: Carla Eiras, Ionara Nayana Gomes Passos, Ana Cristina Facundo de Brito, José Ribeiro dos Santos Júnior, Valtencir Zucolotto, Osvaldo N. Oliveira Jr, Igor L. Kitagawa, Carlos J. L. Constantino, Helder Nunes da Cunha
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2007-10-01
Series:Química Nova
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422007000500020
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author Carla Eiras
Ionara Nayana Gomes Passos
Ana Cristina Facundo de Brito
José Ribeiro dos Santos Júnior
Valtencir Zucolotto
Osvaldo N. Oliveira Jr
Igor L. Kitagawa
Carlos J. L. Constantino
Helder Nunes da Cunha
author_facet Carla Eiras
Ionara Nayana Gomes Passos
Ana Cristina Facundo de Brito
José Ribeiro dos Santos Júnior
Valtencir Zucolotto
Osvaldo N. Oliveira Jr
Igor L. Kitagawa
Carlos J. L. Constantino
Helder Nunes da Cunha
author_sort Carla Eiras
collection DOAJ
description <abstract language="eng">In this work we take advantage of the polyelectrolyte character of some Brazilian native gums to fabricate electrically conductive, nanostructured films. The gums Sterculia urens, (caraia), Sterculia striata (chicha) or Anadenanthera macrocarpa Benth were assembled in conjunction with poly(o-methoxyaniline) (POMA) in the form of layered nanostructured films using the layer-by-layer (LbL) technique. All the LbL films displayed a well-defined electroactivity, as confirmed via cyclic voltammetry. In comparison to POMA LbL films fabricated with conventional polyelectrolytes (viz. poly(vinyl sulfonic acid)-PVS), the presence of the gums in the LbL films increased remarkably the electrochemical stability of the films.
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spelling doaj.art-b6a3831580994564973fd759d97d9d762022-12-21T23:29:48ZengSociedade Brasileira de QuímicaQuímica Nova0100-40421678-70642007-10-013051158116210.1590/S0100-40422007000500020Nanocompósitos eletroativos de poli-o-metoxianilina e polissacarídeos naturais Electroactive nanocomposites made of poly (o-methoxyaniline) and natural polysaccharidesCarla EirasIonara Nayana Gomes PassosAna Cristina Facundo de BritoJosé Ribeiro dos Santos JúniorValtencir ZucolottoOsvaldo N. Oliveira JrIgor L. KitagawaCarlos J. L. ConstantinoHelder Nunes da Cunha<abstract language="eng">In this work we take advantage of the polyelectrolyte character of some Brazilian native gums to fabricate electrically conductive, nanostructured films. The gums Sterculia urens, (caraia), Sterculia striata (chicha) or Anadenanthera macrocarpa Benth were assembled in conjunction with poly(o-methoxyaniline) (POMA) in the form of layered nanostructured films using the layer-by-layer (LbL) technique. All the LbL films displayed a well-defined electroactivity, as confirmed via cyclic voltammetry. In comparison to POMA LbL films fabricated with conventional polyelectrolytes (viz. poly(vinyl sulfonic acid)-PVS), the presence of the gums in the LbL films increased remarkably the electrochemical stability of the films.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422007000500020natural gumspoly-o-methoxyanilinelayer-by-layer films
spellingShingle Carla Eiras
Ionara Nayana Gomes Passos
Ana Cristina Facundo de Brito
José Ribeiro dos Santos Júnior
Valtencir Zucolotto
Osvaldo N. Oliveira Jr
Igor L. Kitagawa
Carlos J. L. Constantino
Helder Nunes da Cunha
Nanocompósitos eletroativos de poli-o-metoxianilina e polissacarídeos naturais Electroactive nanocomposites made of poly (o-methoxyaniline) and natural polysaccharides
Química Nova
natural gums
poly-o-methoxyaniline
layer-by-layer films
title Nanocompósitos eletroativos de poli-o-metoxianilina e polissacarídeos naturais Electroactive nanocomposites made of poly (o-methoxyaniline) and natural polysaccharides
title_full Nanocompósitos eletroativos de poli-o-metoxianilina e polissacarídeos naturais Electroactive nanocomposites made of poly (o-methoxyaniline) and natural polysaccharides
title_fullStr Nanocompósitos eletroativos de poli-o-metoxianilina e polissacarídeos naturais Electroactive nanocomposites made of poly (o-methoxyaniline) and natural polysaccharides
title_full_unstemmed Nanocompósitos eletroativos de poli-o-metoxianilina e polissacarídeos naturais Electroactive nanocomposites made of poly (o-methoxyaniline) and natural polysaccharides
title_short Nanocompósitos eletroativos de poli-o-metoxianilina e polissacarídeos naturais Electroactive nanocomposites made of poly (o-methoxyaniline) and natural polysaccharides
title_sort nanocompositos eletroativos de poli o metoxianilina e polissacarideos naturais electroactive nanocomposites made of poly o methoxyaniline and natural polysaccharides
topic natural gums
poly-o-methoxyaniline
layer-by-layer films
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422007000500020
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