$n$-selective Tsuji–Trost allylation promoted by a recyclable TSIL-palladium complex

$n$-selective Tsuji–Trost allylation promoted by a recyclable TSIL-palladium complex

The Tsuji–Trost reaction of allylic acetates with nucleophiles is optimized using a task-specific ionic liquid (TSIL)-palladium complex in a very efficient manner. Several nucleophiles and allylic systems are studied obtaining very high yields of the corresponding products with total $n$-selectivity...

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Bibliographic Details
Main Authors: Lledó, David, Grindlay, Guillermo, Sansano, José M.
Format: Article
Language:English
Published: Académie des sciences 2022-02-01
Series:Comptes Rendus. Chimie
Subjects:
Tsuji–Trost
Coupling
Palladium
TSIL
Deacetylative allylation
Online Access:https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.134/

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