Dynamics of hindered CF3-rotor in 2,5-bis (trifl uoromethyl )-nitroben zene radical -anion in anhydro us DMF. A temperature - activation theory of reversible HFS transformations of EPR spectrum
The temperature dependence of EPR spectrum of 2,5-bis(trifluoromethyl)nitrobenzene radical anion in anhydrous DMF was investigated. Internal dynamics of hindered rotation of the CF3-group in ortho-position to NO2-group causes HFS modulation. The spectrum changes are reversible and temperature-depend...
| Main Authors: | , |
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| Format: | Article |
| Language: | Russian |
| Published: |
MIREA - Russian Technological University
2016-06-01
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| Series: | Тонкие химические технологии |
| Subjects: | |
| Online Access: | https://www.finechem-mirea.ru/jour/article/view/27 |