{N,N-Dimethyl-N′-[1-(2-pyridyl)ethylidene]propane-1,3-diamine}bis(thiocyanato-κN)copper(II)
In the title complex, [Cu(NCS)2(C12H19N3)], the CuII atom is five-coordinated in a square-pyramidal geometry defined by one pyridine N, one imine N, and one amine N atom of the tridentate Schiff base ligand and two N-bonded thiocyanate ions (one of the latter occupying the apical site). The three br...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810036378 |
| _version_ | 1818286063242706944 |
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| author | Qin-Long Peng Li-Hua Chen Yong-Jun Han Gan-Qing Zhao Ling-Wei Xue |
| author_facet | Qin-Long Peng Li-Hua Chen Yong-Jun Han Gan-Qing Zhao Ling-Wei Xue |
| author_sort | Qin-Long Peng |
| collection | DOAJ |
| description | In the title complex, [Cu(NCS)2(C12H19N3)], the CuII atom is five-coordinated in a square-pyramidal geometry defined by one pyridine N, one imine N, and one amine N atom of the tridentate Schiff base ligand and two N-bonded thiocyanate ions (one of the latter occupying the apical site). The three bridging C atoms and the two terminal C atoms of the Schiff base are disordered over two sets of sites, with occupancies of 0.465 (2) and 0.535 (2). |
| first_indexed | 2024-12-13T01:18:38Z |
| format | Article |
| id | doaj.art-b6ab128900e547708308e9c070377bfa |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T01:18:38Z |
| publishDate | 2010-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-b6ab128900e547708308e9c070377bfa2022-12-22T00:04:17ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-10-016610m1274m127410.1107/S1600536810036378{N,N-Dimethyl-N′-[1-(2-pyridyl)ethylidene]propane-1,3-diamine}bis(thiocyanato-κN)copper(II)Qin-Long PengLi-Hua ChenYong-Jun HanGan-Qing ZhaoLing-Wei XueIn the title complex, [Cu(NCS)2(C12H19N3)], the CuII atom is five-coordinated in a square-pyramidal geometry defined by one pyridine N, one imine N, and one amine N atom of the tridentate Schiff base ligand and two N-bonded thiocyanate ions (one of the latter occupying the apical site). The three bridging C atoms and the two terminal C atoms of the Schiff base are disordered over two sets of sites, with occupancies of 0.465 (2) and 0.535 (2).http://scripts.iucr.org/cgi-bin/paper?S1600536810036378 |
| spellingShingle | Qin-Long Peng Li-Hua Chen Yong-Jun Han Gan-Qing Zhao Ling-Wei Xue {N,N-Dimethyl-N′-[1-(2-pyridyl)ethylidene]propane-1,3-diamine}bis(thiocyanato-κN)copper(II) Acta Crystallographica Section E |
| title | {N,N-Dimethyl-N′-[1-(2-pyridyl)ethylidene]propane-1,3-diamine}bis(thiocyanato-κN)copper(II) |
| title_full | {N,N-Dimethyl-N′-[1-(2-pyridyl)ethylidene]propane-1,3-diamine}bis(thiocyanato-κN)copper(II) |
| title_fullStr | {N,N-Dimethyl-N′-[1-(2-pyridyl)ethylidene]propane-1,3-diamine}bis(thiocyanato-κN)copper(II) |
| title_full_unstemmed | {N,N-Dimethyl-N′-[1-(2-pyridyl)ethylidene]propane-1,3-diamine}bis(thiocyanato-κN)copper(II) |
| title_short | {N,N-Dimethyl-N′-[1-(2-pyridyl)ethylidene]propane-1,3-diamine}bis(thiocyanato-κN)copper(II) |
| title_sort | n n dimethyl n amp 8242 1 2 pyridyl ethylidene propane 1 3 diamine bis thiocyanato amp 954 n copper ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810036378 |
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