Tris(2,2′-bipyridine)cobalt(II) μ6-oxido-dodeca-μ2-oxido-hexaoxidohexamolydate(VI)
In the title compound, [Co(C10H8N2)3][Mo6O19], the Co2+ cation is surrounded in a distorted octahedral coordination by six N atoms from three 2,2′-bipyridine ligands. The distribution of Mo—O bond lengths in the Lindqvist isopolyanion is consistent with other structures c...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810020775 |
| _version_ | 1830230715118125056 |
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| author | Ying Liu Xianxi Zhang Zechun Xue Jian Sheng |
| author_facet | Ying Liu Xianxi Zhang Zechun Xue Jian Sheng |
| author_sort | Ying Liu |
| collection | DOAJ |
| description | In the title compound, [Co(C10H8N2)3][Mo6O19], the Co2+ cation is surrounded in a distorted octahedral coordination by six N atoms from three 2,2′-bipyridine ligands. The distribution of Mo—O bond lengths in the Lindqvist isopolyanion is consistent with other structures containing the same unit. In the crystal, the cations and anions are linked by C—H...O interactions. |
| first_indexed | 2024-12-18T10:58:19Z |
| format | Article |
| id | doaj.art-b6c40e53ee044026be688151e483c421 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-18T10:58:19Z |
| publishDate | 2010-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-b6c40e53ee044026be688151e483c4212022-12-21T21:10:16ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-07-01667m756m75710.1107/S1600536810020775Tris(2,2′-bipyridine)cobalt(II) μ6-oxido-dodeca-μ2-oxido-hexaoxidohexamolydate(VI)Ying LiuXianxi ZhangZechun XueJian ShengIn the title compound, [Co(C10H8N2)3][Mo6O19], the Co2+ cation is surrounded in a distorted octahedral coordination by six N atoms from three 2,2′-bipyridine ligands. The distribution of Mo—O bond lengths in the Lindqvist isopolyanion is consistent with other structures containing the same unit. In the crystal, the cations and anions are linked by C—H...O interactions.http://scripts.iucr.org/cgi-bin/paper?S1600536810020775 |
| spellingShingle | Ying Liu Xianxi Zhang Zechun Xue Jian Sheng Tris(2,2′-bipyridine)cobalt(II) μ6-oxido-dodeca-μ2-oxido-hexaoxidohexamolydate(VI) Acta Crystallographica Section E |
| title | Tris(2,2′-bipyridine)cobalt(II) μ6-oxido-dodeca-μ2-oxido-hexaoxidohexamolydate(VI) |
| title_full | Tris(2,2′-bipyridine)cobalt(II) μ6-oxido-dodeca-μ2-oxido-hexaoxidohexamolydate(VI) |
| title_fullStr | Tris(2,2′-bipyridine)cobalt(II) μ6-oxido-dodeca-μ2-oxido-hexaoxidohexamolydate(VI) |
| title_full_unstemmed | Tris(2,2′-bipyridine)cobalt(II) μ6-oxido-dodeca-μ2-oxido-hexaoxidohexamolydate(VI) |
| title_short | Tris(2,2′-bipyridine)cobalt(II) μ6-oxido-dodeca-μ2-oxido-hexaoxidohexamolydate(VI) |
| title_sort | tris 2 2 amp 8242 bipyridine cobalt ii amp 956 6 oxido dodeca amp 956 2 oxido hexaoxidohexamolydate vi |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810020775 |
| work_keys_str_mv | AT yingliu tris22amp8242bipyridinecobaltiiamp9566oxidododecaamp9562oxidohexaoxidohexamolydatevi AT xianxizhang tris22amp8242bipyridinecobaltiiamp9566oxidododecaamp9562oxidohexaoxidohexamolydatevi AT zechunxue tris22amp8242bipyridinecobaltiiamp9566oxidododecaamp9562oxidohexaoxidohexamolydatevi AT jiansheng tris22amp8242bipyridinecobaltiiamp9566oxidododecaamp9562oxidohexaoxidohexamolydatevi |