Bis(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κO)tetrakis(methanol-κO)calcium methanol tetrasolvate
In the title compound, [Ca(C19H11F2O2)2(CH3OH)4]·4CH3OH, the Ca2+ ion is located on an inversion centre and is hexacoordinated by two O atoms of two 4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylate ligands and four O a...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2013-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813000044 |
| _version_ | 1819290522044334080 |
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| author | Namseok Kim Heeso Noh Sungho Yoon Chan Ryang Park |
| author_facet | Namseok Kim Heeso Noh Sungho Yoon Chan Ryang Park |
| author_sort | Namseok Kim |
| collection | DOAJ |
| description | In the title compound, [Ca(C19H11F2O2)2(CH3OH)4]·4CH3OH, the Ca2+ ion is located on an inversion centre and is hexacoordinated by two O atoms of two 4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylate ligands and four O atoms of four methanol ligands, forming a CaO6 polyhedron with a slightly distorted octahedral coordination geometry. The Ca—O—C angle between the carboxylate group and the calcium ion is 171.8 (2)°. Two types of intermolecular hydrogen-bond interactions (C=O...H and O—H...O) between the carboxylate ligand, the methanol solvent molecules and the coordinating methanol ligands generate a two-dimensional network parallel to (001). |
| first_indexed | 2024-12-24T03:24:04Z |
| format | Article |
| id | doaj.art-b6c9f999f0e0495fb206dddd4fc7484e |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T03:24:04Z |
| publishDate | 2013-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-b6c9f999f0e0495fb206dddd4fc7484e2022-12-21T17:17:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-02-01692m122m12310.1107/S1600536813000044Bis(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κO)tetrakis(methanol-κO)calcium methanol tetrasolvateNamseok KimHeeso NohSungho YoonChan Ryang ParkIn the title compound, [Ca(C19H11F2O2)2(CH3OH)4]·4CH3OH, the Ca2+ ion is located on an inversion centre and is hexacoordinated by two O atoms of two 4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylate ligands and four O atoms of four methanol ligands, forming a CaO6 polyhedron with a slightly distorted octahedral coordination geometry. The Ca—O—C angle between the carboxylate group and the calcium ion is 171.8 (2)°. Two types of intermolecular hydrogen-bond interactions (C=O...H and O—H...O) between the carboxylate ligand, the methanol solvent molecules and the coordinating methanol ligands generate a two-dimensional network parallel to (001).http://scripts.iucr.org/cgi-bin/paper?S1600536813000044 |
| spellingShingle | Namseok Kim Heeso Noh Sungho Yoon Chan Ryang Park Bis(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κO)tetrakis(methanol-κO)calcium methanol tetrasolvate Acta Crystallographica Section E |
| title | Bis(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κO)tetrakis(methanol-κO)calcium methanol tetrasolvate |
| title_full | Bis(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κO)tetrakis(methanol-κO)calcium methanol tetrasolvate |
| title_fullStr | Bis(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κO)tetrakis(methanol-κO)calcium methanol tetrasolvate |
| title_full_unstemmed | Bis(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κO)tetrakis(methanol-κO)calcium methanol tetrasolvate |
| title_short | Bis(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κO)tetrakis(methanol-κO)calcium methanol tetrasolvate |
| title_sort | bis 4 4 8242 8242 difluoro 1 1 8242 3 8242 1 8242 8242 terphenyl 2 8242 carboxylato 954 o tetrakis methanol 954 o calcium methanol tetrasolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813000044 |
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