CO Responses of Sensors Based on Cerium Oxide Thick Films Prepared from Clustered Spherical Nanoparticles

Various types of CO sensors based on cerium oxide (ceria) have been reported recently. It has also been reported that the response speed of CO sensors fabricated from porous ceria thick films comprising nanoparticles is extremely high. However, the response value of such sensors is not suitably high...

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Main Authors: Woosuck Shin, Takafumi Akamatsu, Toshio Itoh, Ichiro Matsubara, Noriya Izu
Format: Article
Language:English
Published: MDPI AG 2013-03-01
Series:Sensors
Subjects:
Online Access:http://www.mdpi.com/1424-8220/13/3/3252
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author Woosuck Shin
Takafumi Akamatsu
Toshio Itoh
Ichiro Matsubara
Noriya Izu
author_facet Woosuck Shin
Takafumi Akamatsu
Toshio Itoh
Ichiro Matsubara
Noriya Izu
author_sort Woosuck Shin
collection DOAJ
description Various types of CO sensors based on cerium oxide (ceria) have been reported recently. It has also been reported that the response speed of CO sensors fabricated from porous ceria thick films comprising nanoparticles is extremely high. However, the response value of such sensors is not suitably high. In this study, we investigated methods of improving the response values of CO sensors based on ceria and prepared gas sensors from core-shell ceria polymer hybrid nanoparticles. These hybrid nanoparticles have been reported to have a unique structure: The core consists of a cluster of ceria crystallites several nanometers in size. We compared the characteristics of the sensors based on thick films prepared from core-shell nanoparticles with those of sensors based on thick films prepared from conventionally used precipitated nanoparticles. The sensors prepared from the core-shell nanoparticles exhibited a resistance that was ten times greater than that of the sensors prepared from the precipitated nanoparticles. The response values of the gas sensors based on the core-shell nanoparticles also was higher than that of the sensors based on the precipitated nanoparticles. Finally, improvements in sensor response were also noticed after the addition of Au nanoparticles to the thick films used to fabricate the two types of sensors.
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spelling doaj.art-b6cb09719905480daa333abf8ab681e52022-12-22T02:56:28ZengMDPI AGSensors1424-82202013-03-011333252326110.3390/s130303252CO Responses of Sensors Based on Cerium Oxide Thick Films Prepared from Clustered Spherical NanoparticlesWoosuck ShinTakafumi AkamatsuToshio ItohIchiro MatsubaraNoriya IzuVarious types of CO sensors based on cerium oxide (ceria) have been reported recently. It has also been reported that the response speed of CO sensors fabricated from porous ceria thick films comprising nanoparticles is extremely high. However, the response value of such sensors is not suitably high. In this study, we investigated methods of improving the response values of CO sensors based on ceria and prepared gas sensors from core-shell ceria polymer hybrid nanoparticles. These hybrid nanoparticles have been reported to have a unique structure: The core consists of a cluster of ceria crystallites several nanometers in size. We compared the characteristics of the sensors based on thick films prepared from core-shell nanoparticles with those of sensors based on thick films prepared from conventionally used precipitated nanoparticles. The sensors prepared from the core-shell nanoparticles exhibited a resistance that was ten times greater than that of the sensors prepared from the precipitated nanoparticles. The response values of the gas sensors based on the core-shell nanoparticles also was higher than that of the sensors based on the precipitated nanoparticles. Finally, improvements in sensor response were also noticed after the addition of Au nanoparticles to the thick films used to fabricate the two types of sensors.http://www.mdpi.com/1424-8220/13/3/3252carbon monoxidecerium oxidegas sensorcore-shell nanoparticlesresistive-type sensor
spellingShingle Woosuck Shin
Takafumi Akamatsu
Toshio Itoh
Ichiro Matsubara
Noriya Izu
CO Responses of Sensors Based on Cerium Oxide Thick Films Prepared from Clustered Spherical Nanoparticles
Sensors
carbon monoxide
cerium oxide
gas sensor
core-shell nanoparticles
resistive-type sensor
title CO Responses of Sensors Based on Cerium Oxide Thick Films Prepared from Clustered Spherical Nanoparticles
title_full CO Responses of Sensors Based on Cerium Oxide Thick Films Prepared from Clustered Spherical Nanoparticles
title_fullStr CO Responses of Sensors Based on Cerium Oxide Thick Films Prepared from Clustered Spherical Nanoparticles
title_full_unstemmed CO Responses of Sensors Based on Cerium Oxide Thick Films Prepared from Clustered Spherical Nanoparticles
title_short CO Responses of Sensors Based on Cerium Oxide Thick Films Prepared from Clustered Spherical Nanoparticles
title_sort co responses of sensors based on cerium oxide thick films prepared from clustered spherical nanoparticles
topic carbon monoxide
cerium oxide
gas sensor
core-shell nanoparticles
resistive-type sensor
url http://www.mdpi.com/1424-8220/13/3/3252
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AT toshioitoh coresponsesofsensorsbasedonceriumoxidethickfilmspreparedfromclusteredsphericalnanoparticles
AT ichiromatsubara coresponsesofsensorsbasedonceriumoxidethickfilmspreparedfromclusteredsphericalnanoparticles
AT noriyaizu coresponsesofsensorsbasedonceriumoxidethickfilmspreparedfromclusteredsphericalnanoparticles