Spectral and kinetic characteristics of ultrathin cadmium selenide nanoscrolls

We have studied the optical and luminescence properties at room temperature of ultrathin colloidal semiconductor cadmium selenide nanoscrolls with a thickness of 2.5 monolayers. For colloidal synthesis of the objects under study, cadmium acetate dihydrate Cd(CH3COO)2·2H2O and trioctylphosphine sel...

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Main Author: Daniil S. Daibagya
Format: Article
Language:English
Published: Saint Petersburg National Research University of Information Technologies, Mechanics and Optics (ITMO University) 2023-10-01
Series:Naučno-tehničeskij Vestnik Informacionnyh Tehnologij, Mehaniki i Optiki
Subjects:
Online Access:https://ntv.ifmo.ru/file/article/22363.pdf
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author Daniil S. Daibagya
author_facet Daniil S. Daibagya
author_sort Daniil S. Daibagya
collection DOAJ
description We have studied the optical and luminescence properties at room temperature of ultrathin colloidal semiconductor cadmium selenide nanoscrolls with a thickness of 2.5 monolayers. For colloidal synthesis of the objects under study, cadmium acetate dihydrate Cd(CH3COO)2·2H2O and trioctylphosphine selenide were used as precursors of cadmium and selenium, respectively, and solutions of oleic acid and octadecene were also used. Luminescence spectrum of cadmium selenide nanoscrolls was recorded using a fiber charge coupled device spectrometer. Spectrally resolved photoluminescence decays for nanoparticles were measured with the use of time-correlated single photon counting technique. The emission of the cadmium selenide nanoscrolls consists of interband and recombination luminescence bands. We found that the normalized photon numbers of recombination luminescence are larger than the normalized photon numbers of interband luminescence. We determined dominant wavelengths, chromaticity coordinates, and correlated color temperatures of ultrathin colloidal semiconductor cadmium selenide nanoscrolls. These ultrathin cadmium selenide nanoscrolls are promising for application in light-emitting diodes.
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spelling doaj.art-b6dbad144c814dd080a05951f5ad53b82023-10-18T11:21:25ZengSaint Petersburg National Research University of Information Technologies, Mechanics and Optics (ITMO University)Naučno-tehničeskij Vestnik Informacionnyh Tehnologij, Mehaniki i Optiki2226-14942500-03732023-10-0123592092610.17586/2226-1494-2023-23-5-920-926Spectral and kinetic characteristics of ultrathin cadmium selenide nanoscrollsDaniil S. Daibagya 0https://orcid.org/0000-0003-1944-1546Junior Researcher, P.N. Lebedev Physical Institute of the Russian Academy of Sciences, Moscow, 119991, Russian Federation; Assistant, Moscow Polytechnic University, Moscow, 107023, Russian Federation; Assistant, Bauman Moscow State Technical University, Moscow, 105005, Russian Federation, sc 57673090900We have studied the optical and luminescence properties at room temperature of ultrathin colloidal semiconductor cadmium selenide nanoscrolls with a thickness of 2.5 monolayers. For colloidal synthesis of the objects under study, cadmium acetate dihydrate Cd(CH3COO)2·2H2O and trioctylphosphine selenide were used as precursors of cadmium and selenium, respectively, and solutions of oleic acid and octadecene were also used. Luminescence spectrum of cadmium selenide nanoscrolls was recorded using a fiber charge coupled device spectrometer. Spectrally resolved photoluminescence decays for nanoparticles were measured with the use of time-correlated single photon counting technique. The emission of the cadmium selenide nanoscrolls consists of interband and recombination luminescence bands. We found that the normalized photon numbers of recombination luminescence are larger than the normalized photon numbers of interband luminescence. We determined dominant wavelengths, chromaticity coordinates, and correlated color temperatures of ultrathin colloidal semiconductor cadmium selenide nanoscrolls. These ultrathin cadmium selenide nanoscrolls are promising for application in light-emitting diodes.https://ntv.ifmo.ru/file/article/22363.pdfphotoluminescencenanoparticlesnanoscrollscadmium selenidechromaticity coordinatescolor puritycorrelated color temperature
spellingShingle Daniil S. Daibagya
Spectral and kinetic characteristics of ultrathin cadmium selenide nanoscrolls
Naučno-tehničeskij Vestnik Informacionnyh Tehnologij, Mehaniki i Optiki
photoluminescence
nanoparticles
nanoscrolls
cadmium selenide
chromaticity coordinates
color purity
correlated color temperature
title Spectral and kinetic characteristics of ultrathin cadmium selenide nanoscrolls
title_full Spectral and kinetic characteristics of ultrathin cadmium selenide nanoscrolls
title_fullStr Spectral and kinetic characteristics of ultrathin cadmium selenide nanoscrolls
title_full_unstemmed Spectral and kinetic characteristics of ultrathin cadmium selenide nanoscrolls
title_short Spectral and kinetic characteristics of ultrathin cadmium selenide nanoscrolls
title_sort spectral and kinetic characteristics of ultrathin cadmium selenide nanoscrolls
topic photoluminescence
nanoparticles
nanoscrolls
cadmium selenide
chromaticity coordinates
color purity
correlated color temperature
url https://ntv.ifmo.ru/file/article/22363.pdf
work_keys_str_mv AT daniilsdaibagya spectralandkineticcharacteristicsofultrathincadmiumselenidenanoscrolls