High-pressure high-temperature synthesis and structure of α-tetragonal boron

Microcrystals of α-tetragonal (α-t) boron with unit cell parameters a=9.05077(6) and c=5.13409(6) Å and measured density 2.16–2.22 g cm−3 were obtained by pyrolysis of decaborane B10H14 at pressures of 8–9 GPa and temperatures of 1100–1600 C. The crystal structure is in good agreement with the model...

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Detalles Bibliográficos
Autor Principal: Evgeny A Ekimov and Igor P Zibrov
Formato: Artigo
Idioma:English
Publicado: Taylor & Francis Group 2011-01-01
Series:Science and Technology of Advanced Materials
Acceso en liña:http://iopscience.iop.org/1468-6996/12/5/055009