High-pressure high-temperature synthesis and structure of α-tetragonal boron

Microcrystals of α-tetragonal (α-t) boron with unit cell parameters a=9.05077(6) and c=5.13409(6) Å and measured density 2.16–2.22 g cm−3 were obtained by pyrolysis of decaborane B10H14 at pressures of 8–9 GPa and temperatures of 1100–1600 C. The crystal structure is in good agreement with the model...

Ausführliche Beschreibung

Bibliographische Detailangaben
1. Verfasser: Evgeny A Ekimov and Igor P Zibrov
Format: Artikel
Sprache:English
Veröffentlicht: Taylor & Francis Group 2011-01-01
Schriftenreihe:Science and Technology of Advanced Materials
Online Zugang:http://iopscience.iop.org/1468-6996/12/5/055009