1,4-Bis[3,11-dithiatricyclo[11.3.1.15,9]octadeca-1(17),5,7,9(18),13,15-hexaen-7-yl]buta-1,3-diyne
The complete molecule of the title compound, C36H30S4 {common name: 1,4-[4-(9,17-dithia[3.3]metacyclophane)]-1,3-butadiyne}, is generated by a crystallographic inversion centre at the mid-point of the central C—C bond [1.367 (5) Å]. Both cyclophane units exist in cisoid pseudo-boat–chair chair–boat...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2016-09-01
|
| Series: | IUCrData |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S241431461601378X |
| _version_ | 1818992149597782016 |
|---|---|
| author | Tetsuji Moriguchi Daisuke Yakeya Venkataprasad Jalli Akihiko Tsuge |
| author_facet | Tetsuji Moriguchi Daisuke Yakeya Venkataprasad Jalli Akihiko Tsuge |
| author_sort | Tetsuji Moriguchi |
| collection | DOAJ |
| description | The complete molecule of the title compound, C36H30S4 {common name: 1,4-[4-(9,17-dithia[3.3]metacyclophane)]-1,3-butadiyne}, is generated by a crystallographic inversion centre at the mid-point of the central C—C bond [1.367 (5) Å]. Both cyclophane units exist in cisoid pseudo-boat–chair chair–boat conformations. In the crystal, the packing is controlled by van der Waals interactions. |
| first_indexed | 2024-12-20T20:21:34Z |
| format | Article |
| id | doaj.art-b6ec00862db348c3b5777cc1c3aece2b |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-20T20:21:34Z |
| publishDate | 2016-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-b6ec00862db348c3b5777cc1c3aece2b2022-12-21T19:27:33ZengInternational Union of CrystallographyIUCrData2414-31462016-09-0119x16137810.1107/S241431461601378Xhb40711,4-Bis[3,11-dithiatricyclo[11.3.1.15,9]octadeca-1(17),5,7,9(18),13,15-hexaen-7-yl]buta-1,3-diyneTetsuji Moriguchi0Daisuke Yakeya1Venkataprasad Jalli2Akihiko Tsuge3Department of Applied Chemistry, Graduate School of Engineering, Kyushu Institute of Technology, 1-1 Sensui-cho, Tobata-ku, Kitakyushu 804-8550, JapanDepartment of Applied Chemistry, Graduate School of Engineering, Kyushu Institute of Technology, 1-1 Sensui-cho, Tobata-ku, Kitakyushu 804-8550, JapanDepartment of Applied Chemistry, Graduate School of Engineering, Kyushu Institute of Technology, 1-1 Sensui-cho, Tobata-ku, Kitakyushu 804-8550, JapanDepartment of Applied Chemistry, Graduate School of Engineering, Kyushu Institute of Technology, 1-1 Sensui-cho, Tobata-ku, Kitakyushu 804-8550, JapanThe complete molecule of the title compound, C36H30S4 {common name: 1,4-[4-(9,17-dithia[3.3]metacyclophane)]-1,3-butadiyne}, is generated by a crystallographic inversion centre at the mid-point of the central C—C bond [1.367 (5) Å]. Both cyclophane units exist in cisoid pseudo-boat–chair chair–boat conformations. In the crystal, the packing is controlled by van der Waals interactions.http://scripts.iucr.org/cgi-bin/paper?S241431461601378Xcrystal structurecyclophanebutadiyne |
| spellingShingle | Tetsuji Moriguchi Daisuke Yakeya Venkataprasad Jalli Akihiko Tsuge 1,4-Bis[3,11-dithiatricyclo[11.3.1.15,9]octadeca-1(17),5,7,9(18),13,15-hexaen-7-yl]buta-1,3-diyne IUCrData crystal structure cyclophane butadiyne |
| title | 1,4-Bis[3,11-dithiatricyclo[11.3.1.15,9]octadeca-1(17),5,7,9(18),13,15-hexaen-7-yl]buta-1,3-diyne |
| title_full | 1,4-Bis[3,11-dithiatricyclo[11.3.1.15,9]octadeca-1(17),5,7,9(18),13,15-hexaen-7-yl]buta-1,3-diyne |
| title_fullStr | 1,4-Bis[3,11-dithiatricyclo[11.3.1.15,9]octadeca-1(17),5,7,9(18),13,15-hexaen-7-yl]buta-1,3-diyne |
| title_full_unstemmed | 1,4-Bis[3,11-dithiatricyclo[11.3.1.15,9]octadeca-1(17),5,7,9(18),13,15-hexaen-7-yl]buta-1,3-diyne |
| title_short | 1,4-Bis[3,11-dithiatricyclo[11.3.1.15,9]octadeca-1(17),5,7,9(18),13,15-hexaen-7-yl]buta-1,3-diyne |
| title_sort | 1 4 bis 3 11 dithiatricyclo 11 3 1 15 9 octadeca 1 17 5 7 9 18 13 15 hexaen 7 yl buta 1 3 diyne |
| topic | crystal structure cyclophane butadiyne |
| url | http://scripts.iucr.org/cgi-bin/paper?S241431461601378X |
| work_keys_str_mv | AT tetsujimoriguchi 14bis311dithiatricyclo1131159octadeca117579181315hexaen7ylbuta13diyne AT daisukeyakeya 14bis311dithiatricyclo1131159octadeca117579181315hexaen7ylbuta13diyne AT venkataprasadjalli 14bis311dithiatricyclo1131159octadeca117579181315hexaen7ylbuta13diyne AT akihikotsuge 14bis311dithiatricyclo1131159octadeca117579181315hexaen7ylbuta13diyne |