Synthesis and Structural Characterization of the Sodium Salt of a New Sulfonate-containing Water Soluble N-Donor Ligand⎯ Self-assembly in the Solid State by À−À Stacking Interactions
The synthesis, spectroscopic characterization, and X-ray crystal structure ofthe sodium salt of a new sulfonated water-soluble ligand, sodium 2-(2-pyridin-2-yl-ethylamino)-benzenesulfonate (L) are described. Compound L crystallizes in thecentrosymmetric space group Pbcn, orthorhombic, a=31.930(13) Ã...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2006-02-01
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| Series: | Molecules |
| Subjects: | |
| Online Access: | http://www.mdpi.com/1420-3049/11/2/163/ |
| Summary: | The synthesis, spectroscopic characterization, and X-ray crystal structure ofthe sodium salt of a new sulfonated water-soluble ligand, sodium 2-(2-pyridin-2-yl-ethylamino)-benzenesulfonate (L) are described. Compound L crystallizes in thecentrosymmetric space group Pbcn, orthorhombic, a=31.930(13) Ã¥, b=7.153(3) Ã¥,c=14.193(6) Ã¥, α=90.00, β=90.00, γ=90.00, V=3220(2) Ã¥3, Z=9. À−À stacking contactsinvolving interactions between the À-donor benzene and the À-acceptor pyridine systemsreinforce and direct the self-assembly of the structural motifs in the solid state. |
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| ISSN: | 1420-3049 |