Synthesis and Structural Characterization of the Sodium Salt of a New Sulfonate-containing Water Soluble N-Donor Ligand⎯ Self-assembly in the Solid State by À−À Stacking Interactions
The synthesis, spectroscopic characterization, and X-ray crystal structure ofthe sodium salt of a new sulfonated water-soluble ligand, sodium 2-(2-pyridin-2-yl-ethylamino)-benzenesulfonate (L) are described. Compound L crystallizes in thecentrosymmetric space group Pbcn, orthorhombic, a=31.930(13) Ã...
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| Format: | Article |
| Language: | English |
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MDPI AG
2006-02-01
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| Series: | Molecules |
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| Online Access: | http://www.mdpi.com/1420-3049/11/2/163/ |
| _version_ | 1818900958861590528 |
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| author | Hong-Chang Liang Yonglian Zhang |
| author_facet | Hong-Chang Liang Yonglian Zhang |
| author_sort | Hong-Chang Liang |
| collection | DOAJ |
| description | The synthesis, spectroscopic characterization, and X-ray crystal structure ofthe sodium salt of a new sulfonated water-soluble ligand, sodium 2-(2-pyridin-2-yl-ethylamino)-benzenesulfonate (L) are described. Compound L crystallizes in thecentrosymmetric space group Pbcn, orthorhombic, a=31.930(13) Ã¥, b=7.153(3) Ã¥,c=14.193(6) Ã¥, α=90.00, β=90.00, γ=90.00, V=3220(2) Ã¥3, Z=9. À−À stacking contactsinvolving interactions between the À-donor benzene and the À-acceptor pyridine systemsreinforce and direct the self-assembly of the structural motifs in the solid state. |
| first_indexed | 2024-12-19T20:12:08Z |
| format | Article |
| id | doaj.art-b6f5bf57a6014e44ad2aae1e1b564a1f |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-12-19T20:12:08Z |
| publishDate | 2006-02-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-b6f5bf57a6014e44ad2aae1e1b564a1f2022-12-21T20:07:16ZengMDPI AGMolecules1420-30492006-02-0111216316810.3390/11020163Synthesis and Structural Characterization of the Sodium Salt of a New Sulfonate-containing Water Soluble N-Donor Ligand⎯ Self-assembly in the Solid State by À−À Stacking InteractionsHong-Chang LiangYonglian ZhangThe synthesis, spectroscopic characterization, and X-ray crystal structure ofthe sodium salt of a new sulfonated water-soluble ligand, sodium 2-(2-pyridin-2-yl-ethylamino)-benzenesulfonate (L) are described. Compound L crystallizes in thecentrosymmetric space group Pbcn, orthorhombic, a=31.930(13) Ã¥, b=7.153(3) Ã¥,c=14.193(6) Ã¥, α=90.00, β=90.00, γ=90.00, V=3220(2) Ã¥3, Z=9. À−À stacking contactsinvolving interactions between the À-donor benzene and the À-acceptor pyridine systemsreinforce and direct the self-assembly of the structural motifs in the solid state.http://www.mdpi.com/1420-3049/11/2/163/SulfonateWater-soluble LigandÀ−À StackingMichael-type Addition. |
| spellingShingle | Hong-Chang Liang Yonglian Zhang Synthesis and Structural Characterization of the Sodium Salt of a New Sulfonate-containing Water Soluble N-Donor Ligand⎯ Self-assembly in the Solid State by À−À Stacking Interactions Molecules Sulfonate Water-soluble Ligand À−À Stacking Michael-type Addition. |
| title | Synthesis and Structural Characterization of the Sodium Salt of a New Sulfonate-containing Water Soluble N-Donor Ligand⎯ Self-assembly in the Solid State by À−À Stacking Interactions |
| title_full | Synthesis and Structural Characterization of the Sodium Salt of a New Sulfonate-containing Water Soluble N-Donor Ligand⎯ Self-assembly in the Solid State by À−À Stacking Interactions |
| title_fullStr | Synthesis and Structural Characterization of the Sodium Salt of a New Sulfonate-containing Water Soluble N-Donor Ligand⎯ Self-assembly in the Solid State by À−À Stacking Interactions |
| title_full_unstemmed | Synthesis and Structural Characterization of the Sodium Salt of a New Sulfonate-containing Water Soluble N-Donor Ligand⎯ Self-assembly in the Solid State by À−À Stacking Interactions |
| title_short | Synthesis and Structural Characterization of the Sodium Salt of a New Sulfonate-containing Water Soluble N-Donor Ligand⎯ Self-assembly in the Solid State by À−À Stacking Interactions |
| title_sort | synthesis and structural characterization of the sodium salt of a new sulfonate containing water soluble n donor liganda¢aza¯ self assembly in the solid state by aa€a¢a a aa€ stacking interactions |
| topic | Sulfonate Water-soluble Ligand À−À Stacking Michael-type Addition. |
| url | http://www.mdpi.com/1420-3049/11/2/163/ |
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