Photoelectrochemical Properties of CuS-GeO2-TiO2 Composite Coating Electrode.

The ITO (indium tin oxide) conductive glass-matrix CuS-GeO2-TiO2 composite coating was generated via EPD (electrophoretic deposition) and followed by a sintering treatment at 450°C for 40 minutes. Characterizations of the CuS-GeO2-TiO2 composite coating were taken by SEM (scanning electron microscop...

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Main Authors: Xinyu Wen, Huawei Zhang
Format: Article
Language:English
Published: Public Library of Science (PLoS) 2016-01-01
Series:PLoS ONE
Online Access:http://europepmc.org/articles/PMC4824510?pdf=render
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author Xinyu Wen
Huawei Zhang
author_facet Xinyu Wen
Huawei Zhang
author_sort Xinyu Wen
collection DOAJ
description The ITO (indium tin oxide) conductive glass-matrix CuS-GeO2-TiO2 composite coating was generated via EPD (electrophoretic deposition) and followed by a sintering treatment at 450°C for 40 minutes. Characterizations of the CuS-GeO2-TiO2 composite coating were taken by SEM (scanning electron microscope), XRD (X-ray diffraction), EDX (energy dispersive X-ray), UV-Vis DRS (ultraviolet-visible diffuse reflection spectrum), and FT-IR (Fourier transform infrared spectroscopy). Results showed that CuS and GeO2 had dispersed in this CuS-GeO2-TiO2 composite coating (mass percentages for CuS and GeO2 were 1.23% and 2.79%, respectively). The electrochemical studies (cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and Tafel polarization) of this CuS-GeO2-TiO2 composite coating electrode were performed in pH = 9.51 Na2CO3-NaHCO3 buffer solution containing 0.50 mol/L CH3OH under the conditions of visible light, ultraviolet light (λ = 365 nm), and dark (without light irradiation as control), respectively. Electrochemical studies indicated that this CuS-GeO2-TiO2 composite coating electrode had better photoelectrocatalytic activity than the pure TiO2 electrode in the electrocatalysis of methanol under visible light.
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spelling doaj.art-b707f3f56da1424185c07424a9d23b4a2022-12-22T01:05:05ZengPublic Library of Science (PLoS)PLoS ONE1932-62032016-01-01114e015286210.1371/journal.pone.0152862Photoelectrochemical Properties of CuS-GeO2-TiO2 Composite Coating Electrode.Xinyu WenHuawei ZhangThe ITO (indium tin oxide) conductive glass-matrix CuS-GeO2-TiO2 composite coating was generated via EPD (electrophoretic deposition) and followed by a sintering treatment at 450°C for 40 minutes. Characterizations of the CuS-GeO2-TiO2 composite coating were taken by SEM (scanning electron microscope), XRD (X-ray diffraction), EDX (energy dispersive X-ray), UV-Vis DRS (ultraviolet-visible diffuse reflection spectrum), and FT-IR (Fourier transform infrared spectroscopy). Results showed that CuS and GeO2 had dispersed in this CuS-GeO2-TiO2 composite coating (mass percentages for CuS and GeO2 were 1.23% and 2.79%, respectively). The electrochemical studies (cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and Tafel polarization) of this CuS-GeO2-TiO2 composite coating electrode were performed in pH = 9.51 Na2CO3-NaHCO3 buffer solution containing 0.50 mol/L CH3OH under the conditions of visible light, ultraviolet light (λ = 365 nm), and dark (without light irradiation as control), respectively. Electrochemical studies indicated that this CuS-GeO2-TiO2 composite coating electrode had better photoelectrocatalytic activity than the pure TiO2 electrode in the electrocatalysis of methanol under visible light.http://europepmc.org/articles/PMC4824510?pdf=render
spellingShingle Xinyu Wen
Huawei Zhang
Photoelectrochemical Properties of CuS-GeO2-TiO2 Composite Coating Electrode.
PLoS ONE
title Photoelectrochemical Properties of CuS-GeO2-TiO2 Composite Coating Electrode.
title_full Photoelectrochemical Properties of CuS-GeO2-TiO2 Composite Coating Electrode.
title_fullStr Photoelectrochemical Properties of CuS-GeO2-TiO2 Composite Coating Electrode.
title_full_unstemmed Photoelectrochemical Properties of CuS-GeO2-TiO2 Composite Coating Electrode.
title_short Photoelectrochemical Properties of CuS-GeO2-TiO2 Composite Coating Electrode.
title_sort photoelectrochemical properties of cus geo2 tio2 composite coating electrode
url http://europepmc.org/articles/PMC4824510?pdf=render
work_keys_str_mv AT xinyuwen photoelectrochemicalpropertiesofcusgeo2tio2compositecoatingelectrode
AT huaweizhang photoelectrochemicalpropertiesofcusgeo2tio2compositecoatingelectrode