K0.78Na0.22MoO2AsO4
The title compound, potassium sodium dioxidomolybdenum(VI) arsenate, K0.78Na0.22MoO2AsO4, was synthesized by a solid-state reaction route. The structure is built up from corner-sharing MoO6 octahedra and AsO4 tetrahedra, creating infinite [MoAsO8]∞ chains running along the b-axis direction...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2013-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813018540 |
| _version_ | 1798031563910283264 |
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| author | Ahmed Driss Mohamed Faouzi Zid Chahira Bouzidi Raja Jouini |
| author_facet | Ahmed Driss Mohamed Faouzi Zid Chahira Bouzidi Raja Jouini |
| author_sort | Ahmed Driss |
| collection | DOAJ |
| description | The title compound, potassium sodium dioxidomolybdenum(VI) arsenate, K0.78Na0.22MoO2AsO4, was synthesized by a solid-state reaction route. The structure is built up from corner-sharing MoO6 octahedra and AsO4 tetrahedra, creating infinite [MoAsO8]∞ chains running along the b-axis direction. As, Mo and all but one O atom are on special positions (4c) with m symmetry and K (occupancy 0.78) is on a position (4a) of -1 in the tunnels. The possible motion of the alkali cations has been investigated by means of the bond-valance sum (BVS) model. The simulation shows that the Na+ motion appears to be easier mainly along the b-axis direction. Structural relationships between the different compounds of the AMoO2AsO4 (A = Ag, Li, Na, K, Rb) series and MXO8 (M = V; X = P, As) chains are discussed. |
| first_indexed | 2024-04-11T19:59:27Z |
| format | Article |
| id | doaj.art-b73fd5d37a1540ec9aae87abd6ebc58f |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T19:59:27Z |
| publishDate | 2013-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-b73fd5d37a1540ec9aae87abd6ebc58f2022-12-22T04:05:43ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-08-01698i47i4710.1107/S1600536813018540K0.78Na0.22MoO2AsO4Ahmed DrissMohamed Faouzi ZidChahira BouzidiRaja JouiniThe title compound, potassium sodium dioxidomolybdenum(VI) arsenate, K0.78Na0.22MoO2AsO4, was synthesized by a solid-state reaction route. The structure is built up from corner-sharing MoO6 octahedra and AsO4 tetrahedra, creating infinite [MoAsO8]∞ chains running along the b-axis direction. As, Mo and all but one O atom are on special positions (4c) with m symmetry and K (occupancy 0.78) is on a position (4a) of -1 in the tunnels. The possible motion of the alkali cations has been investigated by means of the bond-valance sum (BVS) model. The simulation shows that the Na+ motion appears to be easier mainly along the b-axis direction. Structural relationships between the different compounds of the AMoO2AsO4 (A = Ag, Li, Na, K, Rb) series and MXO8 (M = V; X = P, As) chains are discussed.http://scripts.iucr.org/cgi-bin/paper?S1600536813018540 |
| spellingShingle | Ahmed Driss Mohamed Faouzi Zid Chahira Bouzidi Raja Jouini K0.78Na0.22MoO2AsO4 Acta Crystallographica Section E |
| title | K0.78Na0.22MoO2AsO4 |
| title_full | K0.78Na0.22MoO2AsO4 |
| title_fullStr | K0.78Na0.22MoO2AsO4 |
| title_full_unstemmed | K0.78Na0.22MoO2AsO4 |
| title_short | K0.78Na0.22MoO2AsO4 |
| title_sort | k0 78na0 22moo2aso4 |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813018540 |
| work_keys_str_mv | AT ahmeddriss k078na022moo2aso4 AT mohamedfaouzizid k078na022moo2aso4 AT chahirabouzidi k078na022moo2aso4 AT rajajouini k078na022moo2aso4 |