Crystal structure of 1-(2-chloroacetyl)-2,6-bis(4-fluorophenyl)-3,3-dimethylpiperidin-4-one
In the title molecule, C21H20ClF2NO2, the piperidine ring adopts a slightly distorted boat conformation. The two benzene rings form a dihedral angle of 87.43 (1)°. A weak intramolecular C—H...π interaction is observed. In the crystal, weak C—H...O hydrogen bonds and weak C—H...π interactions connect...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014-10-01
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| Series: | Acta Crystallographica Section E |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814021278 |
| _version_ | 1818958832901029888 |
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| author | S. Jothivel Jibon Kotoky S. Kabilan |
| author_facet | S. Jothivel Jibon Kotoky S. Kabilan |
| author_sort | S. Jothivel |
| collection | DOAJ |
| description | In the title molecule, C21H20ClF2NO2, the piperidine ring adopts a slightly distorted boat conformation. The two benzene rings form a dihedral angle of 87.43 (1)°. A weak intramolecular C—H...π interaction is observed. In the crystal, weak C—H...O hydrogen bonds and weak C—H...π interactions connect the molecules, forming a three-dimensional network. |
| first_indexed | 2024-12-20T11:32:01Z |
| format | Article |
| id | doaj.art-b755a8a770fb48299db9b4d630afa31f |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:32:01Z |
| publishDate | 2014-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-b755a8a770fb48299db9b4d630afa31f2022-12-21T19:42:14ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-10-01701026226410.1107/S1600536814021278lh5727Crystal structure of 1-(2-chloroacetyl)-2,6-bis(4-fluorophenyl)-3,3-dimethylpiperidin-4-oneS. Jothivel0Jibon Kotoky1S. Kabilan2Department of Chemistry, Annamalai University, Annamalainagar 608 002, Chidambaram, Tamil Nadu, IndiaDivision of Life Sciences, Central Instrumentation Facility, Institute of Advanced Study in Science & Technology (IASST), Guwahati 781 035, Assam, IndiaDepartment of Chemistry, Annamalai University, Annamalainagar 608 002, Chidambaram, Tamil Nadu, IndiaIn the title molecule, C21H20ClF2NO2, the piperidine ring adopts a slightly distorted boat conformation. The two benzene rings form a dihedral angle of 87.43 (1)°. A weak intramolecular C—H...π interaction is observed. In the crystal, weak C—H...O hydrogen bonds and weak C—H...π interactions connect the molecules, forming a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536814021278Piperidoneweak hydrogen bondscrystal structure |
| spellingShingle | S. Jothivel Jibon Kotoky S. Kabilan Crystal structure of 1-(2-chloroacetyl)-2,6-bis(4-fluorophenyl)-3,3-dimethylpiperidin-4-one Acta Crystallographica Section E Piperidone weak hydrogen bonds crystal structure |
| title | Crystal structure of 1-(2-chloroacetyl)-2,6-bis(4-fluorophenyl)-3,3-dimethylpiperidin-4-one |
| title_full | Crystal structure of 1-(2-chloroacetyl)-2,6-bis(4-fluorophenyl)-3,3-dimethylpiperidin-4-one |
| title_fullStr | Crystal structure of 1-(2-chloroacetyl)-2,6-bis(4-fluorophenyl)-3,3-dimethylpiperidin-4-one |
| title_full_unstemmed | Crystal structure of 1-(2-chloroacetyl)-2,6-bis(4-fluorophenyl)-3,3-dimethylpiperidin-4-one |
| title_short | Crystal structure of 1-(2-chloroacetyl)-2,6-bis(4-fluorophenyl)-3,3-dimethylpiperidin-4-one |
| title_sort | crystal structure of 1 2 chloroacetyl 2 6 bis 4 fluorophenyl 3 3 dimethylpiperidin 4 one |
| topic | Piperidone weak hydrogen bonds crystal structure |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536814021278 |
| work_keys_str_mv | AT sjothivel crystalstructureof12chloroacetyl26bis4fluorophenyl33dimethylpiperidin4one AT jibonkotoky crystalstructureof12chloroacetyl26bis4fluorophenyl33dimethylpiperidin4one AT skabilan crystalstructureof12chloroacetyl26bis4fluorophenyl33dimethylpiperidin4one |