Thermal and Mechanical Properties of Biocomposites Based on Polylactide and Tall Wheatgrass

Biocomposites based on polylactic acid (PLA), tall wheatgrass (TWG), and hemp (H) were made by injection molding. The article discusses the impact of the agrofiller content on the composite properties, including thermal (DSC, DMA, and TG) and mechanical characteristics (tensile modulus, tensile stre...

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Main Authors: Cezary Gozdecki, Krzysztof Moraczewski, Marek Kociszewski
Format: Article
Language:English
Published: MDPI AG 2023-10-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/16/21/6923
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author Cezary Gozdecki
Krzysztof Moraczewski
Marek Kociszewski
author_facet Cezary Gozdecki
Krzysztof Moraczewski
Marek Kociszewski
author_sort Cezary Gozdecki
collection DOAJ
description Biocomposites based on polylactic acid (PLA), tall wheatgrass (TWG), and hemp (H) were made by injection molding. The article discusses the impact of the agrofiller content on the composite properties, including thermal (DSC, DMA, and TG) and mechanical characteristics (tensile modulus, tensile strength, and impact strength). Generally, the introduction of a plant filler into the polylactide matrix reduced the thermal resistance of the resulting composites. Plant fillers influenced primarily the cold crystallization process, probably due to their nucleating properties. The addition of fillers to the PLA matrix resulted in an increased storage modulus across all tested temperatures compared to pure PLA. In the case of a composite with 50% of plant fillers, it was almost 118%. The mechanical properties of the tested composites depended significantly on the amount of plant filler used. It was observed that adding 50% of plant filler to PLA led to a twofold increase in tensile modulus and a decrease in tensile strength and impact strength by an average of 23 and 70%, respectively. It was determined that composites incorporating tall wheatgrass (TWG) particles exhibited a slightly elevated tensile modulus while showcasing a marginally reduced strength and impact resistance in comparison to composites containing hemp (H) components.
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spelling doaj.art-b7765f9164274134a00890124b7c9f7c2023-11-10T15:07:20ZengMDPI AGMaterials1996-19442023-10-011621692310.3390/ma16216923Thermal and Mechanical Properties of Biocomposites Based on Polylactide and Tall WheatgrassCezary Gozdecki0Krzysztof Moraczewski1Marek Kociszewski2Faculty of Materials Engineering, Kazimierz Wielki University in Bydgoszcz, ul. Chodkiewicza 30, 85-064 Bydgoszcz, PolandFaculty of Materials Engineering, Kazimierz Wielki University in Bydgoszcz, ul. Chodkiewicza 30, 85-064 Bydgoszcz, PolandFaculty of Materials Engineering, Kazimierz Wielki University in Bydgoszcz, ul. Chodkiewicza 30, 85-064 Bydgoszcz, PolandBiocomposites based on polylactic acid (PLA), tall wheatgrass (TWG), and hemp (H) were made by injection molding. The article discusses the impact of the agrofiller content on the composite properties, including thermal (DSC, DMA, and TG) and mechanical characteristics (tensile modulus, tensile strength, and impact strength). Generally, the introduction of a plant filler into the polylactide matrix reduced the thermal resistance of the resulting composites. Plant fillers influenced primarily the cold crystallization process, probably due to their nucleating properties. The addition of fillers to the PLA matrix resulted in an increased storage modulus across all tested temperatures compared to pure PLA. In the case of a composite with 50% of plant fillers, it was almost 118%. The mechanical properties of the tested composites depended significantly on the amount of plant filler used. It was observed that adding 50% of plant filler to PLA led to a twofold increase in tensile modulus and a decrease in tensile strength and impact strength by an average of 23 and 70%, respectively. It was determined that composites incorporating tall wheatgrass (TWG) particles exhibited a slightly elevated tensile modulus while showcasing a marginally reduced strength and impact resistance in comparison to composites containing hemp (H) components.https://www.mdpi.com/1996-1944/16/21/6923biocompositePLAhemptall wheatgrassmechanical propertiesDSC
spellingShingle Cezary Gozdecki
Krzysztof Moraczewski
Marek Kociszewski
Thermal and Mechanical Properties of Biocomposites Based on Polylactide and Tall Wheatgrass
Materials
biocomposite
PLA
hemp
tall wheatgrass
mechanical properties
DSC
title Thermal and Mechanical Properties of Biocomposites Based on Polylactide and Tall Wheatgrass
title_full Thermal and Mechanical Properties of Biocomposites Based on Polylactide and Tall Wheatgrass
title_fullStr Thermal and Mechanical Properties of Biocomposites Based on Polylactide and Tall Wheatgrass
title_full_unstemmed Thermal and Mechanical Properties of Biocomposites Based on Polylactide and Tall Wheatgrass
title_short Thermal and Mechanical Properties of Biocomposites Based on Polylactide and Tall Wheatgrass
title_sort thermal and mechanical properties of biocomposites based on polylactide and tall wheatgrass
topic biocomposite
PLA
hemp
tall wheatgrass
mechanical properties
DSC
url https://www.mdpi.com/1996-1944/16/21/6923
work_keys_str_mv AT cezarygozdecki thermalandmechanicalpropertiesofbiocompositesbasedonpolylactideandtallwheatgrass
AT krzysztofmoraczewski thermalandmechanicalpropertiesofbiocompositesbasedonpolylactideandtallwheatgrass
AT marekkociszewski thermalandmechanicalpropertiesofbiocompositesbasedonpolylactideandtallwheatgrass