SRN1 and Stille Reactions: A New Synthetic Strategy
The photostimulated reaction of Me3Sn- ion with mono, di and trichloro arenes in liquid ammonia gave very good yields of stannanes by the SRN1 mechanism. These products reacted by a palladium-catalized cross coupling reaction with halobenzenes to give phenylated products also in very goods yields. S...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2000-03-01
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| Series: | Molecules |
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| Online Access: | http://www.mdpi.com/1420-3049/5/3/431/ |
| _version_ | 1818950928744579072 |
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| author | Eduardo F. Corsico Roberto A. Rossi |
| author_facet | Eduardo F. Corsico Roberto A. Rossi |
| author_sort | Eduardo F. Corsico |
| collection | DOAJ |
| description | The photostimulated reaction of Me3Sn- ion with mono, di and trichloro arenes in liquid ammonia gave very good yields of stannanes by the SRN1 mechanism. These products reacted by a palladium-catalized cross coupling reaction with halobenzenes to give phenylated products also in very goods yields. Similar yields can be obtained in one-pot reactions. |
| first_indexed | 2024-12-20T09:26:23Z |
| format | Article |
| id | doaj.art-b78a2d347e8d48bc8c2c85207bc732fb |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-12-20T09:26:23Z |
| publishDate | 2000-03-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-b78a2d347e8d48bc8c2c85207bc732fb2022-12-21T19:45:12ZengMDPI AGMolecules1420-30492000-03-015343143210.3390/50300431SRN1 and Stille Reactions: A New Synthetic StrategyEduardo F. CorsicoRoberto A. RossiThe photostimulated reaction of Me3Sn- ion with mono, di and trichloro arenes in liquid ammonia gave very good yields of stannanes by the SRN1 mechanism. These products reacted by a palladium-catalized cross coupling reaction with halobenzenes to give phenylated products also in very goods yields. Similar yields can be obtained in one-pot reactions.http://www.mdpi.com/1420-3049/5/3/431/n/a |
| spellingShingle | Eduardo F. Corsico Roberto A. Rossi SRN1 and Stille Reactions: A New Synthetic Strategy Molecules n/a |
| title | SRN1 and Stille Reactions: A New Synthetic Strategy |
| title_full | SRN1 and Stille Reactions: A New Synthetic Strategy |
| title_fullStr | SRN1 and Stille Reactions: A New Synthetic Strategy |
| title_full_unstemmed | SRN1 and Stille Reactions: A New Synthetic Strategy |
| title_short | SRN1 and Stille Reactions: A New Synthetic Strategy |
| title_sort | srn1 and stille reactions a new synthetic strategy |
| topic | n/a |
| url | http://www.mdpi.com/1420-3049/5/3/431/ |
| work_keys_str_mv | AT eduardofcorsico srn1andstillereactionsanewsyntheticstrategy AT robertoarossi srn1andstillereactionsanewsyntheticstrategy |