Pentacarbonyl-2κ5C-chlorido-1κCl-bis[1(η5)-cyclopentadienyl][μ2-oxido(methyl)methylene-1:2κ2O:C]tungsten(0)zirconium(IV)
The title compound, [ZrW(C5H5)2(C2H3O)Cl(CO)5] or [W(CO)5C(CH3)OZr(C5H5)2Cl], consists of two metal centres, with a (tungsten pentacarbonyl)oxymethylcarbene group coordinating as a monodentate ligand to the chloridozirconocene. The two halves of the molecule are related by a crystallographic mirror...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-10-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808028006 |
| _version_ | 1818960373029535744 |
|---|---|
| author | Stephanie Cronje Gert J. Kruger Nyambeni Luruli Arno Neveling Catharine Esterhuysen |
| author_facet | Stephanie Cronje Gert J. Kruger Nyambeni Luruli Arno Neveling Catharine Esterhuysen |
| author_sort | Stephanie Cronje |
| collection | DOAJ |
| description | The title compound, [ZrW(C5H5)2(C2H3O)Cl(CO)5] or [W(CO)5C(CH3)OZr(C5H5)2Cl], consists of two metal centres, with a (tungsten pentacarbonyl)oxymethylcarbene group coordinating as a monodentate ligand to the chloridozirconocene. The two halves of the molecule are related by a crystallographic mirror plane. Delocalization through the Zr—O—C=W unit is indicated by a short Zr—O distance and a nearly linear Zr—O—C angle. |
| first_indexed | 2024-12-20T11:56:30Z |
| format | Article |
| id | doaj.art-b78be7cca3d0435d80b58961a246774e |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:56:30Z |
| publishDate | 2008-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-b78be7cca3d0435d80b58961a246774e2022-12-21T19:41:39ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-10-016410m1252m125210.1107/S1600536808028006Pentacarbonyl-2κ5C-chlorido-1κCl-bis[1(η5)-cyclopentadienyl][μ2-oxido(methyl)methylene-1:2κ2O:C]tungsten(0)zirconium(IV)Stephanie CronjeGert J. KrugerNyambeni LuruliArno NevelingCatharine EsterhuysenThe title compound, [ZrW(C5H5)2(C2H3O)Cl(CO)5] or [W(CO)5C(CH3)OZr(C5H5)2Cl], consists of two metal centres, with a (tungsten pentacarbonyl)oxymethylcarbene group coordinating as a monodentate ligand to the chloridozirconocene. The two halves of the molecule are related by a crystallographic mirror plane. Delocalization through the Zr—O—C=W unit is indicated by a short Zr—O distance and a nearly linear Zr—O—C angle.http://scripts.iucr.org/cgi-bin/paper?S1600536808028006 |
| spellingShingle | Stephanie Cronje Gert J. Kruger Nyambeni Luruli Arno Neveling Catharine Esterhuysen Pentacarbonyl-2κ5C-chlorido-1κCl-bis[1(η5)-cyclopentadienyl][μ2-oxido(methyl)methylene-1:2κ2O:C]tungsten(0)zirconium(IV) Acta Crystallographica Section E |
| title | Pentacarbonyl-2κ5C-chlorido-1κCl-bis[1(η5)-cyclopentadienyl][μ2-oxido(methyl)methylene-1:2κ2O:C]tungsten(0)zirconium(IV) |
| title_full | Pentacarbonyl-2κ5C-chlorido-1κCl-bis[1(η5)-cyclopentadienyl][μ2-oxido(methyl)methylene-1:2κ2O:C]tungsten(0)zirconium(IV) |
| title_fullStr | Pentacarbonyl-2κ5C-chlorido-1κCl-bis[1(η5)-cyclopentadienyl][μ2-oxido(methyl)methylene-1:2κ2O:C]tungsten(0)zirconium(IV) |
| title_full_unstemmed | Pentacarbonyl-2κ5C-chlorido-1κCl-bis[1(η5)-cyclopentadienyl][μ2-oxido(methyl)methylene-1:2κ2O:C]tungsten(0)zirconium(IV) |
| title_short | Pentacarbonyl-2κ5C-chlorido-1κCl-bis[1(η5)-cyclopentadienyl][μ2-oxido(methyl)methylene-1:2κ2O:C]tungsten(0)zirconium(IV) |
| title_sort | pentacarbonyl 2 954 5c chlorido 1 954 cl bis 1 951 5 cyclopentadienyl 956 2 oxido methyl methylene 1 2 954 2o c tungsten 0 zirconium iv |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808028006 |
| work_keys_str_mv | AT stephaniecronje pentacarbonyl29545cchlorido1954clbis19515cyclopentadienyl9562oxidomethylmethylene129542octungsten0zirconiumiv AT gertjkruger pentacarbonyl29545cchlorido1954clbis19515cyclopentadienyl9562oxidomethylmethylene129542octungsten0zirconiumiv AT nyambeniluruli pentacarbonyl29545cchlorido1954clbis19515cyclopentadienyl9562oxidomethylmethylene129542octungsten0zirconiumiv AT arnoneveling pentacarbonyl29545cchlorido1954clbis19515cyclopentadienyl9562oxidomethylmethylene129542octungsten0zirconiumiv AT catharineesterhuysen pentacarbonyl29545cchlorido1954clbis19515cyclopentadienyl9562oxidomethylmethylene129542octungsten0zirconiumiv |