Hydroxylation of Aryl Sulfonium Salts for Phenol Synthesis under Mild Reaction Conditions

Hydroxylation of Aryl Sulfonium Salts for Phenol Synthesis under Mild Reaction Conditions

Hydroxylation of aryl sulfonium salts could be realized by utilizing acetohydroxamic acid and oxime as hydroxylative agents in the presence of cesium carbonate as a base, leading to a variety of structurally diverse hydroxylated arenes in 47–95% yields. In addition, the reaction exhibited broad func...

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Bibliographic Details
Main Authors: Xuan-Bo Hu, Qian-Qian Fu, Xue-Ying Huang, Xue-Qiang Chu, Zhi-Liang Shen, Chengping Miao, Weiyi Chen
Format: Article
Language:English
Published: MDPI AG 2024-02-01
Series:Molecules
Subjects:
hydroxylation
phenol synthesis
aryl sulfonium salts
acetohydroxamic acid
oxime
Online Access:https://www.mdpi.com/1420-3049/29/4/831

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