Principal Component Analysis (PCA) unravels spectral components present in XPS spectra of complex oxide films on iron foil
Principal component analysis (PCA), as applied to the processing of the complex X-ray photoelectron spectroscopy (XPS) lineshapes, is discussed. PCA analysis example is provided of complex native iron oxide films on Fe foil XPS spectra further modified by argon and helium ion beams. Abstract PCA com...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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Elsevier
2023-10-01
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| Series: | Applied Surface Science Advances |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2666523923000818 |
| _version_ | 1797682483662159872 |
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| author | Neal Fairley Pascal Bargiela Wei-Min Huang Jonas Baltrusaitis |
| author_facet | Neal Fairley Pascal Bargiela Wei-Min Huang Jonas Baltrusaitis |
| author_sort | Neal Fairley |
| collection | DOAJ |
| description | Principal component analysis (PCA), as applied to the processing of the complex X-ray photoelectron spectroscopy (XPS) lineshapes, is discussed. PCA analysis example is provided of complex native iron oxide films on Fe foil XPS spectra further modified by argon and helium ion beams. Abstract PCA components are derived from Fe 2p, O 1 s and C 1 s regions leading to the assignments of surface (oxy)hydroxide, Fe2O3, FeO and Fe metal, as corroborated by the corresponding elemental quantification profiles. Detailed mathematical concepts behind PCA analysis of spectra data are provided. |
| first_indexed | 2024-03-12T00:00:23Z |
| format | Article |
| id | doaj.art-b7c0fbfc7261468580fc912cd7f714a0 |
| institution | Directory Open Access Journal |
| issn | 2666-5239 |
| language | English |
| last_indexed | 2024-03-12T00:00:23Z |
| publishDate | 2023-10-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Applied Surface Science Advances |
| spelling | doaj.art-b7c0fbfc7261468580fc912cd7f714a02023-09-18T04:31:00ZengElsevierApplied Surface Science Advances2666-52392023-10-0117100447Principal Component Analysis (PCA) unravels spectral components present in XPS spectra of complex oxide films on iron foilNeal Fairley0Pascal Bargiela1Wei-Min Huang2Jonas Baltrusaitis3Casa Software Ltd, Bay House, 5 Grosvenor Terrace, Teignmouth, Devon TQ 14 8NE, United KingdomThe Institute for Research on Catalysis and the Environment of Lyon (IRCELYON), University of Lyon, 2 Avenue Albert Einstein, Villeurbanne 69626, FranceDepartment of Mathematics, Lehigh University, Chandler-Ullmann Hall, Bethlehem, PA 18015, United StatesDepartment of Chemical and Biomolecular Engineering, Lehigh University, 111 Research Drive, Bethlehem, PA 18015, United States; Corresponding author.Principal component analysis (PCA), as applied to the processing of the complex X-ray photoelectron spectroscopy (XPS) lineshapes, is discussed. PCA analysis example is provided of complex native iron oxide films on Fe foil XPS spectra further modified by argon and helium ion beams. Abstract PCA components are derived from Fe 2p, O 1 s and C 1 s regions leading to the assignments of surface (oxy)hydroxide, Fe2O3, FeO and Fe metal, as corroborated by the corresponding elemental quantification profiles. Detailed mathematical concepts behind PCA analysis of spectra data are provided.http://www.sciencedirect.com/science/article/pii/S2666523923000818PCAXPSIron oxide |
| spellingShingle | Neal Fairley Pascal Bargiela Wei-Min Huang Jonas Baltrusaitis Principal Component Analysis (PCA) unravels spectral components present in XPS spectra of complex oxide films on iron foil Applied Surface Science Advances PCA XPS Iron oxide |
| title | Principal Component Analysis (PCA) unravels spectral components present in XPS spectra of complex oxide films on iron foil |
| title_full | Principal Component Analysis (PCA) unravels spectral components present in XPS spectra of complex oxide films on iron foil |
| title_fullStr | Principal Component Analysis (PCA) unravels spectral components present in XPS spectra of complex oxide films on iron foil |
| title_full_unstemmed | Principal Component Analysis (PCA) unravels spectral components present in XPS spectra of complex oxide films on iron foil |
| title_short | Principal Component Analysis (PCA) unravels spectral components present in XPS spectra of complex oxide films on iron foil |
| title_sort | principal component analysis pca unravels spectral components present in xps spectra of complex oxide films on iron foil |
| topic | PCA XPS Iron oxide |
| url | http://www.sciencedirect.com/science/article/pii/S2666523923000818 |
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