Carbon Nanofibers: A New Adsorbent for Copper Removal from Wastewater

This research describes the adsorption of Cu<sup>2+</sup> onto a helical ribbon carbon nanofiber. The characterization of carbon nanofiber by zeta potential showed an isoelectronic pH of 1.9. The influence of different adsorption factors, such as stirring speed, temperature, pH, adsorben...

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Main Authors: Irene García-Díaz, Felix Antonio López, Francisco José Alguacil
Format: Article
Language:English
Published: MDPI AG 2018-11-01
Series:Metals
Subjects:
Online Access:https://www.mdpi.com/2075-4701/8/11/914
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author Irene García-Díaz
Felix Antonio López
Francisco José Alguacil
author_facet Irene García-Díaz
Felix Antonio López
Francisco José Alguacil
author_sort Irene García-Díaz
collection DOAJ
description This research describes the adsorption of Cu<sup>2+</sup> onto a helical ribbon carbon nanofiber. The characterization of carbon nanofiber by zeta potential showed an isoelectronic pH of 1.9. The influence of different adsorption factors, such as stirring speed, temperature, pH, adsorbent concentration, etc., on the Cu<sup>2+</sup> adsorption capacity have been evaluated. The pH has a great influence on Cu<sup>2+</sup> adsorption, with the maximum adsorption capacity reached at a pH of 10. The experimental data fit well to pseudo-second order kinetic and Langmuir isotherm models (<i>q</i><sub>m</sub> = 8.80 mg&#183;g<sup>&#8722;1</sup>) at <i>T</i> = 298 K and pH = 4. The Cu<sup>2+</sup> adsorption could be explained by the particle diffusion model. Results showed that carbon nanofiber could be successfully used for the elimination of Cu<sup>2+</sup> from wastewater.
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spelling doaj.art-b7c179bada4e4a43a92126aeafd7a5992022-12-22T03:47:56ZengMDPI AGMetals2075-47012018-11-0181191410.3390/met8110914met8110914Carbon Nanofibers: A New Adsorbent for Copper Removal from WastewaterIrene García-Díaz0Felix Antonio López1Francisco José Alguacil2Centro Nacional de Investigaciones Metalúrgicas (CENIM-CSIC), Avda. Gregorio del Amo, 8, 28040 Madrid, SpainCentro Nacional de Investigaciones Metalúrgicas (CENIM-CSIC), Avda. Gregorio del Amo, 8, 28040 Madrid, SpainCentro Nacional de Investigaciones Metalúrgicas (CENIM-CSIC), Avda. Gregorio del Amo, 8, 28040 Madrid, SpainThis research describes the adsorption of Cu<sup>2+</sup> onto a helical ribbon carbon nanofiber. The characterization of carbon nanofiber by zeta potential showed an isoelectronic pH of 1.9. The influence of different adsorption factors, such as stirring speed, temperature, pH, adsorbent concentration, etc., on the Cu<sup>2+</sup> adsorption capacity have been evaluated. The pH has a great influence on Cu<sup>2+</sup> adsorption, with the maximum adsorption capacity reached at a pH of 10. The experimental data fit well to pseudo-second order kinetic and Langmuir isotherm models (<i>q</i><sub>m</sub> = 8.80 mg&#183;g<sup>&#8722;1</sup>) at <i>T</i> = 298 K and pH = 4. The Cu<sup>2+</sup> adsorption could be explained by the particle diffusion model. Results showed that carbon nanofiber could be successfully used for the elimination of Cu<sup>2+</sup> from wastewater.https://www.mdpi.com/2075-4701/8/11/914carbon nanofibersmetal adsorptioncarbon nanomaterialscopper adsorptionwastewater
spellingShingle Irene García-Díaz
Felix Antonio López
Francisco José Alguacil
Carbon Nanofibers: A New Adsorbent for Copper Removal from Wastewater
Metals
carbon nanofibers
metal adsorption
carbon nanomaterials
copper adsorption
wastewater
title Carbon Nanofibers: A New Adsorbent for Copper Removal from Wastewater
title_full Carbon Nanofibers: A New Adsorbent for Copper Removal from Wastewater
title_fullStr Carbon Nanofibers: A New Adsorbent for Copper Removal from Wastewater
title_full_unstemmed Carbon Nanofibers: A New Adsorbent for Copper Removal from Wastewater
title_short Carbon Nanofibers: A New Adsorbent for Copper Removal from Wastewater
title_sort carbon nanofibers a new adsorbent for copper removal from wastewater
topic carbon nanofibers
metal adsorption
carbon nanomaterials
copper adsorption
wastewater
url https://www.mdpi.com/2075-4701/8/11/914
work_keys_str_mv AT irenegarciadiaz carbonnanofibersanewadsorbentforcopperremovalfromwastewater
AT felixantoniolopez carbonnanofibersanewadsorbentforcopperremovalfromwastewater
AT franciscojosealguacil carbonnanofibersanewadsorbentforcopperremovalfromwastewater